研究生: |
古博仁 |
---|---|
論文名稱: |
苯駢菲衍生物暨蒽菎衍生物在有機電致發光元件上之應用 Application of Pyrene Derivatives and Anthraquinone Derivatives in Organic Electroluminescent Devices |
指導教授: | 鄭建鴻 |
口試委員: | |
學位類別: |
博士 Doctor |
系所名稱: |
理學院 - 化學系 Department of Chemistry |
論文出版年: | 2005 |
畢業學年度: | 94 |
語文別: | 中文 |
中文關鍵詞: | 苯駢菲 、蒽菎 、藍光材料 、主發光體材料 、螺旋體結構化合物 |
外文關鍵詞: | Pyrene, Blue-emitting materials, Host materials, Spiro compound |
相關次數: | 點閱:106 下載:0 |
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P1-P6是以Suzuki coupling合成的苯駢菲(Pyrene)衍生物,是相當不錯的藍光材料。P1-P6的熔點在320~450 ℃,P2是唯一可測得Tg(133℃)與Tm(215 ℃)的化合物。螢光放光約在450 nm,元件ITO/NPB or TPD/P1 or P2/TPBI/Mg:Ag的效率已逼近螢光外部量子效率的理論值,可達4.8 %,CIE值也接近CRT標準的純藍色(0.14, 0.09),元件的啟動電壓甚少會超過3.5 V,元件在高電壓之下,能夠保持光色的純度。
蒽菎(Anthraquinone)的衍生物SP1-SP7,結構為spiro形式,用途作為元件中的主發光層材料,HOMO接近6.0 eV,HOMO-LUMO能階差大於3.0 eV,我們以綠色磷光材料pbi2Ir(pytz)、Irppy3及紅色磷光材料BJ-9(mepp2Ir(acac))作為客發光體,元件ITO/TCTA(30 nm)/dopant(5 %):SP1-SP7(30 nm)/BCP(10 nm)Mg:Ag以SP1最適合作為Host,但是與常用的CBP所做成的元件在效率上仍有不及之處。
將P1及P2應用在白光元件的製作也有不錯的成果,元件4j,外部量子效率與電流密度關係圖電壓6-12伏特時元件光色較為一定,電壓上升,光色即偏紅,外部量子效率在11伏特時達2.9 %,CIE = (0.32, 0.34),最大亮度在14.5伏特時達49002 cd/m2最佳電流效率6.9 cd/A(11 V),最佳能量效率2.3 lm/W(8 V),顏色也非常接近白光。
P1-P6 derivatives are synthesized via Suzuki coupling reaction.Melting points of materials are between 320~450 ℃detected by DSC,and P2 is the only one having Tg (133℃)and Tm(215 ℃). Fluorescence's maxium wavelenth is 450 nm,external quantum efficiency of device: ITO/NPB or TPD/P1 or P2/TPBI/Mg:Ag, almost is 4.8 %, and CIE(0.15, 0.09) is closer to standard value of blue CRT (0.14, 0.09). Starting voltage is less than 3.5 V
Anthraquinone derivatives SP1-SP7 have spiro structure designed for host materials.HOMO is closer to 6.0 eV.Energy gap is larger than 3.0 eV.We use green phosphorescent material pbi2Ir(pytz)、Irppy3, and red phosphorescent material BJ-9(mepp2Ir(acac) as dopant, device ITO/TCTA(30 nm)/dopant(5 %):SP1-SP7(30 nm)/BCP(10 nm)Mg:Ag has the best efficiency when host is SP1.
P1P2can be used to make white OLED material.Device 4j can maintain steady white light between 6-12 V. External quantum efficiency is 2.9 %(11 V), CIE(0.32, 0.34), and max luminescence is 49002 cd/m2(14.5 V), current efficiency 6.9 cd/A, power efficiency 2.3 lm/W(8 V).
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