最近這幾年，奈米科技快速地發展，幾乎在生活中都可以找到利用奈米科技來製作的產品，像民生用品或頂尖的高科技產品， 而且所涵蓋的領域非常廣泛，包括生物科技、材料應用及光學研究等。
本論文是利用聚苯乙烯奈米球所擁有自組裝的特性，使其整齊地排列在基板上，之後熱蒸鍍鎳金屬在已塗佈奈米球之基板，用化學方法舉離奈米球，最後可以得到二維鎳金屬奈米陣列，完成樣品的製作並量測其二次諧波，並觀察是否由於陣列鎳金屬粒子之晶格布拉格散射產生類似相位匹配的效果。
內容共分六章。第一章說明奈米科技發展及研究動機，第二章簡單地介紹奈米球微影技術，第三章概述非線性光學的歷史和二次諧波的理論，第四章講解實驗方法跟所使用的儀器裝置與量測系統，第五章對量測到的數據作分析與討論，第六章結論與未來方向。

第一章
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第二章
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第三章
[1] P. Fraken, A. E. Hill, C. W. Peters, and G. Weinreich,” Generation of Optical Harmonics”Phys. Rev. Lett.,7,118 (1961)
[2] R. W. Boyd ,”Nonlinear Optics”(Academic Press, Inc, Boston ,1999)
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第四章
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[4] 郭昆樺著，”氧化鋅奈米柱之成核成長及其發光特性研究”
，(國立清華大學材料科學工程學系研究所，2005)
第五章
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[2] C. C. Tzeng, and J. T. Lue,“Nonlinear optical generation from noble metals and aluminum films in various geometric configurations”Phys. Rev. A 39, 191 (1989)