研究生: |
陳鼎志 |
---|---|
論文名稱: |
以被覆TiO2之玻璃珠填充床處理三氯乙烯之研究 Gas phase photocatalytic oxidation of trichloroethylene over TiO2 supported on glass bead in a packed bed |
指導教授: |
黃世傑
Shyh-Jye Hwang |
口試委員: | |
學位類別: |
碩士 Master |
系所名稱: |
工學院 - 化學工程學系 Department of Chemical Engineering |
論文出版年: | 2004 |
畢業學年度: | 92 |
語文別: | 中文 |
論文頁數: | 64 |
中文關鍵詞: | 光催化 、TCE 、填充床 、TiO2 |
相關次數: | 點閱:91 下載:0 |
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液相與氣相的光催化反應已被廣泛的探討,其中應用於毒化物的處理方面更是被熱烈的研究。本研究之目的在於使用被覆奈米級TiO2之玻璃珠之填充床來處理三氯乙烯(Trichloro- ethylene,TCE)氣體,改變進氣流量、濃度及溼度以及反應溫度來探討其對於TCE之去除率、反應速率與礦化率之影響。實驗並輔助以批次反應器來探討反應溼度對於礦化率影響。實驗結果顯示,TCE之去除效率隨氣體流量的減少、入口濃度的下降、反應溼度的下降而上升。對於TCE的反應速率而言,最佳之氣體流量為300ml/min,而在反應溫度的研究發現在高滯留時間時,去除效率隨溫度上升而上升但在低滯留時間時反應在50℃時有一最佳值,這是因為在低滯留時間時溫度過高會造成TCE在觸媒表面之吸附能力下降而使其成為速率決定步驟,故造成去除效率下降。而在批次反應器之研究發現,TCE之礦化率隨溼度上升而下降,與連續式反應器結果類似。
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