簡易檢索 / 詳目顯示

研究生: 曹國勝
Kuo-Sheng Tsao
論文名稱: mCOC微結構對mCOC-SiO2奈米粒子混成材料的影響
指導教授: 李育德
口試委員:
學位類別: 碩士
Master
系所名稱: 電機資訊學院 - 光電科技產業研發碩士專班
Interdisciplinary Program of Engineering
論文出版年: 2007
畢業學年度: 95
語文別: 中文
論文頁數: 88
中文關鍵詞: COCSiO2奈米粒子
相關次數: 點閱:1下載:0
分享至:
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報
  • 本研究乃針對光學塑膠材料環烯烴共聚物(Cycloolefin copolymer, COC),探討其分子微結構在COC材料加入二氧化矽(Silica)後對高分子性質的影響。由於COC在結構組成上的些微差異,造成混摻材料在光學性質與熱性質以及機械性質上有著不同的變化,這些變化其實都與COC與Silica間的相容性有著很大的關聯性。


    摘要 1 誌謝 2 目錄 3 第一章 緒論 5 1-1 聚環烯烴材料之平面顯示器應用......................6 1-2 mCOC材料之平面顯示器塑膠基板應用..................7 第二章 文獻回顧 9 2-1 COC材料之特性.................................10 2-2 二氧化矽(Silica)之特性........................26 2-3 高分子奈米複合材料之特性......................30 2-4 COC材料之特性與差異...........................41 第三章 研究動機與架構 44 3-1 研究動機......................................44 3-2 研究架構......................................45 第四章 實驗藥品、設備及實驗步驟 46 4-1 實驗藥品......................................46 4-2 實驗設備......................................47 4-3 實驗步驟......................................48 第五章 實驗結果與討論 49 5-1 Silica分析鑑定...................................49 5-1-1 粒徑分析....................................49 5-1-2 熱裂解氣相層析質譜儀 PGC/MS.................50 5-2 微結構........................................53 5-2-1 SEM圖.......................................53 5-3 光學性質分析..................................59 5-3-1 霧度計 Haze meter...........................59 5-3-2 UV-Vis光譜儀................................61 5-3-3 折射率......................................65 5-4 熱性質分析....................................66 5-4-1 熱重分析儀 TGA..............................66 5-4-2 微差掃描熱卡計 DSC..........................70 5-4-3 熱機械分析儀 TMA............................75 5-5 機械性質......................................79 5-5-1 拉力測試....................................79 第六章 結論 84 第七章 參考文獻 86

    1.蕭柏齡,工業材料雜誌,210,174(2004)
    2.蔡金津,化工技術,12,105(2004)
    3.Zeon Chemicals L.P.,Japan(on the web:http://www.zeon.co.jp)
    4.JSR Corporation,Japan(on the web:http://www.jsr.co.jp/jsr_e/)
    5.Ticona Engineering Polymers,German(on the web:http://www.ticona.com/redesign/)
    6.J. Y. Shin, J. Y. Park, Chen Y. Liu, J. S He, and S. C. Kim, “Chemical Structure and Physical Properties of Cyclc Olefin Copolymers”, IUPAC, Pure and Applied Chemistry, 77, 801(2005)
    7.R. Mulhaupt, “Catalytic Polymerization and Post polymerizaton Catalysis Fifty YearsAfter the Discovery for Ziegler’s Catalysts”, Macromol. Chem. Phys, 204, 289(2003)
    8.W. kaminsky, A. Laban, Applied Catalyst A: General 222(2001)47-61”Metallocene Catalyst”
    9.George Odian, Princioles of polymerization, 4rd Ed, Wiley Interscience, 2004, 666-673.
    10.Michael Arndt, Inken Beulich, “C1-symmetric metallocenes for olefin polymerisation, 1Catalytic performance of [Me2C(3-tertBuCp)(Flu)]ZrCl2 in ethene/norbornene copolymerisation”, Macromol. Chem. Phys. 199, 1221–1232 (1998)
    11.J. F. Forsyth, T. Scrivani, R. Benavente, C. Marestin, J.M. Perena, “Thermal and Dynamic Mechanical Behavior of Ethylene- Norbornene Copolymers with Medium Norbornene Contents” , Journal of Applied Polymer Science, Vol. 82, 2159–2165 (2001)
    12.J. Forsyth, R. Benavente, E. Perez, I. Tritto, L. Boggioni, H.H. Brintzinger, “Influence of the Polymer Microstructure on the Thermal Properties of Cycloolefin Copolymers with High Norbornene Contents”, Macromol. Chem. Phys. 2001, 202, 614–620
    13.B.A. Harrington, and D.J. Crowther, “Stereoregular, alternating ethylene–norbornene copolymers from monocyclopentadienyl catalysts activated with non-coordinating discrete anions”, Journal of Molecular Catalysis A : Chemical, 128, 79(1998)
    14.H.H. Shih, P.L. Shiao, H.C. Hsu, H.J. Liu, C.J. Huang, C.C.Tsai, “Effects of Microstructures on the Viscoelastic and Rheological Properties of Metallocene-Catalyzed Cyclo-Olefin Copolymers- A Preliminary Study”, Journal of Applied Polymer Science, Vol. 86, 3695–3701 (2002)
    15.T.Rische, A.j. Waddon, L.C. Dickinsion, W.J. Marknight, “Microstructure and Morphology of Cycloolefin Copolymers”, Macromolecules, 31, 1871-1874, 1998
    16.蔡宏欣,有機高分子包覆無機二氧化矽奈米次微米級複合乳膠顆粒的置備,台大化工所碩士論文(2002)
    17.陳嘉甫,二氧化矽聚苯乙烯聚苯胺核殼型態複合乳膠顆粒之製備及性質研究,台大化工所碩士論文(2002)
    18.鄭舜宇,以溶膠凝膠法合成高分子基氧化矽複合材料之研究,中山大學材料所碩士論文(2001)
    19.T. Jesionowski, A. Krysztafkiewicz, Applied Surface Science, 172, 18-32(2001)
    20.A. Krysztafkiewicz, T. Jesionowski, S. Binkowski, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 173, 73-84(2000)
    21.S. Hayashi, K. Fujiki, N. Tsubokawa, Reactive and Functional Polymers, 46, 193-201(2000)
    22.M. Kogut, K. C-K, Journal of Non-Crystalline Solids, 287, 10-14(2001)
    23.F. Mammeri, E. Le Bourhis, L. Rozes, C. Sanchez, “Elaboration and mechanical characterization of nanocomposites thin films Part I: Determination of the mechanical properties of thin films prepared by in situ polymerisation of tetraethoxysilane in poly(methyl methacrylate)”, Journal of the European Ceramic Society 26 (2006) 259–266
    24.H. Sugimoto, K. Daimatsu, E. Nakanishi, Y. Ogasawara, T. Yasumura, K. Inomata, “Preparation and properties of poly(methylmethacrylate)–silica hybrid materials incorporating reactive silica nanoparticles”, Polymer xx (2006) 1–6
    25.G.H. Hsiue, W.J. Kuo, Y.P. Huangb, R.J. Jeng, “Microstructural and morphological characteristics of PS–SiO2 nanocomposites”, Polymer 41, 2813–2825 (2000)
    26.J.S. Im, J.H. Lee, S.K. An, K.W. Song, N.J. Jo, J.O. Lee, K. Yoshinaga, “Preparation and Properties of Polyimide/Silica Hybrid Composites Based on Polymer-Modified Colloidal Silica”, Journal of Applied Polymer Science, Vol. 100, 2053–2061 (2006)
    27.Z.D. Wang, J.J. Lua, Y. Lib, S.Y. Fu, S.Q. Jiang, X.X. Zhao, “Low temperature properties of PI/SiO2 nanocomposite films”, Materials Science and Engineering B 123, 216–221 (2005)
    28.張智桀,新型光學塑膠(COC)之不同為結構混摻後光學特性探討,清華大學化工所碩士論文(2006)
    29.C.Y. Liu, J. Yu, X.H. Sun, J. Zhang, J.S. He, “Thermal degradation studies of cyclic olefin copolymers”, Polymer Degradation and Stability 81 (2003) 197–205

    無法下載圖示 全文公開日期 本全文未授權公開 (校內網路)
    全文公開日期 本全文未授權公開 (校外網路)

    QR CODE