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研究生: 林鈺孝
Lin, Yu-Xiao
論文名稱: 探討於超重力旋轉床中添加無機鹽類對二氧化碳及氧氣吸收之影響
Effects of Inorganic Salts On Absorption of Carbon Dioxide and Oxygen in a Rotating Packed Bed
指導教授: 談駿嵩
Tan, Chung-Sung
口試委員: 陳郁文
賴慶智
學位類別: 碩士
Master
系所名稱: 工學院 - 化學工程學系
Department of Chemical Engineering
論文出版年: 2013
畢業學年度: 101
語文別: 中文
論文頁數: 83
中文關鍵詞: 二氧化碳捕獲超重力旋轉床氧氣吸收無機鹽類化學吸收
外文關鍵詞: CO2 Capture, Rotating Packed Bed, Oxygen Absorption, Inorganic Salts, Chemical Absorption
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  • 氧氣裂化吸收劑會增加化學吸收法之操作成本,文獻上多以Na2SO3做為氧氣抑制劑,然而,其具有需補充及清除副產物之問題。本研究以添加無機鹽類之方式,降低氧氣在吸收劑中之飽和溶解度,進而降低吸收劑之溶氧量。由於無機鹽類之添加屬於物理抑制,因此沒有補充鹽類或是去除副產物之必要。
    由CO2捕獲實驗結果可知,本研究所添加的四種無機鹽類(KCl、NaCl、LiCl及LiBr),在相同濃度下(1.5 m)因受到Salting-out Effect及Salt Effect之影響,使CO2 Capture Efficiency有0.29%-9.70%之降幅,其中以KCl影響最小。由溶氧量量測結果可知,添加1.5 m之KCl於15% PZ/15% DETA中可使吸收劑之飽和溶氧量降低32.2%。
    以反應曲面法對氣體流率、溫度及KCl濃度等三個因子進行分析,結果顯示,氣體流率為影響CO2 Capture Efficiency之最顯著因子,其次為溫度及KCl濃度;而溫度為影響DO Value之最顯著因子,其次為氣體流率及KCl濃度。由Regression Model計算所得之最佳操作條件下,吸收劑DO Value較未添加鹽類之配方降低46.6%,較添加Na2SO3之配方降低10.1%。證明添加無機鹽類進行氧氣抑制具有其可行性,同時,RPB之HTU為0.02 (m)遠低於傳統填充塔之3.4 m,證明以化學吸收法搭配RPB進行CO2吸收,能有效縮減設備體積。
    理論再生能耗計算之結果顯示,含鹽配方受到蒸氣壓及比熱下降之影響,在蒸發熱及顯熱部分較不含鹽配方降低5%,可視為此吸收劑配方額外之優點。


    摘要 3 目錄 4 圖目錄 6 表目錄 7 第一章 緒論 9 第二章 CO2捕獲製程介紹 13 2-1 CO2捕獲技術 13 2-1.1 Pre-Combustion Carbon Capture 13 2-1.2 Oxy-Combustion Carbon Capture 14 2-1.3 Post-Combustion Carbon Capture 15 2-2 CO2分離技術 15 2-2.1 物理吸收法 16 2-2.2 物理吸附法 16 2-2.3 薄膜分離法 17 2-2.4 低溫冷凝法 17 2-3 化學吸收法 18 2-3.1 吸收劑介紹 19 2-3.2 吸收劑裂化 24 2-4 超重力技術 27 第三章 實驗方法 29 3-1 實驗裝置 29 3-1.1 CO2捕獲實驗 29 3-1.2 吸收劑溶氧量量測實驗 29 3-2 儀器校正 30 3-3 實驗步驟 30 3-3.1 CO2捕獲實驗 30 3-3.2 吸收劑溶氧量量測實驗 31 3-4 實驗藥品 32 3-5 數據處理 32 3-6 反應曲面法 33 第四章 實驗結果 37 4-1 文獻回顧 37 4-2 實驗結果討論 39 第五章 結論 65 第六章 參考文獻 67 第七章 符號說明 79 附錄 80

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