研究生: |
朱英豪 Ying-Hao Chu |
---|---|
論文名稱: |
Ba(Mg1/3Ta2/3)O3緩衝層利用於低溫成長Pb(Zr1-xTix)O3薄膜之研究 Study on Ba(Mg1/3Ta2/3)O3 Buffer Layer for Low Temperature Deposition of Pb(Zr1-xTix)O3 Thin Films |
指導教授: |
劉國雄
Kuo-Shung Liu 林諭男 I-Nan Lin 林樹均 Su-Jien Lin |
口試委員: | |
學位類別: |
博士 Doctor |
系所名稱: |
工學院 - 材料科學工程學系 Materials Science and Engineering |
論文出版年: | 2004 |
畢業學年度: | 92 |
語文別: | 中文 |
論文頁數: | 288 |
中文關鍵詞: | 雷射製程 、PZT 、BMT 、薄膜體聲波元件 、鐵電 、微波介電 、光學特性 |
外文關鍵詞: | Laser Process, PZT, BMT, FBAR, Ferroelectric, Microwave Dielectric, Optical Properties |
相關次數: | 點閱:1 下載:0 |
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Pb(Zr1-xTix)O3 (PZT)材料具有多項優異特性,適合發展很多功能性之元件。但是要將PZT材料開發於元件應用時,會遭遇許多材料問題,比如與Si基板擴散問題、與金屬電極之接面問題,還有最重要之製程溫度問題,如果沒有辦法同時解決目前存在之這些問題,這將使得PZT元件於開發上受到很大之限制,而無法實用化。本研究以材料製程為開發重點,利用BMT材料結構與晶格常數與PZT匹配以及可於低溫合成之優點,積極開發BMT為PZT材料緩衝層。同時由於BMT本身為最優良之微波介電薄膜,開發過程同時利用微波探針系統(EMP),量測(100)優選BMT薄膜之微波介電特性(K=22.0 & tanδ=0.0043)。
接下來利用低溫雷射剝鍍製程,搭配BMT緩衝層之使用,解決了PZT材料與Si基礎基板之交互擴散問題,由於PZT材料之成長完全依賴PZT,因此透過製程參數之調變,探討BMT結晶性與表面形貌對於PZT薄膜成長之影響,並透過TEM之分析建立PZT材料於BMT材料上成長之模型,同時藉由C-V之量測Pt/PZT/BMT/Si結構,可以在400℃製程溫度之薄膜,得到8.0 V之記憶窗。同時間PZT材料與金屬電極介面會產生之鐵電疲勞問題,本研究亦利用BMT緩衝層隔開PZT與金屬之間之接觸形成,BMT/PZT/BMT三明治結構,可以在400℃製程溫度開發出Pr=29.7 μC/cm2與EC=82.5之優良鐵電薄膜,同時經過鐵電疲勞測試,鐵電特性經過1011次之測試,仍不會有下降之趨勢,使得PZT材料更接近於鐵電記憶體之應用。
同時利用製程參數之調整在Sapphire基板上低溫合成高品質(100)之PZT薄膜。如此高品質之薄膜,可以應用於表面聲波元件,更可利用PZT之非線性特性,開發成為可調頻之微波元件,以及PZT之聲光或電光效應,開發成為光學主動元件。為了確定應用之可行性,本研究亦對高品質之PZT薄膜進行微波介電特性(K=105.9 & tanδ=0.0121)與光學特性(n=2.30 & β=2.46 dB/cm)之量測。
為了使PZT高品質薄膜更貼近應用,不受成長基板之限制,積極開發雷射剝離技術,將PZT薄膜成功由sapphire成長基板轉移至Si應用基板,並保持其良好之鐵電特性(Pr=34.4 μC/cm2、EC=360 kV/cm)。同時亦利用低溫雷射剝鍍技術開發數種PZT材料之之奈米粉末與奈米柱,提供PZT材料應用於奈米領域更多形式之選擇。
目前無線通訊射頻前端之線路尺寸,主要受到高頻被動元件所主宰,所以高頻被動元件之微小化,乃為射頻前端線路縮小之主要關鍵,配合單石式微波積體電路之電路設計,才能達到單一系統晶片與降低成本之目標。目前主動元件主要利用薄膜技術來製作,因此高頻被動元件之薄膜化為此一趨勢成敗之關鍵。薄膜體聲波元件具有可整合與尺寸小之優點,為目前最熱門之開發元件。PZT材料應用於體聲波薄膜共振器,具有高機電耦合係數特性,可作為寬頻濾波器上之應用,是十分具有潛力的材料。
最後本研究建立PZT薄膜體聲波元件之分析基礎,透過適當之元件設計與製作流程,將之前400℃製程低溫開發之PZT/BMT薄膜整合於製程中,可以開發出PZT薄膜體聲波元件之雛形,透過製程之檢定,確定解決PZT薄膜應用於元件之材料問題。
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