在本論文研究中，使用了磁控濺鍍製造了摻雜釓的二硫化鉬並利用來作為析氫反應(Hydrogen Evolution Reaction)的催化劑且通過電化學的量測其非磁化、磁化(殘磁)，放置磁場下的過電位，以研究磁性催化劑在不同情況下對於HER的影響。對於材料性質，在本研究中使用了XRD，XPS，SEM，Raman spectroscopy analysis，去研究材料在不同基板、不同摻雜濃度、不同成長時間上的結晶度、成分組成、表面形貌，從電化學LSV的數據可以發現到，摻雜釓的二硫化鉬在殘磁的狀態過電位為210 mV 遠小於沒有摻雜的二硫化鉬(353 mV )，而塔佛斜率也有所下降。而在飽和磁化量最高的3.5 nm樣品中我們透過變化磁場下量測LSV發現到，其過電位會隨著不同的磁場方向而改變，這是以往都沒有人發現到的現象，透過SEM 我們可以觀察到利用磁控濺鍍成長二硫化鉬於金基板上比起其他導電基板擁有更多的花狀結構，這也為二硫化鉬作為催化劑製造更多的工作面積，結合XRD、XPS、Raman spectroscopy 可以觀察到不同濃度的摻雜對於二硫化鉬結晶度、元素價數的影響並藉此去研究摻雜所導致的晶體缺陷對於催化反應的影響，最後透過析吸收光譜(XAS、FTIR)去研究摻雜後所引起電子軌域的變化以及二硫化鉬不同的鍵結方向。

In this study, gadolinium doped molybdenum disulfide was fabricated by magnetron sputtering and used as a catalyst for the hydrogen evolution reaction. The non-magnetization, magnetization (remanent magnetism), and overpotential under a magnetic field were measured electrochemically to investigate the effect of magnetic catalysts on HER under different conditions. For the material properties, XRD, XPS, SEM, and Raman spectroscopy analysis were used in this study to investigate the crystallinity, composition, and surface morphology of the material on different substrates, doping concentrations, and growth times. From the electrochemical LSV data, it can be found that the overpotential of gadolinium doped molybdenum disulfide in the remanent magnetic state is much smaller than that of undoped molybdenum disulfide (353 mV), and the Tafel slope also decreases. In the 3.5 nm sample with the highest absorption magnetization, we measured LSV under transmission changing magnetic fields and found that its overpotential changes with different magnetic field directions. This is a phenomenon that no one has discovered before. Through SEM, we can observe that using magnetron sputtering to grow molybdenum disulfide on gold substrates has more flower like structures than other conductive substrates This also creates more working area for molybdenum disulfide as a catalyst. By combining XRD, XPS, and Raman spectroscopy, the effects of different concentrations of doping on the crystallinity and element valence of molybdenum disulfide can be observed, and the influence of crystal defects caused by doping on catalytic reactions can be studied. Finally, through analysis and absorption spectroscopy (XAS, FTIR) Study the changes in electronic orbital domains caused by doping and the changes in bonding.

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