簡易檢索 / 詳目顯示

研究生: 張家諭
Zhang, Jia Yu
論文名稱: 旋轉床與固定床捕獲高爐燃燒尾氣之二氧化碳效能比較與溶劑評估
Compared Rotating Packed Bed and Packed Bed Capture CO2 from Blast Furnace Vent and Solvent Assessment
指導教授: 鄭西顯
Jang, Shi Shang
口試委員: 張玨庭
汪上曉
錢義隆
學位類別: 碩士
Master
系所名稱: 工學院 - 化學工程學系
Department of Chemical Engineering
論文出版年: 2015
畢業學年度: 103
語文別: 中文
論文頁數: 84
中文關鍵詞: 二氧化碳旋轉床
相關次數: 點閱:134下載:0
分享至:
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報
  • 「溫室效應」為工業革命以來全球平均溫度明顯上升之主要原因,造成「溫室效應」最可能原因之一為石化燃料大量使用使得大氣層中CO2濃度明顯增加,為了抑制CO2濃度攀升,「節能減碳」已成為國家能源環境政策發展之重點項目。為此我們於鋼鐵廠及實驗室內各建立一套CO2吸收示範設備,應用各種吸收劑作為相關研究之依據,並提供製程改善方法以達到節能效果。
    本研究以化學吸收法利用30wt% MEA和4mPZ+4mDETA水溶液作為吸收劑捕獲CO2,並串聯超重力旋轉床(Rotating packed bed,RPB)和氣提塔,建立吸收脫附循環,取代傳統吸收塔以縮減傳統化學吸收製程所需之龐大設備體積並減少再生能耗。由於超重力旋轉床被研究出可以提升氣液接觸表面積,本研究將在相同操作條件下,分別在固定床及旋轉床進行兩者二氧化碳捕獲效率比較,實驗結果發現兩者捕獲效率相近,但旋轉床的體積為固定床的體積1/3倍,顯示以超重力旋轉床取代傳統填充床之可行性。


    Greenhouse effect main reason for the significant increase in global average temperatures since the industrial revolution. Greenhouse effect is most likely one of the reasons for the extensive use of fossil fuels so that the CO2 concentration in the atmosphere increased significantly. In order to suppress the rise in CO2 concentration, Energy saving and carbon reduction have become the key projects of the National Energy Policy Development Environment. For this purpose, we build a carbon capture system in steel plant and laboratory. As a basis for the application of various absorbents related research, and provide process improvement methods to achieve energy savings.
    The study capture CO2 by 30wt% MEA solution and 4mPZ+4mDETA solution that was carried out in rotating packed bed connected gas stripper. The conventional packed bed absorber and stripper were replaced by a rotating packed bed for reducing the volumes of conventional packed bed absorber and stripper and the regeneration energy of chemical absorbent in CO2 capture process. Developed as a result of gravity rotating bed can improve the gas-liquid contact surface area. In the study, compared with conventional packed bed and rotating packed bed for CO2 capture efficiency at same fixed operation condition. It was found that both capture efficiency are similar, but the volume of rotating bed is the volume of the conventional packed bed 1/3 times.

    目錄 摘要 I 表目錄 V 圖目錄 VI 第一章、緒論 1 1.1研究背景 1 1.2研究目標 7 1.3文獻回顧 8 1.3.1各類醇胺介紹及其反應機制醇胺種類及其反應機制 8 1.3.2填充床 12 1.3.3超重力旋轉床 13 第二章、研究內容 16 2.1實驗工廠介紹 16 2.2配置吸收劑 16 2.3開啟加熱器時間點 19 2.4實驗方法 20 2.4.1中鋼先導工廠連結旋轉床測試 20 2.4.2中鋼先導工廠以30wt%MEA水溶液及4mPZ+4mDETA進行CO2吸收脫附實驗 22 2.4.3中鋼先導工廠與RPB串聯以30wt%MEA水溶液及4mPZ+4mDETA進行CO2吸收脫附實驗 25 2.5滴定方法 27 2.5.1 MEA滴定 27 2.5.2 PZ+DETA滴定 30 第三章、研究結果 33 3.1中鋼先導工廠固定床與旋轉床實驗測試結果 33 3.2中鋼先導工廠30WT%MEA水溶液固定床與旋轉床 35 3.3中鋼先導工廠4MPZ+4MDETA固定床與旋轉床實驗 38 3.4設備及吸收劑結果比較 42 3.5探討吸收劑中二氧化碳含量 47 第四章、結論 50 參考文獻 51 附錄A、 30WT%MEA現場操作原始數據 53 附錄B、 4MPZ+4MDETA現場操作原始數據 69

    [1] J. Albo and A. Irabien, "Carbon Dioxide Capture from Flue Gases Using a Cross-Flow Membrane Contactor and the Ionic Liquid 1-Ethyl-3-methylimidazolium Ethylsulfate," Industrial & Engineering Chemistry Research, vol. 49, pp. 11045-11051, 2010.
    [2] G. T. Rochelle, "Amine scrubbing for CO2 capture," Science, vol. 325, pp. 1652-1654, 2009.
    [3] IEA, Key World Energy Statistics : IEA., 2012.
    [4] M. Wang, A. Lawal, P.Stephenson, J. Sidders, and C. Ramshaw, "Post-combustion CO2 capture with chemical absorption: A state-of-the-art review," Chemical Engineering Research and Design, vol. 89, pp. 1609-1624, 2011.
    [5] G. T. Rochelle, "Amine Scrubbing for CO2 Capture," Science, vol. 325, pp. 1652-1654, 2009.
    [6] M. Caplow, "Kinetics of carbamate formation and breakdown," Journal of the American Chemical Society, vol. 90, pp. 6795-6803, 1968.
    [7] P. V. Danckwerts, "The reaction of CO2 with ethanolamines," Chemical Engineering Science, vol. 34, pp. 443-446, 1979.
    [8] P. Blauwhoff, G. F. Versteeg and W. Van Swaaij, "A study on the reaction between CO2 and alkanolamines in aqueous solutions," Chemical Engineering Science, vol. 38, pp. 1411-1429, 1984.
    [9] E. B. Rinker, S. A. Sami and O. C. Sandall, "Kinetics and modelling of carbon dioxide absorption into aqueous solutions of N-methyldiethanolamine," Chemical Engineering Science, vol. 50, pp. 755-768, 1995.
    [10] T.L. Donaldson and Y. N. Nguyen, "Carbon Dioxide Reaction Kinetics and Transport in Aqueous Amine Membranes," Industrial & Engineering Chemistry Fundamentals, vol. 19, pp. 260-266, 1980.
    [11] R. H. Mallinson and C. Ramshaw, "Mass transfer process," Google Patents, 1981.
    [12] S.P. Singh, J. H. Wilson, R. M. Counce, A. J. Lucero, G. D. Reed, R. A. Ashworth and M.G.Elliott, "Removal of volatile organic compounds from groundwater using a rotary air stripper," Industrial & Engineering Chemistry Research, vol. 31, pp. 574-580, 1992.
    [13] T. J. Ho, C. C. Lin, and W. T. Liu, "Distillation in a Rotating Packed Bed," Journal of chemical engineering of Japan, vol. 35, pp. 1298-1304, 2002.
    [14] F. Guo, C. Zheng, K. Guo, Y. Feng, and N. C. Gardner, "Hydrodynamics and mass transfer in cross-flow rotating packed bed," Chemical Engineering Science, vol. 52, pp. 3853-3859, 1997.
    [15] C.C. Lin, B.C. Chen,, "Carbon dioxide absorption in a cross-flow rotating packed bed," Chem. Eng. Res. and Des. Article in Press, 2011.
    [16] W. T. Liu. C.C. Lin, and C.S. Tan, "Removal of carbon dioxide by absorption in a rotating packed bed," Industrial & engineering chemistry research, vol. 42, pp. 2381-2386, 2003.
    [17] M. S. Jassim, G .Rochelle, D. Eimer, and C. Ramshaw, "Carbon Dioxide Absorption and Desorption in Aqueous Monoethanolamine Solutions in a Rotating Packed Bed," Industrial & Engineering Chemistry Research, vol. 46, pp. 2823-2833, 2007.
    [18] B. C. Sun, X. M. Wang, J. M. Chen, G. W. Chu, J.F.Chen and L. Shao, "Simultaneous Absorption of CO2 and NH3 into Water in a Rotating Packed Bed," Industrial & Engineering Chemistry Research, vol. 48, pp. 11175-11180, 2009.
    [19] G. Q. Wang, Z. C. Xu, Y. L. Yu, and J. B. Ji, "Performance of a rotating zigzag bed—A new HIGEE," Chemical Engineering and Processing: Process Intensification, vol. 47, pp. 2131-2139, 2008.

    無法下載圖示 全文公開日期 本全文未授權公開 (校內網路)
    全文公開日期 本全文未授權公開 (校外網路)

    QR CODE