摘　要

　　吾人利用步進式掃瞄時域解析-霍氏轉換紅外光譜放光技術，研究C6H5OH分子於193 nm之光解動態學。藉由觀測CO的振轉動放光譜線，以分析光解產物CO的內能分佈。C6H5OH經193 nm激發後躍遷至高電子激發態，再經由內轉移至基態位能面而進行三中心分解途徑產生CO。
C6H5OH經193 nm雷射光解後，可觀測到產物CO之最高振動態達υ<4，轉動態達J<70的振-轉動解析放光光譜，從所得的光譜可推算出CO的平均轉動能量為28.6 ± 3 kJ mol-1，佔可用能量frot = 0.054 ± 0.005；平均振動能量為12.7 ± 3 kJ mol-1，佔可用能量fvib = 0.024 ± 0.006。利用外插法可得CO的初生態平均轉動溫度為4520 ± 70 K、初生態平均轉動能量為31.0 ± 3.0 kJ mole-1，以及CO (υ = 0－4)之振動態佈居數相對百分比，分別為63.6%，24.0%，8.1%，3.2%，1.2%。
另外，利用GAUSSIAN 03程式以G2M方法所得到C6H5OH之反應位能圖，並根據RRKM理論，發現C6H5OH經TS14過渡態產生CO之解離途徑為可能的主要反應途徑。同時以改良衝擊模式所預測CO之轉動能，與實驗所得之結果接近。

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