本篇論文以水熱反應法，以一步還原成功還原出具有高比表面積、高電子傳導率之三維結構氧化石墨烯(reduced Graphene Oxide, rGO)。利用本實驗室自製之開方式還原系統，沉積奈米顆粒於前述碳材之上，以提高觸媒承載量，利用石墨烯之材料特性提高白金觸媒高承載表面積，亦可提高觸媒分散性。應用於直接甲醇燃料電池中做為高效能、高反應面積、低成本之白金觸媒或多元材料觸媒。應用於高效能直接甲醇反應式燃料電池之觸媒載體。
本實驗以水熱法和官能基接合兩種方式，其中水熱法將氧化石墨烯(Graphene Oxide, GO)和碳布(carbon cloth, CC)接合。成功同時一步還原白金顆粒和氧化石墨烯成為一多孔結構觸媒載體，再沉積白金顆粒以提高觸媒總體效能。從其半電池循環伏安法性質可看出，白金氧化峰電流密度以達到286 mA/cm2，氫離子吸脫附反應表面積為32.9 mC/cm2，其片電阻約為1.1Ω∙cm，相較於不使用石墨烯之碳布觸媒(Pt/CC)之效能提升約為2倍。在70℃之最佳全電池功率密度約有52mW/cm2，電流密度約為120mA/cm2。未來期望利用氫氣將PtrGO電極進行熱退火，以提升電極導電性，進而提升整體全電池效能。
官能基接合部分，本實驗以1,12-diaminododecane接合GO/CC和CNT/CC兩種電極。並沉積奈米白金顆粒製備Pt/GO/CC和Pt/CNT/CC。從循環伏安法的分析中可看出，相較於不處理的Pt/CC電極，此兩種電極的白金氧化峰並無明顯的提升，主因為GO和CNT接貼合在碳布表面上，無助於觸媒分散性的提升。

In this paper, The Graphene Oxide and the Pt particles were successfully reduced into three-dimensional expansion reduced Graphene Oxide(PtrGO) by the one step Hydrothermal synthesis method at 180℃ as the anode electrode for micro Direct Methanol Fuel Cells (μDMFC). For the higher performance of the PtrGO. The electrode was operated into the Homemade Open-loop reduced system (OLRS) for reducing high performance Pt particles as the anode electrode(Pt/PtrGO). The best fuel cell performance of Pt/PtrGO was 55 mW/cm2 for the power density and 120 mA/cm2 for the current density. For further experiment, the H2 annealing for the PtrGO should be operated to improve the conductivity.

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