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研究生: 陳韻琳
論文名稱: 含高比例顆粒磷光材料懸浮液塗佈特性之研究
指導教授: 劉大佼
口試委員: 吳平耀
朱文彬
學位類別: 碩士
Master
系所名稱: 工學院 - 化學工程學系
Department of Chemical Engineering
論文出版年: 2013
畢業學年度: 101
語文別: 中文
論文頁數: 128
中文關鍵詞: 狹縫式塗佈高比例顆粒懸浮溶液磷光材料影像感光板
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  • 本研究開發利用濕式塗佈技術,將高比例顆粒懸浮溶液之磷光材料,以具有生產優勢之狹縫式塗佈技術製備電腦放射影像系統中的影像感光板。
    本研究的重點在於克服粒子懸浮溶液於塗佈製程中沉澱之問題,以維持長期操作之可行性,並研發符合商業化條件產品,以提供工業化量產之參考基礎。研究的架構主要分成配方研究及製程研究兩部分,配方以參考公開專利中影像感光板之材料與合作廠商所提供之配方作結合,並以刮刀塗佈、單層狹縫式塗佈、雙層塗佈及後續滾輪輾壓乾燥等製程研究其塗佈之效果以作調整,除此之外也針對各種溶液配方之基本流體物性進行量測。
    製程部分,首先以刮刀塗佈瞭解塗層成膜之基本性質,爾後利用不同單層狹縫式模具尋找適合之塗佈製程及參數條件,再嘗試製備具有一定均勻度及不同厚度之影像感光板,並以理論計算驗證狹縫式塗佈技術之可行性;再則以雙層塗佈進行多功能塗層測試,最後針對粒子堆疊進行研究,以滾輪輾壓方式測試顆粒緊密堆疊之效果。


    The research is related to the manufacturing of an image plate of computed radiography(CR).
    Single-layered slot die coating operation with a T-die was chosen to be a method of manufacturing of an image plate of computed radiography. Under proper control of coating parameters, phosphorescent material which is a suspensions with high solid content can form a coating layer on a PET substrate with width 10 cm. The phosphorescent coating layer has good quality after drying. The dry film thickness can be controlled in the range 100-150 μm and the uniformity can be controlled within ±10%.

    摘要 I 目錄 II 圖目錄 IV 表目錄 X 第一章、緒論 1 1-1 前言 1 1-2 簡述X射線檢測技術的發展 2 1-3 塗佈技術簡介 3 1-4 研究動機與研究架構 8 第二章、文獻回顧 11 2-1 懸浮溶液系統 11 2-2 狹縫式塗佈技術 13 2-2-1 狹縫式塗佈技術之介紹 13 2-2-2 狹縫式塗佈技術的發展 16 2-3 數位化X光檢測技術概論 18 2-3-1 電腦放射影像系統(CR)之簡介與原理 23 2-3-2 影像感光板製作之簡介 26 2-3-3 影像感光板之專利文獻回顧 28 第三章、實驗方法與流程 37 3-1 實驗藥品 37 3-2 實驗設備與分析儀器 38 3-3 實驗方法 45 3-3-1 實驗溶液配置 45 3-3-2 塗液物性量測 45 3-3-3 實驗裝置建立 46 3-3-4 實驗流程 52 第四章、實驗數據與結果討論 54 4-1 塗液物性分析 54 4-1-1 流變及黏度分析 54 4-1-2 表面張力分析 58 4-1-3 塗液溶解度及沉澱觀測 60 4-1-4 磷光材料粒子粒徑分佈探討 61 4-2 刮刀塗佈 64 4-2-1 手動刮刀塗佈 64 4-2-2 方塊式塗佈機台自動刮刀塗佈 67 4-3 狹縫式塗佈 78 4-3-1 單層狹縫式特殊模具 A-B die之塗佈研究 78 4-3-2 單層狹縫式模具 T-die之厚膜塗佈研究 86 4-3-3 單層狹縫式模具 T-die之薄膜塗佈研究 91 4-3-4 雙層塗佈 97 4-4 滾輪輾壓之粒子堆疊效果探討 109 4-4-1 手動滾輪輾壓之初步探討 110 4-4-2 機械式滾輪設備輾壓 113 4-5 產品整合氣阻膜 118 第五章、結論 119 附錄A、相關計算 121 A1、塗液之屈服應力 121 A2、塗液之冪次現象線性逼近數據(power law fitting) 122 A3、T-die之管壁剪切應力(apparent wall shear stress) 123 附錄B、均勻度算法 125 附錄C、參考文獻 126

    [1] Haus, A. G. and Cullinan, J. E. Screen film processing systems for medical radiography: a historical review. RadioGraphics 9, 1203-1224 (1989)
    [2] Sonoda, M., Takano, M., Miyahara, J., and Kato, H. Computed radiography utilizing scanning laser stimulated luminescence. Radiology 148, 833-838 (1983)
    [3] Russel, W. B. Review of the role of colloidal forces in the rheology of suspensions. Journal of Rheology 24, 287-317 (1980)
    [4] Sato, T. and Ruch, R. Stabilization of colloid dispersions by polymer adsorption. Marcel Dekker Inc., 1-36 (1980)
    [5] Einstein, A. A new determination of molecular dimensions. Annalen der Physik 19, 289-306 (1906)
    [6] Mooney, M. The viscosity of a concentrated suspension of spherical particles. Journal of Colloid Science 6, 162-170 (1951)
    [7] Macosko, C. W. and Larson, R. G. Rheology: principles, measurements, and applications. Wiley, New York (1994)
    [8] Liang, G. G., Hawkett, B. S., and Tanner, R. I. The determination of the isoelectric point from measurements of dispersion viscosity as a function of pH. Journal of Dispersion Science and Technology 26, 469-472 (2005)
    [9] Chibowski, St. and Paszkiewicz, M. Studies of the influence of acetate groups from polyvinyl alcohol on absorption and electrochemical properties of the TiO2-polymer solution interface. Journal of Dispersion Science and Technology 22, 281-289 (2001)
    [10] Yamamura, M., Miura, H., and Kage, H. Postponed air entrainment in dilute suspension coatings. AIChE Journal 51, 2171-2177 (2005)
    [11] Yamamura, M., Matsunaga, A., Mawatari, Y., Adachi, K., and Kage, H. Particle-assisted dynamic wetting in a suspension liquid jet impinged onto a moving solid at different flow rates. Chemical Engineering Science 61, 5421-5426 (2006)
    [12] 朱文彬。含有機/無機粒子塗液於精密模具塗佈流動之分析。國立清華大學化學工程研究所博士論文。(2007)
    [13] Beguin, A. E. and Rochester, N. Y. Method of coating strip material. United States Patent 2,681,294 (1954)
    [14] Russell, T. A., Wilson, R. M., and Sanford, C. R. Multiple coating apparatus. United States Patent 2,761,417 (1956)
    [15] Landau, L. and Levich, B. Dragging of a liquid by a moving plate. Acta Physicochimica URSS 17, 42-54 (1942)
    [16] Ruschak, K. J. Limiting flow in a pre-metered coating device. Chemical Engineering Science 31, 1057-1060 (1976)
    [17] Higgins, B. G. and Scriven, L. E. Capillary-pressure and viscous pressure-drop set bounds on coating bead operability. Chemical Engineering Science 35,673-682 (1980)
    [18] Hens, J. and Boiy, L. Operation of the bead of a pre-metered coating device. Chemical Engineering Science 41, 1827-1831 (1986)
    [19] Chang, Y. R., Chang, H. M., Lin, C. F., Liu, T. J., and Wu, P. Y. Three minimum wet thickness regions of slot die coating. Journal of Colloid and Interface Science 308, 222-230 (2007)
    [20] Chang, Y. R., Lin, C. F., and Liu, T. J. Start-up of slot die coating. Polymer Engineering and Science 49, 1158-1167 (2009)
    [21] Lee, K. Y., Liu, L. D. and Liu, T. J. Minimum wet thickness in extrusion slot coating. Chemical Engineering Science 47, 1703-1713 (1992)
    [22] Ning, C. Y., Tsai, C. C. and Liu, T. J. The effect of polymer additives on extrusion slot coating. Chemical Engineering Science 51, 3289-3297 (1996)
    [23] 林育彥。適用含有機/無機微奈米粒子懸浮塗液系統於濕式塗佈製程之精密模具設計。國立清華大學化學工程研究所碩士論文。(2010)
    [24] Neitzel, U. Status and prospects of digital detector technology for CR and DR. Radiation Protection Dosimetry 114, 32-38 (2005)
    [25] 陈朝,李仓敏,贾铎默。IP板研究現狀與前景展望。影像技術 3, 3-7 (2011)
    [26] 葉善宏,蔡縈晏,丁明德。胸部電腦放射攝影與數位放射攝影及傳統底片X光攝影病人有效劑量之評估比較。慈濟技術學院學報 13,91-102 (2009)
    [27] Seggern, H. V. Photostimulable X-ray storage phosphors: a review of present understanding. Brazilian Journal of Physics 29, 254-268 (1999)
    [28] Leblans, P., Vandenbroucke, D., and Willems, P. Storage phosphors for medical imaging. Materials 4, 1034-1086 (2011)
    [29] Seggern, H. V. X-ray imaging with photostimulable phosphors. Nuclear Instruments and Methods in Physics Reasearch A332, 467-471 (1992)
    [30] Yamazaki, H., Kitada, A., and Yamazaki K. Radiation image storage panel and process for the preparation of the same. United States Patent 4,728,583 (1988)
    [31] Li, H., Epilbaum, E., Batentschuk, M., and Winnacker, A. Tape casting of storage phosphor BaFBr:Eu2+ for X-ray imaging. Material Science and Engineering B96, 313-319 (2002)
    [32] Kohda, K. Stimulable phosphor sheet and process for producing the same. United States Patent 6,507,037 B2 (2003)
    [33] Ogawa, H. Radiation image conversion panel and method of manufacturing radiation image conversion panel. United States Patent 6,744,056 B1 (2004)
    [34] Fukui, S., Suzuki, H., and Saito, H. Radiation image storage panel. United States Patent 2005/0211917 A1 (2005)
    [35] Hagiwara, K., Wakamatsu, H., and Ito, N. Radiation image conversion panel United States Patent 7,372,046 B2 (2008)
    [36] Wakamatsu, H., and Nabeta, H. Preparation method of rare earth activated alkaline earth metal fluorohalide stimulable phosphor precursor, rare earth activated alkaline earth metal fluorohalide stimulable phosphor and radiographic image conversion panel. United States Patent 7,422,705 B2 (2008)
    [37] Hagiwara, K. Rare earth activated alkaline earth metal fluorohalide stimulable phosphor and radiation image conversion panel employing the same. United States Patent 2009/0039287 A1 (2009)
    [38] Matsumoto, H. and Suzuki, H. Stimulable phosphor sheet for double-side reading system. United States Patent 6,344,657 B1 (2002)
    [39] Arakawa, S., Miyahara, J., and Takahashi, K. Radiation image storage panel. United States Patent 4,800,136 (1989)
    [40] Seibert, J. A. Acceptance testing and quality control of photostimulable storage phosphor imaging systems. American Association of Physicists in Medicine REPORT NO. 93 (2006)
    [41] Liu, T. J. Fully developed flow of power-law fluids in ducts. Ing. Eng. Chem. Fundam. 22, 183-186 (1983)
    [42] Liu, T. J., and Hong, C. N. The pressure drop/flow rate equation for non-newtonian flow in channels of irregular cross-section. Polymer Engineering and Science 28, 1559-1564 (1988)

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