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研究生: 胡耀仁
Hu, Yao-Jen
論文名稱: 低溫壁面對H2/O2層流預混火焰之冷卻效應
The Quenching Effect of Cold Walls on Steady Laminar Premixed H2/O2 Flame
指導教授: 王訓忠
Wong, Shwin-Chung
口試委員:
學位類別: 碩士
Master
系所名稱: 工學院 - 動力機械工程學系
Department of Power Mechanical Engineering
論文出版年: 2000
畢業學年度: 88
語文別: 中文
論文頁數: 57
中文關鍵詞: 冷卻效應低溫壁面H2/O2層流預混火焰一步驟化學反應詳細化學反應
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  • 本研究是以數值方法來模擬低溫壁面對穩態層流氫氧預混火焰之冷卻效應。將問題簡化為二維直角座標,當火焰接觸到低溫的固態表面時會產生冷卻熄滅的現象而造成燃燒上的不完全,其中氣相化學反應分別就一步驟反應和詳細化學反應兩方面來探討,文中同時模擬了在不同的進口速度和平板間距下,低溫壁面對流場的冷卻效應。從模擬所得結果發現,一步驟反應在低溫下的模擬與實際情形並不相符,低溫壁面對於H2、O2和H2O等組份在流場中的分佈並無太大的影響;以詳細化學反應模擬時,則很明顯的,組份在低溫壁面與平行板對稱軸附近的高溫區部分的分佈有明顯不同,在高溫區化學反應較完全,低溫區則有較多反應不完全的殘餘物質,同時這些殘餘物質在壁面上因累積而再次發生反應,產生了類似擴散火焰的次高溫反應區。以詳細化學反應模擬時,不同的進口速度會使火焰面固定在不同的位置,不會因進口速度大於火焰速度而造成火焰吹熄,這是因為邊界層的低速流場對於火焰有穩定作用。而平板間距在小於一特定值後,任何的流場條件都無法引燃氣體。


    圖表目錄 ii 符號說明 v 第一章 緒論 1 1.1 引言···················· ·1 1.2 文獻回顧·················· ·1 1.3 研究目的·················· ·5 第二章 理論模式 7 2.1 問題描述············ ····7 2.2 數學模式·········· ······7 2.3 數值方法與計算程序 ···········11 2.4 熱物理性質與H2/O2化學反應機制的決定···17 第三章 結果與討論 20 3.1 無擴散對流之化學反應 ··········20 3.2 一步驟化學反應和詳細化學反應 對低溫壁面之冷卻效應 ··········22 3.3 火焰面位置 ···············24 3.4 平板間距對火焰冷卻效應的影響 ······25 第四章 結論 27 參考文獻 28 圖一(a)、冷卻效應類型示意圖············30 圖一(b)、平板流之物理模型示意圖··········30 圖二、模型之程式計算流程圖 ············31 圖三(a)、無擴散對流之一步驟化學反應( ) 溫度對時間之分佈圖 ········ ···32 圖三(b)、無擴散對流之一步驟化學反應( ) 莫耳分率對時間之分佈圖··········33 圖四(a)、無擴散對流之詳細化學反應( ) 溫度對時間之分佈圖············34 圖四(b)、無擴散對流之詳細化學反應( ) 莫耳分率對時間之分佈圖··········35 圖四(c)、無擴散對流之詳細化學反應( ) 莫耳分率對時間之分佈圖··········36 圖四(d)、無擴散對流之詳細化學反應( ) 莫耳分率對時間之分佈圖··········37 圖五(a)、一步驟化學反應之等溫線圖(進口速度250cm/s,平板間距 1cm, , ) · ··············38 圖五(b)、一步驟化學反應組份O2之等量線圖(進口速度250cm/s, 平板間距1cm, , ) ········ ···39 圖五(c)、一步驟化學反應組份H2之等量線圖(進口速度250cm/s, 平板間距1cm, , ) ········ ···40 圖五(d)、一步驟化學反應組份H2O之等量線圖(進口速度250cm/s, 平板間距1cm, , ) ····· ······41 圖五(e)、一步驟化學反應組份H2O莫耳生成率(mole/cm3sec)之等量 線圖(進口速度250cm/s,平板間距1cm, , ) ················ ·····42 圖六(a)、詳細化學反應步驟之等溫線圖(進口速度250cm/s,平板間 距1cm, , ) ··········· ···43 圖六(b)、詳細化學反應步驟組份O2之等量線圖(進口速度250cm/s, 平板間距1cm, , ) ·········· ·44 圖六(c)、詳細化學反應步驟組份H2之等量線圖(進口速度250cm/s, 平板間距1cm, , ) ·········· ·45 圖六(d)、詳細化學反應步驟組份H2O之等量線圖(進口速度250cm/s, 平板間距1cm, , ) ············46 圖六(e)、詳細化學反應步驟組份HO2之等量線圖(進口速度250cm/s, 平板間距1cm, , ) ············47 圖六(f)、詳細化學反應步驟組份H2O2之等量線圖(進口速度250cm/s, 平板間距1cm, , ) ············48 圖六(g)、詳細化學反應步驟組份OH之等量線圖(進口速度250cm/s, 平板間距1cm, , ) ············49 圖六(h)、詳細化學反應步驟組份O之等量線圖(進口速度250cm/s, 平板間距1cm, , ) ·········· ·50 圖六(i)、詳細化學反應步驟組份H之等量線圖(進口速度250cm/s, 平板間距1cm, , ) ·········· ·51 圖六(j)、詳細化學反應組份H2O莫耳生成率(mole/cm3sec)之等量線 圖(進口速度250cm/s,平板間距1cm, , ) ················· ····52 圖七、一步驟化學反應之等溫線圖(進口速度300cm/s,平板間距 1cm, , ) ······· ·········53 圖八、一步驟化學反應之等溫線圖(進口速度250cm/s,平板間距 0.2cm, , ) ············ ···54 表一、各組份之 Lewis number ···· ·······55 表二、Curvefit coefficients for··········56 表三、詳細氫氧化學反應機制 ············57

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