本論文是我在碩士班期間研究的八顆單晶結構的成果報告。本論文包含兩個部分：在第一部份裡，回顧X光結晶學的基本原理，其中包括了厄瓦球與布拉格繞射定理；而在第二部分裡，則討論了我所解的八顆單晶的結構，裡面也探討其鍵長、鍵角以及分子之間的作用力等，此八顆晶體如下：
單晶結構1 1-(N,N-diethyl)-2-[2-(pyridyl) benzylidene] ethane triazido cobalt(III)

單晶結構2 Bis-[1-ethyl-2-(p-tolylazo)] imidazole diazido copper(II)

單晶結構3 1,3-Bis[2-(pyridyl) benzylidene] propane azido copper(II) perchlorate

單晶結構4 1,4-Bis-[2-(pyridyl) benzylidene] butane diazido cadmium(II)

單晶結構5 Bis-(μ-1,4-pyrazine)-diselenocyanate cadmium(II) Polymer

單晶結構6 Bis[(4,4,-dipyridyl) disulfide]-bis[dicyano imide] diaquo manganese(II) (4,4,-dipyridyl) disulfide

單晶結構7 2,6-Bis(2-phenylazo) pyridine

單晶結構8 1,2-Bis(4-pyridyl) ethene monohydrate

This thesis is the report on the research work of crystal structure determination of eight compounds during my master degree study. It contained two parts: Part I. reviews the basic principle of X-ray structure determination; such as the relationship between Ewald sphere and Bragg’s law. Part II. comprises the eight crystal structures I solved. The structures are as following：
Crystal 1. 1-(N,N-diethyl)-2-[2-(pyridyl) benzylidene] ethane triazido cobalt(III)

Crystal 2. Bis-[1-ethyl-2-(p-tolylazo)] imidazole diazido copper(II)

Crystal 3. 1,3-Bis[2-(pyridyl) benzylidene] propane azido copper(II) perchlorate

Crystal 4. 1,4-Bis-[2-(pyridyl) benzylidene] butane diazido cadmium(II)

Crystal 5. Bis-(μ-1,4-pyrazine)-diselenocyanate cadmium(II) Polymer

Crystal 6. Bis[(4,4,-dipyridyl) disulfide]-bis[dicyano imide] diaquo manganese(II) (4,4,-dipyridyl) disulfide

Crystal 7. 2,6-Bis(2-phenylazo) pyridine

Crystal 8. 1,2-Bis(4-pyridyl) ethene monohydrate

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