| 研究生: |
陳建忠 |
|---|---|
| 論文名稱: |
以Ni-SDC作為固態氧化物燃料電池陽極材料行直接內部甲烷蒸氣重組反應之研究 Study of Ni-SDC anode for internal steam reforming of methane in solid oxide fuel cells |
| 指導教授: |
黃大仁
tj.huang |
| 口試委員: | |
| 學位類別: |
碩士 Master |
| 系所名稱: |
工學院 - 化學工程學系 Department of Chemical Engineering |
| 論文出版年: | 2003 |
| 畢業學年度: | 91 |
| 語文別: | 中文 |
| 中文關鍵詞: | 固態氧化物燃料電池 、甲烷蒸氣重組 |
| 外文關鍵詞: | sofc, steam reforming of methane |
| 相關次數: | 點閱:203 下載:0 |
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本研究以氧化釤添加氧化鈰(Samaria-doped Ceria)簡稱(SDC),
混合硝酸鎳製成Ni-SDC作為固態氧化物燃料電池之陽極觸媒材料,在閉路的條件下,進行直接甲烷和直接甲烷內部蒸氣重組反應,並改變反應的溫度、陽極的燒結溫度及加入水氣的量,測量電池的電流,並以阻抗(impedance)分析法探討電池的阻力。
實驗結果發現,電池的電流隨著反應溫度的升高而增加,應該是溫度愈高則電解質傳導氧離子的能力愈強,且反應的活性也是隨著溫度的上升而提昇。陽極燒結的溫度愈高,所表現出來的結果也愈好,可能是此時陽極的結構較緻密,陽極本身形成好的連結,進行電化學反應時能將電子快速的傳導出去,所以測得的電流較大,電池的反應阻力也較小。進行甲烷蒸氣重組反應時,在陽極上完全沒有積碳的生成,且電池都處在很穩定的狀態下,表示電池能夠長時間進行放電。
另外,在實驗中也發現積碳有導電的功能,可作為陽極表面上金屬之間的橋樑;當金屬擔載量不足時,積碳不但能夠增加陽極的導電性,也因此能有效地傳導電子而促進電化學反應的發生,使電池電流增加。
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