本研究藉由錫/銅/錫/鎳/錫/銅/錫反應偶，在200℃下分別進行48~1416小時之界面反應，探討錫中溶入微量鎳時對錫/銅界面反應之影響，以及錫中溶入微量銅時對錫/鎳界面反應之影響。實驗結果顯示：錫/銅界面反應部分，錫中微量鎳的添加，不會改變生成相的種類，但會減緩生成相的成長，甚至改變Cu3Sn相的成長機制。錫/鎳界面反應部分，錫中微量銅的添加，會減緩Ni3Sn4相的成長，在生成相種類方面，除了出現Ni3Sn4外，還會生成Cu6Sn5相。反應後，生成相的順序為Cu/Cu3Sn/Cu6Sn5/Sn/Cu6Sn5/Ni3Sn4/Ni。由擴散路徑發現，銅原子乃由濃度高至濃度低再往濃度高處擴散，此現象似乎不太合理，但若由熱力學角度切入，從化學勢梯度來進行討論，或許可合理解釋此現象，此為一未來可以繼續探討的方向。

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