本研究針對粒子對擴大淋幕式塗佈視窗之機制進行探討。實驗塗液系統是分別將不同粒徑的聚甲基丙烯酸甲酯(PMMA)粒子、二氧化矽(SiO2)與親水性及疏水性的二氧化鈦(TiO2)加入在甘油水溶液內，使其形成分散良好的懸浮液，再進行塗佈實驗。結果顯示除了疏水性粒子外，添加粒子均能減緩空氣滲入發生，提升最大塗佈速度。對此現象我們提出了一個理論來說明，即親水性粒子在水含量較少的溶液中，會容易往液氣介面的部分脫離，擠壓滲入的空氣層，穩定其動態濕潤線來延後缺陷發生，而達到提高最大塗佈速度的效果。經由分光光譜儀的檢測，發現在溶液的液泡中，粒子濃度皆比溶液中來的高，與理論預測相同，表示粒子具有往表面移動的的行為。在雙層淋幕式塗佈系統中，發現添加粒子在攜帶層塗液可提升最大塗佈速度，而添加於上層塗液中並無效果。

[1]. Brown, D.R. (1961). “A Study of the Behavior of thin sheet of Moving Liquid ’’, Journal of Fluid Mechanics 10,297-303.
[2]. Lin, S.P. (1981). “Stability of a Viscosity Liquid Curtain’’, Journal of Fluid Mechanics 104,111-118.
[3]. Kistler, S. F. (1983). “The Fluid Mechanics of Curtain Coating and Related Viscous Free Surface Flow with Contact Lines’’, PhD Thesis, pp. 414–421, Univ. of Minnesota.
[4]. Finnicum, D. S., Weinstein, S. J. and Ruschak, K. J. (1993). “The Effect of Applied Pressure on the Shape of a Two-dimensional Liquid Curtain Falling under the Influence of Gravity”, J. Fluid Mech. 255, 647-665
[5]. Hughes, D.J. (1970). ” Method for Simultaneously Applying a Plurality of Coated Layers by Forming a Stable Multilayer Free-Falling Vertical Curtain”, US Patent 3,508,947.
[6]. Reiter T.C. (1989). ’’Curtain Coating Method and Apparatus”, US Patent 4,830,887.
[7]. Schweizer, P., Krebs, F. (2007). ”Curtain coater and curtain coating method ”, US Patent 2007013753.
[8]. Kistler, S. F. and Scriven L. E. (1984). “Coating Flow Theory by Finite Element and Asymptotic Analysis of the Navier-Stokes System”, International Journal for Numerical Methods in Fluids 4, 207-229.
[9]. Blake, T. D., Clarke A. and Ruschak K. J. (1994). “Hydrodynamic Assist of Dynamic Wetting”, AIChE Journal 40, 229-242.
[10]. Blake, T. D., Dobson R. A. and Ruschak K. J. (2004). “Wetting at high capillary numbers”, Journal of Colloid and Interface Science 279, 198-205
[11]. Kistler, S.F., Schweizer, P.M., (Eds.), (1997). “ Liquid Film Coating”, Chapman & Hall, London
[12]. Buonopane, R.A., Gutoff, E.B. and Rimore, M.M.T. (1986). “Effect of. Plunging Tape Surface Properties on Air-Entrainment Velocity”, AIChE Journal 32, 682-683.
[13]. Blake, T. D., and Ruschak K. J. (1997). “Wetting: Static and Dynamic Contact Lines”, Liquid Film Coating, S. F. Kistler and P. M. Schweizer, Editors, Chapmans Hall, London.
[14]. Clarke, A. (2002). “Coating on a Rough Surface”, AIChE Journal 48, 2149-2156.
[15]. Benkreira, H. (2004). “The effect of substrate roughness on air entrainment in dip coating”, Chemical Engineering Science 59, 2745.
[16]. Deryagin, B.V. and Levi, S.M., (1964). Film Coating Theory, The Focal Press, London.
[17]. Burley, R. and Kennedy, B.S., (1976). “An Experimental Study of Air Entrainment at a Solid/Liquid/Gas Interface”, Chem. Eng. Sci., 31, 901-911.
[18]. Gutoff, E.B. and Kendrick, C.E., (1987). “Low Flow Limits of Coatability on a Slide Coater”, AIChE Journal, 33, 141-145.
[19]. Macosko, C.W. (1994). “Rheology：Principles Measurements and Applications”, Wiley-VCH Publishers, New York.
[20]. Liang, G.G. and Hawkett, B.S. (2005). “The Determination of the Isoelectric Point from Measurements of Dispersion Viscosity as a Function of pH”, Journal of Dispersion Science and Technology 26, 469-472.
[21]. Chibowski. (2001). “Studies of the Influence of Acetate Groups from Polyvinyl Alcohol on Adsorption and Electrochemical Properties of the TiO2-Polymer Solution Interface”, Journal of Dispersion Science and Technology 22, 281-289.
[22]. Boisvert, J. P., Persello J. and Guyard A. (2003). “Influence of the Surface Chemistry on the Structural and Mechanical Properties of Silica-Polymer Composites”, Journal of Polymer Science 41, 3127-3138.
[23]. Eistein, A. (1906). ’’A New Determination of the Molecular dimension’’, Ann. Physik., 19, 289-306.
[24]. Mooney, M. (1951). ’’The Viscosity of a Concentrated Suspension of Spherical Particles ’’, Journal of Colloid and Interface Science 6,162-170.
[25]. Yamamura, M., Miura, H. and Kage, H. (2005). “Postponed Air Entrainment in Dilute Suspension Coatings”, AIChE Journal 51, 2171-2177.
[26]. M. Yamamura, A. Matsunaga, Y. Mawatari, K. Adachi, H. Kage. (2006). “Particle-assisted dynamic wetting in a suspension liquid jet impinged onto a moving solid at different flow rates” Chemical Engineering Science 61, 5421-5426.
[27]. 朱文彬, (2007). 含有機/無機粒子塗液於精密模具塗佈流動之分析, 國立清華大學化學工程研究所博士論文.
[28]. 林奕村, (2008). 懸浮液系統對模具塗佈行為的影響, 國立清華大學化學工程研究所碩士論文.
[29]. 石家榮, (2010). 雙層淋幕式塗佈之分析, 國立清華大學化學工程研究所碩士論文.
[30]. 章興國, (2011). 具有分散相的塗液在淋幕式塗佈之行為研究, 國立清華大學化學工程研究所博士論文.
[31]. 吳平耀, (2001). 電子與材料雜誌第12期, p148-150.