多壁奈米碳管/陶瓷複合材料之物化性質與微結構研究

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研究生：	詹崑汶 CHAN, KUN WEN
論文名稱：	多壁奈米碳管/陶瓷複合材料之物化性質與微結構研究 Physic-chemical properties and microstructure of carbon nanotubes reinforced ceramics
指導教授：	徐文光
口試委員:	林樹均賴宏仁
學位類別：	碩士 Master
系所名稱：	工學院 - 材料科學工程學系 Materials Science and Engineering
論文出版年：	2012
畢業學年度：	100
語文別：	中文
論文頁數：	54
中文關鍵詞：	奈米碳管、陶瓷材料、複合材料、孔洞性
相關次數：	點閱：1 下載：0
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本論文在探討奈米碳管/陶瓷複合材的物化性質與微結構。加入少量多壁碳管有強化複合材的效果，但過多的碳管則會產生聚集反而使強度降低。同時複合材內的孔徑也因添加碳管而有縮小的傾向。加入2wt%以上的碳管使複合材產生electrical percolation現象，導致電導率提升。

Multi-walled carbon nanotubes/ceramic composites are fabricated and their Physic-chemical properties and microstructure are investigated. Addition of carbon nanotubes improves composite hardness and creates a uniform pore size. Electrical percolation is observed at 2wt% addition and improved electrical conductivity is verified.

摘要......................................................I
Abstract.................................................II
誌謝....................................................III
目錄......................................................V
圖目錄.................................................VIII
表目錄....................................................X 
第一章 研究動機...........................................1
第二章 文獻回顧...........................................2
2-1奈米碳管的特性.................................2
2-2奈米碳管的合成方法.............................5
2-2-1直流電弧放電法...........................5
2-2-2雷射蒸發法...............................6
2-2-3化學氣相沉積.............................7
2-3奈米碳管的電性.................................8
2-4奈米碳管的機械性質............................10
2-5陶瓷材料簡介..................................11
2-6奈米碳管/陶瓷複合材料.........................14
第三章 實驗方法..........................................16
3-1實驗藥品與儀器................................16
3-2實驗流程......................................18
3-2-1多壁奈米碳管............................18
3-2-2多壁奈米碳管/陶瓷複合材製備.............19
3-3實驗步驟......................................20
3-3-1多壁奈米碳管/陶瓷複合材製備.............20
3-3-2傅立葉紅外光譜量測......................21
3-3-3密度量測................................22
3-3-4導電率量測..............................23
3-3-5硬度量測................................26
3-3-6孔徑、比表面積量測......................28
3-3-7感應耦合電漿質譜儀量測..................28
3-3-8 X光繞射量測.............................29
第四章 實驗結果與討論....................................30
4-1感應耦合電漿質譜儀量測與X光繞射圖............30
4-2傅立葉紅外線光譜..............................33
4-3比表面積與孔隙分析............................36
4-4機械性質硬度及密度............................43
4-5導電率........................................48
第五章 結論..............................................50
參考文獻.................................................51

                                

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