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研究生: 陳璽人
Chen, Xi-Ren
論文名稱: 碳氣凝膠暨多壁奈米碳管對碳纖維補強高分子複合材料機械性質與環境效應特質之研究
Study on Mechanical Properties and Environmental Effects of Carbon Aerogel and Multi-Wall Carbon Nanotubes for Carbon Fiber Reinforced Polymer Composites
指導教授: 葉銘泉
Yip, Ming-Chuen
口試委員: 蔡宏營
葉維磬
學位類別: 碩士
Master
系所名稱: 工學院 - 動力機械工程學系
Department of Power Mechanical Engineering
論文出版年: 2012
畢業學年度: 100
語文別: 中文
論文頁數: 110
中文關鍵詞: 碳氣凝膠奈米碳管團聚機械性質複合材料
外文關鍵詞: Carbon aerogel, Carbon nanotube, Agglomeration, Mechanical properties, Composite
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  • 碳氣凝膠具有獨特的多孔奈米結構與高比表面積特性,對於增加高分子積層板的機械性質以及物理性質具有開發潛力。本研究使用不同含量的碳氣凝膠搭配固定含量的奈米碳管,在製程方面利用超音波震盪以及均質機攪拌來改善奈米碳材於複合材料之分散性。本研究旨在探討添加兩種奈米碳材的可行性。結果顯示碳氣凝膠對於環氧樹脂高分子複合材料的拉伸強度、衝擊強度、彎曲強度都隨著添加量增加而增加。在本研究中,旨在探討其於實際應用環境下的探討。結果顯示,碳氣凝膠於添加量為0.1wt%、0.2wt%有較佳的機械性質,當添加量增加時即會產生團聚現象。此外碳氣凝膠對於山區環境中具有良好的機械性質。實驗最後利用SEM觀測破壞斷面,藉此討論其介面情形和破壞機制。


    Carbon aerogels have promising potential in increasing the mechanical and physical properties of carbon-fiber reinforced polymer (CFRP) laminates as a result of the possession of a unique property of porous structure at nanoscale and high specific surface. This study used a fixed amount of CNT (1 wt%) mixed with a different proportion of carbon aerogel by using homogenizer and ultrasonication in process to improve the dispersion of carbon materials.
    The early stage of the study is aimed at investigating the possibility of adding two types of carbon materials in epoxy matrix. The experimental results indicate that the tensile properties, impact strength and flexural strength of epoxy matrix are proportional to the adding proportions. The later stage of the study is aimed at examining the changing conditions of carbon materials under a variety of environment effects. The experimental results specify that the overall mechanical properties are better when adding 0.1 wt% and 0.2wt% carbon aerogels, when increasing the amount will cause agglomeration. Furthermore, the overall mechanical properties of carbon aerogels are outstanding when in mountain regions.
    Morphologies of the fracture surface of the specimen are observed by scanning electron microscope (SEM) to examine and discuss its interface condition and fracture mechanism.

    摘要 I Abstract II 致謝 III 目錄 IV 表目錄 VIII 圖目錄 X 符號表 XIV 第一章 前言 1 第二章 研究目的與動機 3 2-1 研究動機 3 2-2 研究目的 4 第三章 文獻回顧 6 3-1 碳氣凝膠介紹 6 3-2 奈米孔洞於複合材料之補強應用 8 3-3 奈米碳管介紹 8 3-4 環氧樹脂 11 3-5 材料破壞模式 12 3-6 複合材料受疲勞負荷之影響 13 3-6.1 破壞型態 13 3-6.2 應力(S)與破壞周次(Nf)的關係 14 3-7 複合材料受溫度的影響 15 第四章 實驗內容及程序 16 4-1 實驗材料 16 4-2 實驗儀器與設備 18 4-2.1 試片加工設備 18 4-2.2 實驗測試儀器 20 4-3 試片製作流程 23 4-3.1 製備碳氣凝膠/奈米碳管/環氧樹脂試片 23 4-3.2 製備碳纖維/碳氣凝膠/奈米碳管/環氧樹脂積層板 25 4-4 實驗測試流程 26 4-4.1 實驗測試條件 26 4-4.2 實驗測試方法 27 第五章 結果與討論 32 5-1碳氣凝膠/1wt%奈米碳管/環氧樹脂複合材料機械性質測試 32 5-1.1 彎曲測試分析 32 5-1.2 衝擊測試分析 34 5-1.3拉伸測試分析 35 5-2碳氣凝膠/1wt%奈米碳管/環氧樹脂複合材料物理性質探討 37 5-3碳氣凝膠/1wt%奈米碳管/碳纖維積層板機械性質測試 37 5-3.1 彎曲測試分析 37 5-3.2 層間剪切強度分析 39 5-3.3 拉伸測試分析 40 5-4碳氣凝膠/1wt%奈米碳管/碳纖維積層板溫濕效應後機械性質測試 42 5-4.1 常溫高濕(25℃/ 85%RH)環境之機械性質分析 42 5-4.2 高溫高濕(85℃/ 85%RH)環境之機械性質分析 44 5-4.3 兩種老化環境下之機械性質分析 46 5-5碳氣凝膠/1wt%奈米碳管/碳纖維積層板山區效應後機械性質測試 47 5-5.1 山區效應之機械性質分析-1week 47 5-5.2 山區效應之機械性質比較-1week、2week、4week 49 第六章 結論與未來工作 50 參考文獻 52 附表 58 附圖 65

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