研究生: |
王淳楷 Wang, Chun-Kai |
---|---|
論文名稱: |
鐵鈀金三元鐵磁性記憶合金塊材研究 |
指導教授: |
胡塵滌
Hu, Chen-Ti |
口試委員: |
吳錫侃
楊聰仁 |
學位類別: |
碩士 Master |
系所名稱: |
工學院 - 材料科學工程學系 Materials Science and Engineering |
論文出版年: | 2011 |
畢業學年度: | 99 |
語文別: | 中文 |
論文頁數: | 117 |
中文關鍵詞: | 鐵磁性形狀記憶合金 、麻田散相變化 、磁伸縮 、形狀記憶效應 |
外文關鍵詞: | Ferromagnetic shape memory alloy, Martensitic transformation, Magnetostriction, Shape memory effect |
相關次數: | 點閱:2 下載:0 |
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本研究探討熱鍛、熱輥壓與熱機處理後Fe70Pd30-XAuX(X=3,5,7)塊材試片其微結構、相變化溫度、磁性質、磁伸縮值、形狀記憶效應、織構的變化。
用熱輥壓製備AuX(X=0,3,5,7)塊材試片,發現添加Au可改善試片抗氧化性與塑性變形能力,減少熱輥壓產生的裂紋。在冷輥過程中發現Au5(1)- TMT2試片具有177.33%的長度變化,初步推測原因為試片母相結構為非序化 fcc結構,添加Au更增加傾向類似Au的巨大塑性變形能力,其中機制待更進一步研究。
熱機處理後的AuX-TMT1(X=3,5,7)塊材試片中Au5(1)-TMT1、Au7-TMT1在室溫下結構為熱彈性fct麻田散相,顯示添加Au可提升相變化溫度,以添加5% Au效果最好可提升Ms約30K,得到最低晶格常數比值(c/a)為0.93。各試片降至液態氦溫度4K仍不會產生非熱彈性bct麻田散相,顯示添加Au能有效抑制bct生成。
室溫飽和磁化量以Au3-TMT1最高,Au5(1)-TMT1最低,矯頑磁場變化趨勢則相反;磁伸縮值上,θ=90o時的最大磁伸縮值隨Au含量增加而上升。
形狀記憶效應方面,成份相同的Au5試片,形狀回復率隨試片厚度增加而升高。不同成份的Fe70Pd(30-x)AuX試片在近似厚度下,各塊材試片形狀記憶回復率大致相同。
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