本研究探討BaO對BaO-ZnO-B2O3玻璃系統性質的影響以及添加BaO-ZnO-B2O3玻璃對BaTi4O9粉末燒結的影響。隨著玻璃成分BaO的量增加，BaO-ZnO-B2O3玻璃的軟化點（Ts）、結晶溫度（Tcr）與熔點（Tm）隨之降低。而BaO-ZnO-B2O3玻璃經熱處理後，形成的結晶相由Zn3B2O6和Zn4B6O17變成Ba4B2O7、Ba2B2O5與Ba2B10O17。此外，BaO-ZnO-B2O3玻璃的介電常數隨著玻璃成分BaO的量增加而提高。
玻璃成分BaO明顯改善BaO-ZnO-B2O3玻璃與BaTi4O9的潤濕情況。但添加BaO-ZnO-B2O3玻璃的燒結緻密度卻隨著玻璃成分BaO的量增加而降低。其原因在於BaO-ZnO-B2O3玻璃與BaTi4O9的燒結系統屬於反應燒結，而在燒結過程中玻璃成分BaO的存在會抑制BaO-ZnO-B2O3玻璃與BaTi4O9間的固相反應，以致於燒結緻密度降低。

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