研究生: |
王賢軍 |
---|---|
論文名稱: |
碳氧化矽與氮氧化矽薄膜應用於離子感測膜之研究 Study on ion sensing membrane with silicon oxycarbide and silicon oxynitride thin films |
指導教授: | 陳建瑞 |
口試委員: | |
學位類別: |
碩士 Master |
系所名稱: |
工學院 - 材料科學工程學系 Materials Science and Engineering |
論文出版年: | 2004 |
畢業學年度: | 92 |
語文別: | 中文 |
論文頁數: | 83 |
中文關鍵詞: | 離子感應場效電晶體 、高密度電漿化學氣相沉積 、感應耦合型電漿 、碳氧化矽 、氮氧化矽 |
相關次數: | 點閱:1 下載:0 |
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本實驗以感應耦合電漿源(Inductively Coupled Plasma, ICP)沈積離子感測薄膜,以探討製程溫度與不同氣體流量比對感測膜之敏感度之影響。在沉積完感測薄膜後,利用原子力顯微鏡量測表面的粗糙度、傅利葉紅外光譜儀量測薄膜之化學鍵結、膜厚測厚儀量測薄膜厚度與折射率、低掠角X光繞射分析感測膜結晶情形與敏感度之關係、能量散佈分析儀可分析感測膜之成份與敏感度之關係、C-V曲線量測感測膜之界面陷阱電荷對感測敏感度之影響及I-V曲線量測感測膜之漏電流之情形。
由實驗結果可知當氣體流量比N2O / NH3=0/180,製程溫度200℃時,有最佳之氫離子敏感度54.6mV/pH,其氫離子感測範圍為pH 1至pH 11,非常接近理論值59.6 mV/pH。當氣體流量比N2O / NH3=180/0,製程溫度300℃時,其最佳之鈉離子敏感度29.5mV/pNa,其鈉離子感測範圍為pNa 1至pNa 3;當氣體流量比N2O / NH3=150/30,製程溫度200℃時,可得最佳之鉀離子敏感度 24.5 mV/pK,其鉀離子感測範圍為pK 1至pK 3
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