研究生: |
蘇育陞 Yu-Sheng Su |
---|---|
論文名稱: |
添加BaO-ZnO-Li2O-B2O3-SiO2玻璃對BaTi4O9的燒結行為與微波介電性質之影響 Low-Fire Processing and Microwave Dielectric Properties of BaTi4O9 with BaO-ZnO-Li2O-B2O3-SiO2 Glass |
指導教授: |
簡朝和
Jau-Ho Jean |
口試委員: | |
學位類別: |
碩士 Master |
系所名稱: |
工學院 - 材料科學工程學系 Materials Science and Engineering |
論文出版年: | 2007 |
畢業學年度: | 95 |
語文別: | 中文 |
論文頁數: | 28 |
中文關鍵詞: | 低溫共燒陶瓷 、微波介電性質 、助燒玻璃 |
外文關鍵詞: | LTCC, BaO-ZnO-Li2O-B2O3-SiO2, ZnO-Li2O-B2O3-SiO2, BaTi4O9, BaTi5O11, glass |
相關次數: | 點閱:1 下載:0 |
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本研究主題探討BaO-ZnO-Li2O-B2O3-SiO2(BZLBS)玻璃以及ZnO-Li2O-B2O3-SiO2(ZLBS)玻璃的添加對BaTi4O9陶瓷粉末燒結以及微波介電性質的影響。
玻璃中BaO的添加(BZLBS玻璃)小幅提高了玻璃轉換點、軟化點及熔點,此外也改善了與BaTi4O9間的潤濕行為。選用以上兩種玻璃作為BaTi4O9的助燒劑可大幅降低燒結溫度至900℃~925℃左右,其中BZLBS玻璃相對於ZLBS玻璃有較好的助燒效果,原因除了BZLBS玻璃具有較佳的潤濕性外,燒結時ZLBS玻璃與BaTi4O9反應造成大量的相變化,生成BaTi5O11新相的過程中阻礙了燒結緻密化的行為,而含有BaO的BZLBS玻璃可抑制元素Ba的擴散,阻止新相的產生,燒結緻密程度以及介電性質也因此獲得改善。
在微波介電性質方面,在925℃燒結溫度下,添加5 vol.% BZLBS玻璃於BaTi4O9中具有最佳的介電性質:介電常數(K)為33.5、品質因子(Q)為3030而Q × f0為19720 GHz。
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