本研究的目標為發展一種特殊塗細條及薄層的塗佈技術，取代傳統寬幅式塗佈彩色濾光片製程，如能成功，可減少塗液之使用和減少塗液之成本，省下曝光、蝕刻等手續。
　　影響條紋式塗佈工程的因素非常多，物理參數如黏度、表面張力、接觸角，幾何參數如狹縫間隙、塗佈間隙等，除此之外，由於本實驗操作尺度更為精細，所以實驗過程中發現了更多微小的細節會影響到條紋式塗佈工程的成功與否，其原因主要在於實驗本身操作機制的精密度與塗液本身性質的配合有關。此外，本研究利用CCD建立流場觀測技術以及拍照分析膜面的平整性與寬度，藉此觀察這些不同參數對於塗膜的影響程度。
　　本研究需要克服膜寬上尺度的限制，必須使用更為精密的流量控制器來提供所需要的微小流量，所以本實驗採用了一套精密空氣控制系統作為塗出150μm膜寬的供料系統，同時採用精密點膠塗佈設備做為塗佈工具，此系統可完全克服塗佈流體潤濕膜唇以及塗液回流等問題，如此一來，配合實驗參數即可塗出150μm的條紋寬度，但礙於實驗機台與儀器配合上的限制，未能找到屬於150μm條紋塗佈的塗佈視窗，只能設定一個操作區間能有150μm條紋膜寬出現，此外，藉由工研院膜厚測量儀的幫助下，發現了一項特殊的物理現象，本實驗定義此現象稱為雙牛角現象（double horn effect），在透過多次實驗上的測試輔助和塗液改良後，已經掌握控制雙牛角現象形成的機制和塗液配方，並經由FTIR和流變儀的分析結果，了解到高分子鏈氫鍵效應的發生是雙牛角現象形成的主要關鍵，只要掌握控制塗液氫鍵能力的強弱以及有適當溶劑的搭配，就可以控制雙牛角現象。

[1] Haaland, P., McKibben, J. and Parodi, M. (1995). "The art and science of thin-film coating - a progress report." Solid State Technology 38(4): 83-&.
[2] Bagen, S., Melgaard, H., Minnich, C., Newquist, C. and Gibson, G. (1996). "Novel low cost process technologies for application and curing of polyimide films." Int. J. of Microcircuits & Electronic Packaging 19: 418-426.
[3] Cohen, E. and Gutoff, E. (1992). Modern coating and drying technology. New York, VCH publisher.
[4] Ruschak, K. J. (1976). "Limited flow in a pre-metered coating device." Chemical Engineering Science 31: 1057-1060.
[5] Higgins, B. G. and Scriven, L. E. (1980). "Capillary-pressure and viscous pressure-drop set bounds on coating bead operability." Chemical Engineering Science 35(3): 673-682.
[6] Lee, K. Y., Liu, L. D. and Liu, T. J. (1992). "Minimum wet thickness in extrusion slot coating." Chemical Engineering Science 47(7): 1703-1713.
[7] Landau, L. and Levich, B. (1942). "Dragging of a liquid by moving plate." Acta physicochim. URSS 17: 42-54.
[8] Sullivan, T. M. and Middleman, S. (1986). "Film thickness in blade coating of viscous and viscoelastic liquids." Journal of Non- Newtonian Fluid Mechanics 21(1): 13-38.
[9] Huppert, H. E. (1982). "The propagation of two-dimensional and axissymmetric viscous gravity currents over a rigid horizontal surface." Journal of Fluid Mechanics 121(AUG): 43-58.
[10] Ito, H., Doi, M., Isaki, T. and Takeo, M. (2003). "A model of neck-in phenomenon in film casting process." Journal of the Society of Rheology Japan 31(3): 157-163.
[11] Ito, H., Doi, M., Isaki, T., Takeo, M. and Yagi, K. (2003). "2D flow analysis of film casting process." Journal of the Society of Rheology Japan 31(3): 149-155.
[12] Dobroth, T. and Erwin, L. (1986). "Causes of edge beads in cast films." Polymer Engineering and Science 26(7): 462-467.
[13] Bartlett, L. C. (1977). "Apparatus for multiple stripe coating " United States Patent 4,106,437.
[14] Oi, R. (1993). "Production of color filter."Japan Patent 05-142407.
[15] Watanabe, M. (1997). "Coating device and a method of coating." United States Patent 5,700,325.
[16] Kamikihara, N. and Watanabe, M. (2002). "Stripe coating applicator and method." United States Patent 6,344,088.
[17] Deegan, R. D., Bakajin, O., Dupont, T. F., Huber, G., Nagel, S. R. and Witten, T. A. (1997). "Capillary flow as the cause of ring stains from dried liquid drops." Nature 389(6653): 827-829.
[18] Deegan, R. D. (2000). "Pattern formation in drying drops." Physical Review E 61(1): 475-485.
[19] Deegan, R. D., O. Bakajin, et al. (2000). "Contact line deposits in an evaporating drop." Physical Review E 62(1): 756-765.
[20] de Gans, B. J. and Schubert, U. S. (2004). "Inkjet printing of well-defined polymer dots and arrays." Langmuir 20(18): 7789-7793.
[21] de Gans, B. J., Kazancioglu, E., Meyer, W. and Schubert, U. S. (2004). "Ink-jet printing polymers and polymer libraries using micropipettes." Macromolecular Rapid Communications 25(1): 292-296.
[22] Pesach, D. and Marmur, A. (1987). "Marangoni Effects in the Spreading of Liquid-Mixtures on a Solid." Langmuir 3(4): 519-524.
[23] de Gans, B. J., Tekin, E. and Schubert, U. S. (2004). "Ink-jet printing of polymers - from single dots to thin film libraries." Journal of Materials Chemistry 14(17): 2627-2632.
[24] Park, J. and Moon, J. (2006). "Control of colloidal particle deposit patterns within picoliter droplets ejected by ink-jet printing." Langmuir 22(8): 3506-3513.
[25] Lim, J. A., Lee, W. H., Lee, H. S., Lee, J. H., Park, Y. D. and Cho, K. (2008). "Self-organization of ink-jet-printed triisopropylsilylethynyl pentacene via evaporation-induced flows in a drying droplet." Advanced Functional Materials 18(2): 229-234.
[26] Tekin, E., Smith, P. J., Hoeppener, S., van den Berg, A. M. J., Susha, A. S., Rogach, A. L., Feldmann, J. and Schubert, U. S. (2007). "Inkjet printing of luminescent CdTe nanocrystal-polymer composites." Advanced Functional Materials 17(1): 23-28.
[27] van den Berg, A. M. J., A. W. M. de Laat, et al. (2007). "Geometric control of inkjet printed features using a gelating polymer." Journal of Materials Chemistry 17(7): 677-683.
[28] Tekin, E., E. Holder, et al. (2007). "Controlled pattern formation of poly [2-methoxy-5(2 '-ethylhexyloxyl)-1,4-phenylenevinylene] (MEH-PPV) by ink-jet printing." Advanced Functional Materials 17(2): 277-284.
[29] Soltman, D. and V. Subramanian (2008). "Inkjet-printed line morphologies and temperature control of the coffee ring effect." Langmuir 24(5): 2224-2231.
[30] Chen, X., Knight, D. P., Shao, Z. Z. and Vollrath, F. (2001). "Regenerated Bombyx silk solutions studied with rheometry and FTIR." Polymer 42(25): 9969-9974.
[31] Lyon, P. J., Carter, J. C., Bright, J. C. and Cacheiro, M. (2002). "Formulation and method for depositing a material on a substrate." WO patent 02/069119 A1.
[32] Lin, H. C., Wang, C. F., Kuo, S. W., Tung, P. H., Huang, C. F., Lin, C. H. and Chang, F. C. (2007). "Effect of intermolecular hydrogen bonding on low-surface-energy material of poly(vinylphenol)." Journal of Physical Chemistry B 111(13): 3404-3410.
[33] Huang, C. F. and Chang, F. C. (2003). "Comparison of hydrogen bonding interaction between PMMA/PMAA blends and PMMA-co-PMAA copolymers." Polymer 44(10): 2965-2974.
[34] Huang, C. F., Kuo, S. W., Lin, F. J., Wang, C. F., Hung, C. J. and Chang, F. C. (2006). "Syntheses and specific interactions of poly (hydroxyethyl methacrylate-b-vinyl pyrrolidone) diblock copolymers and comparisons with their corresponding miscible blend systems." Polymer 47(20): 7060-7069.
[35] Huang, K. T., Chao, S. D., Cheng, I. J. and Chang, M. H. (2006). "Alkali-soluble resin with polyaromatic group and photosensitive composition comprising the resin." United States Patent 7,090,062.
[36] Warren, N. S. and Michael, A. V. (2006). "Liquid dispensing valve and method with improved stroke length calibration and fluid fittings." United States Patent 7,070,066.
[37] John, M. R. (2006). "Device for dispensing a heated liquid." United States Patent 2006/0097010.
[38] Milbourn, T. M. and Barth, J. J. (1994). "Method of applying discrete coating patches on a moving web." United States Patent 5,360,629.
[39] Sigma-Aldrich (2007). "THF Miscibility / Immiscibility Table." from http://www.sigmaaldrich.com/Area_of_Interest/Research_Essentials/Solvents/Tetrahydrofuran_Center/Miscibility__Immiscibility.html.
[40] Zhang, S., Liang, Z., Wang, Q. and Zhang, Q. M. (2006) "Ink-jet printing of ferroelectric poly(vinylidene fluoride-trifluoroethylene) copolymers." Mater. Res. Soc. Symp. Proc. 889(W05-02):1-20.
[41] Bird, R. B., Stewart, W. E. and Lightfoot, E. N. (1960). Transport phenomena. New York, John Wiley & Sons.
[42] Perry, R. H., Green, D. W. and Maloney, J. O. (1984). Perry's Chemical engineers handbook. New York, McGraw-Hill.
[43] Lee, H. and Scriven, L. E. (2002). Tensioned-web slot coating：study of the coating window. Minneapolis, Minnesota, Presented at the 11th ISCST.
[44] 李國陽 (1990). "擠壓式塗佈工程之研究." 國立清華大學化學工程研究所博士論文.
[45] 朱文彬 (1997). "低黏度牛頓流體之預調式塗佈分析." 國立清華大學化學工程研究所碩士論文.
[46] 喻雲威 (1998). "擠壓式模具內複雜流動之分析." 國立清華大學化學工程研究所博士論文.
[47] 方聰偉 (2001). "微米級條紋式塗佈." 國立清華大學化學工程研究所碩士論文.
[48] 楊之光 (2001). "先進狹縫式塗佈研究." 國立清華大學化學工程研究所博士論文.
[49] 張凱鈞 (2007). "條紋式塗佈之研究." 國立清華大學化學工程研究所碩士論文.