水熱法合成BiFeO3和Bi2Fe4O9及改變其形貌｜國立清華大學博碩士論文庫

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研究生：	廖瑩蟬 Liao, Ying Chan
論文名稱：	水熱法合成BiFeO3和Bi2Fe4O9及改變其形貌 Fabrication of BiFeO3 and Bi2Fe4O9 with Controllable Morphologies via the Hydrothermal Approach
指導教授：	闕郁倫 Chueh, Yu-Lun 蔡哲正 Tsai, Cho-Jen
口試委員:	林居南俎永熙
學位類別：	碩士 Master
系所名稱：	工學院 - 材料科學工程學系 Materials Science and Engineering
論文出版年：	2012
畢業學年度：	100
語文別：	英文
論文頁數：	210
中文關鍵詞：	鐵酸鉍、水熱法
外文關鍵詞：	bismuth ferrites
相關次數：	點閱：103 下載：0
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The bismuth ferrites have attracted renewed interest in applications not only because BiFeO3, with high Curie temperature (TC = 1143 K) and Neel temperature (TN = 643 K), is a room temperature multiferroic material, but also because there is another phase, Bi2Fe4O9 with space group Pbam and Neel temperature TN ＝ 263 K, that has variety of applications including gas sensor, photocatalysts and catalysts. Through conventional hydrothermal synthetic route, we can obtain well-defined single crystallites of Bi2Fe4O9 and BiFeO3. The crystals obtained were characterized by the SEM (scanning electron microscope), XRD (X-ray diffraction), TEM (Transmission electron microscope) and VSM (Vibrating sample magnetometer) techniques. In addition, we were able to successfully synthesize a variety of morphologies of BiFeO3 and Bi2Fe4O9 by adding surfactant, oxidative anion, different ratios of precursor or K+/Na+, and by controlling the temperatures of suspension and mineralizer solutions. Controllable morphologies with facile hydrothermal methods are potentially useful in the aspect of variable magnetic, optical and electrical properties through development of various faces.

Contents
Abstract    I
Acknowledgement ……………………………………………………....Ⅱ
Chapter 1    Introduction    1
1-1 The properties of Bi2Fe4O9 and BiFeO3    1
1-1.1    Bi2Fe4O9    1
1-1.2    BiFeO3    7
1-1.3    Multiferroic materials:    13
1-2 Preparation of Bi2Fe4O9 and BiFeO3 by hydrothermal approaches:    20
1-2.1    Introduction of hydrothermal synthetic methods:    20
1-2.2 Hydrothermal methods for ternary bismuth ferrites:    22
1-3 Motivation:    38
Chapter 2    Experimental procedures    39
2-1 Hydrothermal Synthesis of Bi2Fe4O9 and BiFeO3 single crystals    39
2-2 Scanning Electron Microscope Observation (SEM)    42
2-3 X-ray Diffraction Analysis (XRD)    42
2-4 Transmission Electron Microscope Observation (TEM)    42
2-5 Vibrating sample magnetometer (VSM)    43
Chapter 3    Results and discussion    44
3-1 The effect of the surfactant polyethylene glycol (PEG) on BiFeO3 and Bi2Fe4O9    44
3-1.1    PEG (M.W. = 200) in the Bi-Fe solution    44
3-1.2    PEG (M.W. = 6000) in the Bi-Fe solution    52
3-2 The participation of Fe2+ ions in the Bi-Fe reaction system    62
3-2.1    The introduction of FeCl2‧4H2O compound into the Bi-Fe solution environment    62
3-2.2    The introduction of FeSO4‧7H2O compound into the Bi-Fe solution environment    70
3-2.3    Different synthetic time    77
3-2.4    Discussion of possible formation mechanism for the donut shape structure with the presence of FeSO4．7H2O or FeCl2．4H2O    85
3-3  The syntheses of rod-like structure Bi2Fe4O9    92
3-3.1    Syntheses rod structure of Bi2Fe4O9 for different hydrothermal temperature in the Fe3+ rich environment    92
3-3.2    Tuning the molar ratio of precursor Bi3+ and Fe3+    108
3-3.3    Syntheses of the rod structure of Bi2Fe4O9 with different molar ratio of K+ and Na+ in the Fe3+ rich environment    117
3-3.4    The addition of surfactant of hexadecyl trimethyl ammonium chloride (CTAC) in the condition of Bi3+ / Fe3+ = 1/2 for various reaction time    138
3-3.5    Temperature issue of mineralizer on the elongated structure of Bi2Fe4O9    151
3-3.6    The temperature difference between mineralizer and mixing solutions    174
3-3.7    The reaction system of Bi3+/Fe3+ = 1/2 under different reaction temperature    193
Chapter 4    Conclusion    204
Reference………………………………………………………………207 

                                

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