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研究生： 郭淑華
Kuo, Shu-Hua
論文名稱： 插層法合成具超導調控性之二硼化鎂可撓複合材料
MgB2 Intercalated Muscovite with Dynamically Tunable Superconductivity
指導教授： 朱英豪
Chu, Ying-Hao
口試委員: 鄭澄懋
Cheng, Cheng-Maw
林俊源
Lin, Jiunn-Yuan
學位類別： 碩士
Master
系所名稱： 工學院 - 材料科學工程學系
Materials Science and Engineering
論文出版年： 2024
畢業學年度： 112
語文別： 中文
論文頁數： 108
中文關鍵詞： 插層法 、超導體 、複合材料 、可調變臨界溫度 、二硼化鎂 、雲母
外文關鍵詞： Intercalation, Superconductivity, muscovite, MgB2, Alterable Critical Temperature, composite
相關次數： 點閱：68  下載：0 
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    • 在本研究中，我們開發了一種簡單的方法來研究壓力對材料在低維環境中超導性質的影響。透過氣相插層法（Gas-Phase Intercalation），我們將二硼化鎂（MgB2）奈米晶體插入到雲母（Muscovite）的層間，這些層間以弱的凡德瓦力（Van der Waals Force）連結，被視為二維腔體，很容易經過熱處理使 MgB2 以氣相蒸氣進入雲母的間隙中成核、成長。插層後的複合材料 MgB2－Muscovite 其超導臨界溫度（Critical Temperature, Tc）可以透過兩種不同的效應來調節：(1) 在雲母二維腔體的MgB2 會受到來自雲母層間的壓力，這個插層效應在本研究中產生的靜態壓力使 Tc 降低，且以不同的熱處理條件可調控 Tc (2) 因雲母的可撓性，我們示範了可透過彎曲此複合材料施加外應力於 MgB2 ，此動態彎曲效應進一步將 Tc 降低了 1.3 K，相當於約1.17 GPa 的壓力。 Tc 的變化與施加的壓力相關，這種變化證明雲母插層可以成為一個廣泛的平台，用於研究在壓力的作用下，不同功能材料的性質變化。本研究系統性地探討 MgB2－Muscovite 的結構、元素組成、形貌及超導性質，我們以 MgB2 作為插層系統壓力研究的範例，期望透過 MgB2 的結果展示，啟發更多雲母插層複合材料的開展。

    In this study, a simple approach to studying the influence of pressure on the superconducting properties of materials in a reduced-dimension environment has been developed. By employing gas phase intercalation, we have inserted MgB2 nanocrystals into the muscovite interlayers, where can be viewed as 2D cavities. The superconducting critical temperature of MgB2-muscovite composites is modulated through two distinct effects: static pressure from the intercalation effect decreases with various process parameters; dynamic bending effect further reduces the critical temperature by 1.3K, corresponding to a pressure of 1.17 GPa. The change in the critical temperature exhibits a high correlation to the applied external stress. This variation proves that muscovite intercalation can be a universal platform for studying functional materials in reduced dimensions under external pressure in ambient conditions. This study uses MgB2 as an example of an intercalation system under pressure, aiming to inspire further development of mica intercalated composite materials through our results obtained from MgB2.

    序 I 摘要 II Abstract III 誌謝 IV 目錄 VII 圖目錄 IX 表目錄 XIII 第一章　緒論 1 第一節　研究動機 1 第二節　簡介與文獻回顧 2 一、　超導體 Superconductor 2 二、　二硼化鎂 MgB2 9 三、　高壓物理 High-pressure Research 13 四、　人工雲母 Artificial Muscovite 14 五、　插層法 Intercalation 16 六、　文獻回顧 18 第二章　實驗方法及分析儀器原理 21 第一節　實驗方法原理 21 一、　高溫退火爐 21 二、　製程設計 23 第二節　分析儀器原理 25 一、　X光繞射儀 X-ray diffractometer 25 二、　拉曼光譜儀 Raman Spectrometer 30 三、　掃描式電子顯微鏡 Scanning Electron Microscope 37 四、　原子力顯微鏡 Atomic Force Microscope 42 五、　穿透式電子顯微鏡Transmission Electron Microscope 45 六、　電子微探儀 Electron Probe Microanalyzer 48 七、　震動樣品磁化儀 Vibrating Sample Magnetometer 51 八、　超導量子干涉儀 Superconducting QUantum Interference Device 54 第三章　實驗結果與討論 57 第一節　製程參數、樣品外觀及量測前處理 57 一、　製程參數與樣品外觀 57 二、　儀器分析前處理 60 第二節　結構與元素分析 61 一、　結構分析 61 二、　元素分析 68 第三節　樣品形貌分析 73 第四節　超導性質分析 82 一、　MgB2－Muscovite 的超導性質 82 二、　插層效應與彎曲實驗 95 第四章　結論 102 參考資料 105

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