本論文共分兩個部分，第一階段利用本實驗室所開發的多段式燒結，及低溫燒結所產生的中間相，以三種不同的起始粉末配製兩種不同成分的Ni-Al-Fe介金屬化合物，並比較各組試片的機械性質。結果發現以純鎳、純鋁及純鐵粉為起始粉末的Ni-25Al-15Fe試片在經過兩次熱機處理後，可以到最佳的密度(98%)及最高的延展率(2.86%)。
第二階段則是以不同來源不同尺寸的四種鐵粉製作Fe3Al試片，並觀察不同試片在燒結過程中的釋氣現象，相反應變化，放熱峰曲線及物理性質。結果發現5μm鐵粉因為以carbonyl decomposition method製成，在低溫燒結時有大量氣體釋放的現象，而以10μm鐵粉所製作的試片，燒結時有最高的放熱溫度及較好的成品密度。

1.Gerhard Sauthoff in Intermerallics,pp.3
2.K.Aoki, O.Izumi,”Improvement in Room-Temperature Ductility of L12 Type Intermetallic Compound”,JIM,Vol.43,pp.1190-1196,1979
3.S.Guha,I,Baker,P.R.Munroe and J.R.Michael,”The Effect of Annealing on Ni-Al-Fe B2 Compounds”, Materials Science and Engineering A152,pp.258-263,1992
4.S.Guha ,P.Munroe and I,Baker,”Room Temperature Tensile Ductility in Polycrystalline B2 Ni-30Al-20Fe”,Scripta Metall,Vol.23,pp. 897-900, 1989
5. D.Golberg and A.Shevakin,Proc.of Advanced Materials,September 1-4,pp.865,Tokyo,Japan,1993
6. J.H.Yang and C.M.Wayman,”Training and Aging Effects on Shape-Memory Behavior in a 2-Phase Nialfe Alloy”,Materials Letters, Vol.16, pp.254,1993
7. E.P.George,C.T.Liu,J.A.Horton,C.J.Sparks,M.Kao,H.Kunsmann and T.King,”Characterization Processing and Alloy Design of NiAl-Based Shape-Memory Alloys”,Materials Characterization,Vol.32,pp.139,
1994
8. R.Kainuma,K.Oikawa and L.Ishida,Proc.of International Symposium and Exhibition of SMA,SMM-94,Beijing,china,September 25-28, pp.464,1994
9. K.Ishida,R.Kainuma,N.Uneo and T.Nishizawa,”Ductility Enhancement in NiAl-Base Alloys by Microstructural Control”, Metall. Trans,22A,
pp.441,1991
10. R.Kainunia,H.Nakano,K.Oikawa,K.Ishida ,”Thermoelastic Martensite and Shape Memory Effect in B2 Phase Ni-Al-Fe Alloy with enhanced Ductility”, Mat.Res.Symp.Proc.246,pp.403,1992
11. C.Y.Xei,B.H.Jiang and G.X.Hu,”3 Stage Yielding Phenomenon in a NiAl-Fe Alloy”,Scripta Metall.,31,pp.155,1994
12.H.G.Kunsuanm,J.W.Krou,T.J.Kuczkowski,C.T.Liu:Abstract Conf.of Materials Research Society,Fall,Boston,USA,403,1991
13. Z.G.Liu,J.T.Guo,L.Z.Zhou,Z.Q.Hu and M.Umemoto,”Mecjanical Alloying Synthesis and Structural Characterization of Ternary Ni-Al-Fe Alloys”, Journal of Materials Science, Vol 32, pp 4857-4864, 1997
14. E.Y.Gutmanas,O.B.Botstein and A.Lawley ,”Elevated Temperature Stability of Power Processed Al-Fe-Ni”, International Journal of Powder Metallurgy, Vol.36,pp.47-55,2000
15. C.G. Mckamey,J.H. Devan,P.F. Tortorelli,and V.K. Sikka J.Mater.
Res.,Vol.6,No.8,Aug1991,p1779□1805
16. 邱文智 博士論文 〝鎳鋁介金屬化合物及其複合材之粉末製程研究〞,1994
17. 陳江耀 碩士論文.〝鎳鋁介金屬化合物粉末冶金製程及記憶效應研究〞,1999
18. 吳瑞城 碩士論文 〝鐵鋁介金屬化合物粉末冶金製程之研究〞,1996
19. 康慧貞 碩士論文 〝鐵鋁介金屬化合物及其複合材研究,1998
20. Osamu Izumi 〝金屬間化合物〞pp.54□59,產業圖書株式會社,東京,日本（1988）.
21. Idem,ibid21,1992,pp.336□340.
22. Metal Handbook,10th edition.,Vol.2,pp.914,ASM,Ohio,USA(1990).
23. E.P. George and C.T. Liu,〝Brittle Fracture and Ductility Improvement in nickle and aluminides〞,Y Han (ed.),”Advanced Structural Materials”,pp.621-633,Elsevier Science Publishers,(1991).
24. D.Shechtman,M.J.Blackburn and H.A.Lipsitt,Metall.Trans.
,5(6),pp.1373,(1974).
25. MJ.Blackburn and M.P.Smith,〝R＆D on Composition and Processing of Titanium Aluminide Alloys for turbine engines〞（Report AFWAL-TR-82-4086,1982）
26. D.Banerjee,T.K.Nandy and A.K.Gogia,Scripta.Metall.,21,pp.597-600, (1987).
27. C.T.Liu,C.G.Mckamey and E.H.Lee,Scripta Metall.24,pp385（1990）
28. D.G. Morris and M. Leboeuf,Acta Metall.Mater.42,pp1817（1994）.
29. E.A.Feest and J.H.Tweed,”Comparative Viability of Processing Rotes for Intermetallic Based Materials”, Mat.Sci.Tech.., Vol.8,pp. 308-316, 1992
30. A.Taylor and N.J.Doyle,”Further Studies on the Nickel-Aluminum System.II.Vacancy Filling in and -Phase Alloys by Compression at High Temperature “,J.Appl.Cryst,Vol.5,pp.210-15,1972
31. C.T.Liu and K.S.Kumar,”Ordered Intermetallic Alloys Part I:Nickel and Iron Aluminides”, J.Mater.,pp.38-44,1993
32. R.T.Pascoe and C.W.Anewey,Phys.Status Solidi,29,pp.357,1968
33. E.M.Savitsky,G.S.Burchanov and I.M.Zalivin,Strength Problems
(USSR),11,pp.111,1972
34. S.Dymek,M.Dollar,S.J.Hwang and P.Nash,”Deformation Mechanism and Ductility of Mechanically Alloyed NiAl”,Materials Science and Engneering,A152,pp.160-65,1992
35. S.Nourbakhsh and P.Chen,”Microstructure and Mechanical-Properties of Rapidly Solidified and Annealed Ni-Al Intermetallic Alloys”,Acta Metall.,37,pp.1573,1989
36. S.M.Merchant and M.R.Notis,”A Review-Constitution of the Al-Cr-Ni System”,Mater.Sci.Eng.,Vol.66,pp.47-60,1984
37. J.Schramm:Z.metallkd.,Vol.33,pp.403-12,1941.
38. W.Koster,U.Zwicker and K.Moeller:Z. Metallkd.,Vol.39,225-31,1948
39. A.Inoue,T.Masumoto and H.Tomioka, Journal of Materials Science, Vol.16,p3097,1984
40. S.Guha ,P.Munroe and I,Baker,”Improving the Low Temperature Ductility Of NiAl”, Materials Research Society,Vol.133,pp.633-638, 1989
41. A.J.Duncan,M.J.Kaufman,C.T.Liu and M.K. Miller,”Site Occupation of Iron in Intermetallic NiAl”,Applied Surface Science,Vol.77,pp. 155-159,1994
42. ”PoederMetallurgy”,Metal Handbook,Vol.7,9th Edition by ASM,pp.92-93,1984
43.K.A. Philpot,Z.A. Munir and J.B.Holt ,”An Investigation of the Synthesis of Nickel Aluminides Through Gasless Combustion”,
Journal of Materials Science,Vol.22,pp.159-169,1987.
44.A.MiSRA and R.GIBALA”Room-Temperature Deformation Behavior of Directionally Solidified Nultiphase Ni-Fe-Al Alloys”,Metallurgical and Materials Transactions 28A,pp.795-807,1997