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研究生: 蕭伊淵
論文名稱: 在不同條件下硒化銅銦硒(CuInSe2)薄膜之影響
The influence of selenization conditions on CuInSe2 thin film
指導教授: 吳孟奇
Wu, Meng-Chyi
朱治偉
Chu, Chih-Wei
口試委員: 何充隆
陳方中
學位類別: 碩士
Master
系所名稱: 電機資訊學院 - 電子工程研究所
Institute of Electronics Engineering
論文出版年: 2012
畢業學年度: 100
語文別: 英文
論文頁數: 62
中文關鍵詞: 太陽能電池薄膜銅銦硒
外文關鍵詞: chalcopyrite
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  • 在這篇論文中將會探討,銅銦硒薄膜利用爐管兩段式加熱,會因第一段的溫度使得硒粉末蒸發速率不同,當溫度恰好過其沸點蒸發速率小於其與銅銦金屬起化學反應的速率,會使得薄膜內硒的組成比增加,第二段固定在攝氏500度,調變退火時間,使得銅銦硒薄膜能夠完成再結晶,並使用Br2/ MeOH蝕刻金屬相,以提高硒的組成比,在背電極鉬以及前驅物之間蒸鍍上硒,以提高薄膜內硒的組成比,使其略微超過50%。並嘗試製作背電極Mo、緩衝層CdS、窗層i-ZnO以及透明導電電極AZO,以製作銅銦硒太陽能電池。


    Abstract(in Chinese)……………………………………………I Abstract(in English)……………………………………………II Thanks(in Chinese)…………………………………………III Contents…………………………………………………………IV Chapter 1 Introduction……………………………………1 1-1 Introduction and motivation…………………………………1 Chapter 2 Property of the CIS solar cell………………4 2-1 Introduction of CuInSe2 solar cell…………………………4 2-2 CuInSe2 thin film……………………………………………6 Chapter 3 Experimental detail…………………………8 3-1 Device structure………………………………………………8 3-2 Experimental instrument…………………………………13 3-2-1 Sputter……………………………………………13 3-3 Measurement instrument…………………………………16 3-3-1 The Four-probe electrical measurements………16 3-3-2 The X-ray Diffraction……………………………17 3-3-3 The X-ray Fluorescence (XRF)…………………19 3-3-4 Atomic Force Microscopy (AFM)………………22 3-3-5 The Scanning Electron Microscope……………25 Chapter 4 Results and discussion 26 4-1 DC Power Sputter Molybdenum thin film………………26 4-2 Growth of CdS thin films by chemical bath deposition process………………………………………………………29 4-3 RF Power Sputter AZO thin film analysis………………35 4-4 Selenization CuInSe2 by furnace……………………………38 Summary…………………………………………………………58 Reference…………………………………………………………60

    1. P. Jackson, D. Hariskos, E. Lotter, S. Paetel, R. Wuerz, R. Menner, W. Wischmann, and M. Powalla, Progress in Photovoltaics: Research and Applications, 19, 894–897 (2011).

    2. J. A. M. AbuShama, S. Johnston, T. Moriarty, G. Teeter, K. Ramanathan, and R. Noufi, Progress in Photovoltaics: Research and Applications, 12, 39-45 (2004).

    3. M. A. Contreras, H. Wiesner, D. Niles, K. Ramanathan, R. Matson, J. Tuttle, J. Keane, R. Noufi, in: Conference Record of the 25th IEEE Photovoltaic Specialists Conference, 809–812 (1996).

    4. P. J. Dale, A. P. Samantilleke, G. Zoppi, I. Forbes, and. L. M. Peter, Journal of Physics D, 41, 085105 (2008).

    5. D. Liao and A. Rockett, in: Proceedings of the 29th IEEE Photovoltaic Specialists Conference, (2002), edited by T. Anderson in press.

    6. A. D. Compaan, I. Matulionis, and S. Nakade, Optics and Lasers in Engineering, 34, 15–45 (2000).
    7. ED. A.J.C. Wilson, Dordrect Kluwer Academic Pub. For International Union of Crystallography, (1995).

    8. L. S. Birks, X-Ray spectrochemical analysi, 2nd ed. New York: Interscience, (1969).

    9. G. Binnig, C. F. Quated, Ch. Gerber, Physical Review Letters, 56, 930 (1986).

    10. T.R. Albrecht, S. Akamine, T.E. Carver, C.F. Quate, Journal of Vacuum Science and Technology a-Vacuum Surfaces and Films, vol.8, no.4, 3386–3396 (1990).

    11. W. Bambynek, B. Crasemann, R. W. Fink, H. U. Freund, H. Mark, C. D. Swift, X-Ray Fluorescence Yields, Auger, and Coster-Kronig Transition Probabilities Rev. mod. phys.44, 716-813 (1972)

    12. J. H. Scofield, A. Duda, D. Albin, B. L. Ballard, and P. K. Predecki, Thin Solid Films 260, 26–31 (1995).

    13. M. A. Contreras, M. J. Romero, B. To, F. Hasoon, R. Noufi,. S. Ward, K. Ramanathan, Thin Solid Films 403–404, 204–211 (2002).

    14. J. M. Dona and J. Herrero, Journal of the Electrochemical Society, 144, 11 , 4081-4091 (1997).
    15. S. H. Jeong, J. W. Lee, S. B. Lee, J. H. Boo, Thin Solid Films 435, 78-82 (2003).

    16. Bin-Zhong Dong, Hao Hu, Guo-Jia Fang, Xing-Zhong Zhao, Da-Yu Zheng, and Yuan-Ping Sun, Journal of Applied Physics 103,073711 (2008)

    17. Shih-Hsien Liu, Fu-Shan Chen and Chung-Hsin Lu, Chemistry Letters, 39, 12, 1333-1335 (2010).

    18. L. Stolt, J. Hedstrom, J. Kessler, M. Ruckh, K.O. Velthaus, H.W. Schock, Applied Physics Letters, 62, 6, 597–599 (1993).

    19. K. Siemer, J. Klaer, I. Luck, J. Bruns, R. Klenk, D. Bräunig, Solar Energy Materials and Solar Cells, 67, 159-166 (2001).

    20. O. Volobujeva, M. Altosaar, J. Raudoja, E. Mellikov, M. Grossberg, L. Kaupmees, P. Barvinschi, Solar Energy Materials and Solar Cells, 93, 11-14 (2009)

    21. Q. Cuo, S. J. Kim, M. Kar, W. N. Shafarman, R. W. Birkmire, E. A. Stach, R. Agrawal, and H. W. Hillhouse, Nano Letters, 8, 2982-2987, (2008).

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