簡易檢索 / 詳目顯示

研究生: 陳劭宇
Chen, Shao-Yu
論文名稱: 海水發電模組設計與最佳輸出功率之研究
Study and design of seawater Powering module and Optimized output power
指導教授: 徐文光
Hsu, Wen-Kuang
口試委員: 黃金花
Huang, Jin-Hua
許景棟
Hsu, Ching-Tung
學位類別: 碩士
Master
系所名稱: 工學院 - 材料科學工程學系
Materials Science and Engineering
論文出版年: 2017
畢業學年度: 105
語文別: 中文
論文頁數: 70
中文關鍵詞: 海水發電模組設計
外文關鍵詞: seawater, powering
相關次數: 點閱:1下載:0
分享至:
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報
  • 1945年美國貝爾實驗室設計、通用電氣公司製造出以鎂為陽極,氯化銀為陰極之海水發電模組(或稱海水電池)作為魚雷電源及照明設備。但由於氯化銀成本昂貴且會汙染環境,隨後有許多不含銀的材料被研究做為替代的海水電池陰極。我們承襲這樣的想法,去設計一個穩定而無汙染的海水發電模組。
    為了提升海水電池輸出功率,我們從三個方面著手。首先,在材料選擇上,承前學長姐在電池陰極上之複合材料研究。在系統上,設計電池發電模組,通以水流循環海水以解決氫氧化鎂沉澱以及氧氣消耗之問題。在電路上,以串並聯方式觀察其放電表現,我們藉由增加金屬反應面積來提升電流,並且以定電流放電觀察其壓降表現,並探討電壓與金屬板腐蝕的影響。


    In 1945, Bell lab and GM had developed a seawater battery using Mg and AgCl as anode and cathode for powering torpedo and lighting devices. The AgCl is expensive and non-ecofriendly. Therefore, various materials have been later studied and tested as cathode, including carbon-made cath-odes. Based on previous ideas, we have designed a stable and free of sea pollution seawater battery. In order to enhance output performance, we im-prove seawater cell in three aspects. First, cathode material is carefully se-lected. Second, a seawater-cycling system is developed to resolve the prob-lems on precipitation of magnesium hydroxide and the assumption of ox-ygen. Third, cells are connected in different fashions (in series and in paral-lel).

    摘要 i Abstract i 致謝 ii 目錄 iv 圖目錄 vii 表目錄 x 第一章 文獻回顧 1 1.1海水電池研究背景 ……1 1.2海水電池工作原理 ……3 1.2.1陽極 3 1.2.2陰極 3 1.2.3電解液 6 1.2.4反應式 7 1.3陽極材料-鎂鋁合金 …….…8 1.3.1鎂鋁合金腐蝕 9 1.3.2 負差效應(Negative Difference Effect)……………………….10 1.4 陰極材料的選擇…..………………………………………………………… ……… 12 1.4.1 CNT奈米碳管 12 1.4.2 PEDOT:PSS 15 1.4.3鎳基板(黃銅鍍鎳) 17 第二章 研究動機 18 第三章 實驗分析與量測 19 3.1實驗流程 ….19 3.2藥品與儀器 ….19 3.2.1藥品 19 3.2.2儀器 20 3.2.3海水電池基本組成 21 3.2.4海水電池模具 22 3.2.5水循環系統……………………………………... 23 3.2.6模組串並聯與量測 25 3.2.7升壓器 25 3.3實驗分析與量測 ….27 3.3.1 掃描式電子顯微鏡分析(SEM) 27 3.3.2 X-RAY繞射分析 278 3.3.3 腐蝕性質量測………………….……………………...……...29 3.3.4 定電流放電 32 3.3.5線性伏安量測 ..………………………………………………34 3.3.6感應耦合電漿原子發射光譜/質譜 儀 ..………………………35 第四章 結果與討論 37 4.1陰極材料的選擇 .…39 4.2循環海水影響電池性能討論 .…39 4.3海水電池模組之串聯 .…43 4.3.1 S型與U型串聯法對內部電池電動勢之分析 43 4.3.2 串聯對短路電流之討論 46 4.4海水電池分析 ….48 4.4.1 線性掃描伏安法 48 4.4.2 腐蝕性質分析 48 4.4.3 定電流放電測試 52 4.4.4 升壓器應用之討論 53 4.4.5 極版尺寸與電流之討論 56 4.4.6 沉澱物分析-感應耦合電漿原子發射光譜儀/質譜&SEM 63 第五章 結論……………….. 67 參考文獻 68

    1. 維基百科, 潛艇 ;
    Available form: https://zh.wikipedia.org/wiki/%E6%BD%9B%E8%89%87
    2. Raymond L. Tayloig'Summit, N. J., assigner to Bell Telephone Laboratories, Incor-porated, New York, N. Y., a corporation of New York, UNITED STATES PATENT OFFICE‐SEA‐WATER BATTERY. 1945.
    3. Hasvold Ø, Henriksen H, Melvær E, Citi G, Johansen BØ, Kjønigsen T, et al. Sea water battery for subsea control systems. Journal of power sources 1997;65:253-61.
    4. 馮 豔, 王日初, 彭超群, 海水電池用鎂陽極的研究與應用, The Chinese Journal of Nonferrous Metals 2011; 21
    5. Koontz, RF, et al., Magnesium water-activated batteries, in Handbook of batteries. 2002, McGraw-Hill: New York. p. 17.1-17.27
    6. Medeiros MG, Dow EG, Magesium-solution phase catholyte seawater electrochemical system, Journal of power sources 1999; 80,78-82
    7. 戴昌鳳, 台灣區域海洋學, p243, 2014
    8. Koontz, R., et al., Magnesium water-activated batteries, in Handbook of batteries. 2002, McGraw-Hill: New York. p. 17.1-17.27
    9. Hasvold,Ø.;Henriksen,H.;Melv˦r,E.;Citi,G.;Johansen,B.Ø.;Kjønigsen,T.;Galetti,R.,Sea‐water battery for subsea control systems. Journal of Power Sources 1997; 65, 253‐261.
    10. Hasvold, Ø.; Lian, T.; Haakaas, E.; Størkersen, N.; Perelman, O.; Cordier, S., CLIP-PER: a long‐range, autonomous underwater vehicle using magnesium fuel and oxygen from the sea. Journal of power sources 2004; 136, 232‐239
    11. ∅.Hasvold, in T. Keily and B.W. Baxter (eds.), Power Sources ,International Power Sources Committee, 1991,13, 307-318
    12. ∅istein Hasvold , et al., Sea-water battery for subsea control systems , Journal of Power Sources 1997; 65, 253-261
    13. Ono S, Asami K, Osaka T, Masuko N. Structure of aodic films on magnesium. J Electrochem Soc 1996; 143; L62-3
    14. Kemin Song, Wenyi Lu, Shuying Gao, et al. Preparation of low-sulfur expansible graphite Chinese Journal of Applied Chemistry,1995; 12 , 94–95
    15. 百度 available:
    https://translate.google.com.tw/translate?hl=zh-TW&sl=zh-CN&u=http://baike.baidu.com/view/2337623.htm&prev=search
    16. Understanding MagnesiumCorrosionA Framework for Improved Alloy Perfor-mance**By Guangling Song and Andrej Atrens*
    17. Hassanien A., et al., Geometrical structure and electronic properties of atomically re-solved multiwall carbon nanotubes. Applied Physics Letters, 1999.75(18): p.2755-2757
    18. Lambin P., Electronic structure of carbon nanotubes. Comptes Rendus Physique, 2003.4(9): p. 1009-1019
    19. W. Dacheng, Y. Liu, The Intromolecular Junctions of Carbon Nanotubes, Adv. Mater., 9999, 2008; 1-27
    20. Ebbesen, T. W. & Ajatan, P.M., Large-scale synthesis of carbon nanotubes, Nature 358, 1992; 220-222
    21. 馬振基, 奈米材料原理與應用, 全華科技圖書公司, 2003
    22. Li Y F. Conducting polymers[J] , Progress in Chemistry , 2002 , 14 : 2072211Stenger-Smith J D, Intrinsically electronically conducting polymers. Synthesis, characterization and their applications [J]. Prog. Polym. Sci., 1998 ,23:57-79.
    23. Kanatzldls M G. Conducting polymers[J] . Chem. & Engin., 1990, (12):36254.
    24. Shi G Q, Li C, Liang Y Q. High quality conducting polymers[J]. University Chemistry, 1998, (1):1-5.
    25. Zhu D B,Wang F S. Organic Solids[M]. Shanghai:Shanghai Press of Science and Technology. 1999. 89-136 ,274-296.
    26. 陳一帆, The Study of Conducting Polymer Polyaniline in Organic Solar Cells,國立中山大學光電工程學系博士論文, 2012
    27. 陳建清, LiNi0.8Co0.2O2 陰極材料製程與改質研究,國立中央大學化學工程與材料工程研究所 碩士論文, 2002
    28. Hu H, Zhang C, Liu Z, Zhou X, Pang S, et al. Nanostructured titanium ni-tride/PEDOT:PSS composite films as counter electrodes of dye-sensitized solar cells. ACS Appl Mater Interfaces 2012;4(2):1087-92
    29. Hou J, Zhu G, Xu J, Liu H, Anticorrosion performance of epoxy coatings containing small amount of inherently conducting PEDOT/PSS on hull steel in seawater . J Mater Sci Technol 2013;290(7):678-84
    30. Shi H, Liu C, Xu J, Song H, Lu B, Jiang F, et al. Facile fabrication of PE-DOT:PSS/polythiophenes bilayered nonofilms on pure organic electrodes and their thermoelectric performance. ACS Appl Mater Interfaces 2013; 5(24):12811-9.
    31. Xu H, Wang Y, Luo Z, Pan Y. A miniature all-solid-state calcium electrode applied to in situ seawater measurement. Mean Sci Technol 2013; 24(12):125105
    32. 黃桂武, 軟性印製透明導電高分子材料技術發展,光連雙月刊, No.102, 2013
    33. Wang T J ,Qi Y Q ,Chen P , et al. Effect of addition of poly (ethylene glycol) on elec-trical conductivity of poly (3 ,4-ethylenedioxythiophene)-poly (styrene sulfonate) hy-brid[J]. Chinese Science Bulletin , 2003 , 48(22) : 244422445.
    34. Frank L . 3 ,4-alkylenedioxy2thiophene copolymer[P] . EP , 1 323 763 , 2003.
    35. Worldwide, M. I., Dynamic Light Scattering Introduction.
    36. (a) Dresselhaus, M.; Eklund, P., Phonons in carbon nanotubes. Advances in Physics 2000, 49 (6), 705‐814; (b) Saito, R.; Dresselhaus, G.; Dresselhaus, M. S., Physical properties of carbon nanotubes. World cientific: 1998; Vol. 4; (c) Chico, L.; Crespi, V. H.; Benedict, L. X.; Louie, S. G.; Cohen, M. L., ure carbon nanoscale devices: nano-tube heterojunctions. Physical Review Letters 1996, 76 (6), 971.
    37. William F. Smith, Principles of Material Science and Engineering, 707, 1996.
    38. 田福助,電化學理論與應用,新科技書局出版, 2014
    39. C. Gabrielli, Identification of Electrochemical Processes by Frequency Response Analysis, Technical Report Number, 004/83, August 1984
    40. 升壓器原理: Available: http://cocdig.com/docs/show-post-14065.html
    41. 感應耦合電漿原子發射光譜儀/質譜 原理
    Available: http://www.eaglabs.com.tw/icp-oes-ms.html

    QR CODE