聚碳酸酯具有優良的機械、化學和電子性能，應用範圍非常廣泛，已成為泛用工程塑膠中生產規模最大者，自從具劇毒的光氣被碳酸二苯酯取代，與雙酚A反應合成聚碳酸酯此種對環境有利的新技術被發展後，碳酸二苯酯的需求大增，使最近幾年碳酸二苯酯的研究與開發成為熱門重點。碳酸二苯酯的合成主要使用光氣法與非光氣法，但光氣法中所使用之光氣的劇毒和强腐蝕性以及相當數量副產物的產生，使此法不利於清潔生產和環境保護，本研究以無毒之綠色化學品-碳酸二甲酯為原料，使用酯交換法來合成碳酸二苯酯，以取代對環境不利的光氣法。
程序強化是綠色化學程序的尖端技術之一，已成為發展化工程序技術非常重要的趨勢，反應蒸餾與熱結合蒸餾是對高耗能的傳統蒸餾實施程序強化後可獲得非常明顯經濟效益的技術。在以酯交換法合成碳酸二苯酯的製程中，包括了一些串級反應與多個反應物和產物的分離，這些酯交換反應皆為受平衡限制的反應，但在以酚與碳酸二甲酯進行轉酯化反應系統中，因具有低轉化率、會發生副反應與產生共沸物的缺點，因此本研究以較具經濟效益的醋酸苯酯與碳酸二甲酯進行酯交換合成碳酸二苯酯之反應系統為對象，探討同時具有分離、反應與節能功能的反應蒸餾綠色製程之設計策略。為提高反應轉化率，本研究使用過量的碳酸二甲酯反應物進料，以年總成本為目標函數，設計醋酸甲酯、碳酸二甲酯與碳酸二苯酯產品符合高純度要求的最適化程序，並結合熱結合蒸餾技術，探討其對能源效率的影響，模擬結果顯示所設計之熱結合反應蒸餾程序，不僅可消除原反應蒸餾塔內之再混合效應，且可使反應段之反應物濃度更接近其進行反應所需之莫耳比，能源消耗可因此大幅降低，提供了更具經濟效益的碳酸二苯酯合成製程。

[1] A. K. Jana, "Heat integrated distillation operation," Applied Energy, vol. 87, pp. 1477-1494, 2010.
[2] I. Mueller and E. Y. Kenig, "Reactive distillation in a dividing wall column: Rate-based modeling and simulation," Industrial & Engineering Chemistry Research, vol. 46, pp. 3709-3719, May 23 2007.
[3] A. K. Kolah, N. S. Asthana, D. T. Vu, C. T. Lira, and D. J. Miller, "Reaction kinetics for the heterogeneously catalyzed esterification of succinic acid with ethanol," Industrial & Engineering Chemistry Research, vol. 47, pp. 5313-5317, Aug 6 2008.
[4] Y. T. Tsai, H. M. Lin, and M. J. Lee, "Kinetics of Catalytic Esterification of Propionic Acid with Methanol over Amberlyst 36," Industrial & Engineering Chemistry Research, vol. 50, pp. 1171-1176, Feb 2 2011.
[5] M. J. Lee, P. L. Chou, and H. M. Lin, "Kinetics of synthesis and hydrolysis of ethyl benzoate over Amberlyst 39," Industrial & Engineering Chemistry Research, vol. 44, pp. 725-732, Feb 16 2005.
[6] Y. S. Mahajan, R. S. Kamath, P. S. Kumbhar, and S. M. Mahajani, "Self-condensation of cyclohexanone over ion exchange resin catalysts: Kinetics and selectivity aspects," Industrial & Engineering Chemistry Research, vol. 47, pp. 25-33, Jan 2 2008.
[7] M. Schmitt and H. Hasse, "Phase equlibria for hexyl acetate reactive distillation," Journal of Chemical and Engineering Data, vol. 50, pp. 1677-1683, Sep-Oct 2005.
[8] J. C. Cardenas-Guerra, T. Lopez-Arenas, R. Lobo-Oehmichen, and E. S. Perez-Cisneros, "A reactive distillation process for deep hydrodesulfurization of diesel: Multiplicity and operation aspects," Computers & Chemical Engineering, vol. 34, pp. 196-209, Feb 2010.
[9] Y. C. Cheng and C. C. Yu, "Effects of feed tray locations to the design of reactive distillation and its implication to control," Chemical Engineering Science, vol. 60, pp. 4661-4677, Sep 2005.
[10] I. L. Chien, Y. P. Teng, H. P. Huang, and Y. T. Tang, "Design and control of an ethyl acetate process: coupled reactor/column configuration," Journal of Process Control, vol. 15, pp. 435-449, Jun 2005.
[11] W. J. Hung, I. K. Lai, Y. W. Chen, S. B. Hung, H. P. Huang, M. J. Lee, and C. C. Yu, "Process chemistry and design alternatives for converting dilute acetic acid to esters in reactive distillation," Industrial & Engineering Chemistry Research, vol. 45, pp. 1722-1733, Mar 1 2006.
[12] H. Y. Lee, Y. T. Tang, H. P. Huang, and I. L. Chien, "Bifurcation in the reactive distillation for ethyl acetate at lower Murphree plate efficiency," Journal of Chemical Engineering of Japan, vol. 39, pp. 642-651, Jun 2006.
[13] M. J. Okasinski and M. F. Doherty, "Prediction of heterogeneous reactive azeotropes in esterification systems," Chemical Engineering Science, vol. 55, pp. 5263-5271, Nov 2000.
[14] N. Ramzan, M. Faheem, R. Gani, and W. Witt, "Multiple steady states detection in a packed-bed reactive distillation column using bifurcation analysis," Computers & Chemical Engineering, vol. 34, pp. 460-466, Apr 2010.
[15] Y. T. Tang, H. P. Huang, and I. L. Chien, "Design of a complete ethyl acetate reactive distillation system," Journal of Chemical Engineering of Japan, vol. 36, pp. 1352-1363, Nov 2003.
[16] Y. T. Tang, Y. W. Chen, H. P. Huang, C. C. Yu, S. B. Hung, and M. J. Lee, "Design of reactive distillations for acetic acid esterification," AIChE Journal, vol. 51, pp. 1683-1699, Jun 2005.
[17] S. J. Wang, D. S. H. Wong, and E. K. Lee, "Effect of interaction multiplicity on control system design for a MTBE reactive distillation column," Journal of Process Control, vol. 13, pp. 503-515, Sep 2003.
[18] M. F. Doherty and J. D. Perkins, "Dynamics of Distillation Processes .3. Topological Structure of Ternary Residue Curve Maps," Chemical Engineering Science, vol. 34, pp. 1401-1414, 1979.
[19] S. Hauan, S. M. Schrans, and K. M. Lien, "Dynamic evidence of the multiplicity mechanism in methyl tert-butyl ether reactive distillation," Industrial & Engineering Chemistry Research, vol. 36, pp. 3995-3998, Sep 1997.
[20] Y. H. Jhon and T. H. Lee, "Dynamic simulation for reactive distillation with ETBE synthesis," Separation and Purification Technology, vol. 31, pp. 301-317, Jun 1 2003.
[21] Y. D. Lin, H. P. Huang, and C. C. Yu, "Relay feedback tests for highly nonlinear processes: Reactive distillation," Industrial & Engineering Chemistry Research, vol. 45, pp. 4081-4092, Jun 7 2006.
[22] S. J. Wang and D. S. H. Wong, "Control of reactive distillation production of high-purity isopropanol," Journal of Process Control, vol. 16, pp. 385-394, Apr 2006.
[23] M. F. Doherty and G. Buzad, "Reactive Distillation by Design," Chemical Engineering Research & Design, vol. 70, pp. 448-458, Sep 1992.
[24] R. Taylor and R. Krishna, "Modelling reactive distillation," Chemical Engineering Science, vol. 55, pp. 5183-5229, Nov 2000.
[25] C. P. Almeida-Rivera, P. L. J. Swinkels, and J. Grievink, "Designing reactive distillation processes: present and future," Computers & Chemical Engineering, vol. 28, pp. 1997-2020, Sep 15 2004.
[26] J. R. Fair, "Conceptual design of distillation system. By M. F. Doherty and M. F. Malone, McGraw-Hill, New York, 2001, 568 pp., 85.31," AIChE Journal, vol. 49, pp. 2452-2452, 2003.
[27] F. S. Atalay, "Buchbesprechung: Reactive Distillation. Von K. Sundmacher, A. Kienle," Chemie Ingenieur Technik, vol. 76, pp. 981-982, 2004.
[28] Luyben, W. L.; Yu, C. C. Reactive Distillation Design and Control. Wiley-VCH, New York, U.S.A. 2008
[29] V. H. Agreda, L. R. Partin, and W. H. Heise, "High-Purity Methyl Acetate Via Reactive Distillation," Chemical Engineering Progress, vol. 86, pp. 40-46, Feb 1990.
[30] M. G. Sneesby, M. O. Tade, and T. N. Smith, "Multiplicity and pseudo-multiplicity in MTBE and ETBE reactive distillation," Chemical Engineering Research & Design, vol. 76, pp. 525-531, May 1998.
[31] M. G. Sneesby, M. O. Tade, R. Datta, and T. N. Smith, "ETBE synthesis via reactive distillation .2. Dynamic simulation and control aspects," Industrial & Engineering Chemistry Research, vol. 36, pp. 1870-1881, May 1997.
[32] M. G. Sneesby, M. O. Tade, and T. N. Smith, "Two-point control of a reactive distillation column for composition and conversion," Journal of Process Control, vol. 9, pp. 19-31, Feb 1999.
[33] N. Vora and P. Daoutidis, "Analysis and nonlinear control of an ethyl acetate reactive distillation column," Proceedings of the 1998 American Control Conference, Vols 1-6, pp. 2113-2117, 1998.
[34] N. Vora and P. Daoutidis, "Nonlinear model reduction of reaction systems with multiple time scale dynamics," Proceedings of the 2001 American Control Conference, Vols 1-6, pp. 4752-4757, 2001.
[35] R. Monroy-Loperena, E. Perez-Cisneros, and J. Alvarez-Ramirez, "A robust PI control configuration for a high-purity ethylene glycol reactive distillation column," Chemical Engineering Science, vol. 55, pp. 4925-4937, Nov 2000.
[36] M. Al-Arfaj and W. L. Luyben, "Comparison of alternative control structures for an ideal two-product reactive distillation column," Industrial & Engineering Chemistry Research, vol. 39, pp. 3298-3307, Sep 2000.
[37] M. A. Al-Arfaj and W. L. Luyben, "Control study of ethyl tert-butyl ether reactive distillation," Industrial & Engineering Chemistry Research, vol. 41, pp. 3784-3796, Aug 2002.
[38] M. A. Al-Arfaj and W. L. Luyben, "Control of ethylene glycol reactive distillation column," AIChE Journal, vol. 48, pp. 905-908, Apr 2002.
[39] M. A. Al-Arfaj and W. L. Luyben, "Design and control of an olefin metathesis reactive distillation column," Chemical Engineering Science, vol. 57, pp. 715-733, Mar 2002.
[40] M. A. Al-Arfaj and W. L. Luyben, "Comparative control study of ideal and methyl acetate reactive distillation," Chemical Engineering Science, vol. 57, pp. 5039-5050, Dec 2002.
[41] M. A. Al-Arfaj and W. L. Luyben, "Plantwide control for TAME production using reactive distillation," AIChE Journal, vol. 50, pp. 1462-1473, Jul 2004.
[42] S. G. Huang, C. L. Kuo, S. B. Hung, Y. W. Chen, and C. C. Yu, "Temperature control of heterogeneous reactive distillation," AIChE Journal, vol. 50, pp. 2203-2216, Sep 2004.
[43] Y. T. Tang, H. P. Huang, and I. L. Chien, "Plant-wide control of a complete ethyl acetate reactive distillation process," Journal of Chemical Engineering of Japan, vol. 38, pp. 130-146, Feb 2005.
[44] S. J. Wang, D. S. H. Wong, and E. K. Lee, "Control of a reactive distillation column in the kinetic regime for the synthesis of n-butyl acetate," Industrial & Engineering Chemistry Research, vol. 42, pp. 5182-5194, Oct 15 2003.
[45] S. J. Wang and D. S. H. Wong, "Control of transesterification distillation for the production of methanol and n-butyl acetate," Journal of Chemical Engineering of Japan, vol. 39, pp. 340-350, Mar 2006.
[46] S. J. Wang and D. S. H. Wong, "Design and control of entrainer-added reactive distillation for fatty ester production," Industrial & Engineering Chemistry Research, vol. 45, pp. 9042-9049, Dec 20 2006.
[47] S. J. Wang, D. S. H. Wong, and S. W. Yu, "Design and control of transesterification reactive distillation with thermal coupling," Computers & Chemical Engineering, vol. 32, pp. 3030-3037, Dec 22 2008.
[48] S. J. Wang, C. C. Yu, and H. P. Huang, "Plant-wide design and control of DMC synthesis process via reactive distillation and thermally coupled extractive distillation," Computers & Chemical Engineering, vol. 34, pp. 361-373, Mar 5 2010.
[49] S. J. Wang, H. P. Huang, and C. C. Yu, "Design and Control of a Heat-Integrated Reactive Distillation Process to Produce Methanol and n-Butyl Acetate," Industrial & Engineering Chemistry Research, vol. 50, pp. 1321-1329, Feb 2011.
[50] S. B. Hung, I. K. Lai, H. P. Huang, M. J. Lee, and C. C. Yu, "Reactive distillation for two-stage reaction systems: Adipic acid and glutaric acid esterifications," Industrial & Engineering Chemistry Research, vol. 47, pp. 3076-3087, May 2008.
[51] I. K. Lai, S. B. Hung, W. J. Hung, C. C. Yu, M. J. Lee, and H. P. Huang, "Design and control of reactive distillation for ethyl and isopropyl acetates production with azeotropic feeds," Chemical Engineering Science, vol. 62, pp. 878-898, Feb 2007.
[52] I. K. Lai, Y. C. Liu, C. C. Yu, M. J. Lee, and H. P. Huang, "Production of high-purity ethyl acetate using reactive distillation: Experimental and start-up procedure," Chemical Engineering and Processing, vol. 47, pp. 1831-1843, Sep 2008.
[53] Y. D. Lin, J. H. Chen, J. K. Cheng, H. P. Huang, and C. C. Yu, "Process alternatives for methyl acetate conversion using reactive distillation. 1. Hydrolysis," Chemical Engineering Science, vol. 63, pp. 1668-1682, Mar 2008.
[54] S. T. Tung and C. C. Yu, "Effects of relative volatility ranking to the design of reactive distillation," AIChE Journal, vol. 53, pp. 1278-1297, May 2007.
[55] K. L. Zeng, C. L. Kuo, and I. L. Chien, "Design and control of butyl acrylate reactive distillation column system," Chemical Engineering Science, vol. 61, pp. 4417-4431, Jul 2006.
[56] H. Y. Lee, Y. C. Lee, I. L. Chien, and H. P. Huang, "Design and Control of a Heat-Integrated Reactive Distillation System for the Hydrolysis of Methyl Acetate," Industrial & Engineering Chemistry Research, vol. 49, pp. 7398-7411, Aug 18 2010.
[57] H. Y. Lee, C. H. Jan, I. L. Chien, and H. P. Huang, "Feed-splitting operating strategy of a reactive distillation column for energy-saving production of butyl propionate," Journal of the Taiwan Institute of Chemical Engineers, vol. 41, pp. 403-413, Jul 2010.
[58] H. Y. Lee, L. T. Yen, I. L. Chien, and H. P. Huang, "Reactive Distillation for Esterification of an Alcohol Mixture Containing n-Butanol and n-Amyl Alcohol," Industrial & Engineering Chemistry Research, vol. 48, pp. 7186-7204, Aug 5 2009.
[59] H. Y. Wei, A. Rokhmah, R. Handogo, and I. L. Chien, "Design and control of reactive-distillation process for the production of diethyl carbonate via two consecutive trans-esterification reactions," Journal of Process Control, vol. 21, pp. 1193-1207, Sep 2011.
[60] I. L. Chien, K. Chen, and C. L. Kuo, "Overall control strategy of a coupled reactor/columns process for the production of ethyl acrylate," Journal of Process Control, vol. 18, pp. 215-231, Mar-Apr 2008.
[61] S. B. Hung, M. J. Lee, Y. T. Tang, Y. W. Chen, I. K. Lai, W. J. Hung, H. P. Huang, and C. C. Yu, "Control of different reactive distillation configurations," AIChE Journal, vol. 52, pp. 1423-1440, Apr 2006.
[62] H. Y. Lee, H. P. Huang, and I. L. Chien, "Control of reactive distillation process for production of ethyl acetate," Journal of Process Control, vol. 17, pp. 363-377, Apr 2007.
[63] S. B. Hung, J. H. Chen, Y. D. Lin, H. P. Huang, M. J. Lee, J. D. Ward, and C. C. Yu, "Control of plantwide reactive distillation processes: Hydrolysis, transesterification and two-stage esterification," Journal of the Taiwan Institute of Chemical Engineers, vol. 41, pp. 382-402, Jul 2010.
[64] B. G. Rong and A. Kraslawski, "Optimal design of distillation flowsheets with a lower number of thermal couplings for multicomponent separations," Industrial & Engineering Chemistry Research, vol. 41, pp. 5716-5726, Nov 13 2002.
[65] I. M. Alatiqi and W. L. Luyben, "Alternative Distillation Configurations for Separating Ternary Mixtures with Small Concentrations of Intermediate in the Feed," Industrial & Engineering Chemistry Process Design and Development, vol. 24, pp. 500-506, 1985.
[66] A. J. Finn, "Consider Thermally Coupled Distillation," Chemical Engineering Progress, vol. 89, pp. 41-45, Oct 1993.
[67] D. W. Tedder and D. F. Rudd, "Parametric Studies in Industrial Distillation .1. Design Comparisons," AIChE Journal, vol. 24, pp. 303-315, 1978.
[68] S. Hernandez and A. Jimenez, "Design of optimal thermally-coupled distillation systems using a dynamic model," Chemical Engineering Research & Design, vol. 74, pp. 357-362, Apr 1996.
[69] S. Hernandez and A. Jimenez, "Design of energy-efficient Petlyuk systems," Computers & Chemical Engineering, vol. 23, pp. 1005-1010, Aug 1 1999.
[70] R. Agrawal and Z. T. Fidkowski, "Are thermally coupled distillation columns always thermodynamically more efficient for ternary distillations?," Industrial & Engineering Chemistry Research, vol. 37, pp. 3444-3454, Aug 1998.
[71] G. Dunnebier and C. C. Pantelides, "Optimal design of thermally coupled distillation columns," Industrial & Engineering Chemistry Research, vol. 38, pp. 162-176, Jan 1999.
[72] R. Agrawal, "Synthesis of multicomponent distillation column configurations," AIChE Journal, vol. 49, pp. 379-401, Feb 2003.
[73] K. A. Amminudin, R. Smith, D. Y. C. Thong, and G. P. Towler, "Design and optimization of fully thermally coupled distillation columns part 1: Preliminary design and optimization methodology," Chemical Engineering Research & Design, vol. 79, pp. 701-715, Oct 2001.
[74] K. A. Amminudin and R. Smith, "Design and optimization of fully thermally coupled distillation columns part 2: Application of dividing wall columns in retrofit," Chemical Engineering Research & Design, vol. 79, pp. 716-724, Oct 2001.
[75] J. L. Blancarte-Palacios, M. N. Bautista-Valdes, S. Hernandez, V. Rico-Ramirez, and A. Jimenez, "Energy-efficient designs of thermally coupled distillation sequences for four-component mixtures," Industrial & Engineering Chemistry Research, vol. 42, pp. 5157-5164, Oct 15 2003.
[76] S. Bruggemann and W. Marquardt, "Rapid screening of design alternatives for nonideal multiproduct distillation processes," Computers & Chemical Engineering, vol. 29, pp. 165-179, Dec 15 2004.
[77] J. A. Caballero and I. E. Grossmann, "Design of distillation sequences: from conventional to fully thermally coupled distillation systems," Computers & Chemical Engineering, vol. 28, pp. 2307-2329, Oct 15 2004.
[78] O. A. Flores, J. C. Cardenas, S. Hernandez, and V. Rico-Ramirez, "Thermodynamic analysis of thermally coupled distillation sequences," Industrial & Engineering Chemistry Research, vol. 42, pp. 5940-5945, Nov 12 2003.
[79] I. J. Halvorsen and S. Skogestad, "Minimum energy consumption in multicomponent distillation. 1. V-min diagram for a two-product column," Industrial & Engineering Chemistry Research, vol. 42, pp. 596-604, Feb 5 2003.
[80] I. J. Halvorsen and S. Skogestad, "Minimum energy consumption in multicomponent distillation. 2. Three-product Petlyuk arrangements," Industrial & Engineering Chemistry Research, vol. 42, pp. 605-615, Feb 5 2003.
[81] I. J. Halvorsen and S. Skogestad, "Minimum energy consumption in multicomponent distillation. 3. More than three products and generalized Petlyuk arrangements," Industrial & Engineering Chemistry Research, vol. 42, pp. 616-629, Feb 5 2003.
[82] Y. H. Kim, "Structural design of extended fully thermally coupled distillation columns," Industrial & Engineering Chemistry Research, vol. 40, pp. 2460-2466, May 30 2001.
[83] Y. H. Kim, "Rigorous design of extended fully thermally coupled distillation columns," Chemical Engineering Journal, vol. 89, pp. 89-99, Oct 28 2002.
[84] Y. H. Kim, "Structural design and operation of a fully thermally coupled distillation column," Chemical Engineering Journal, vol. 85, pp. 289-301, Jan 28 2002.
[85] B. Kolbe and S. Wenzel, "Novel distillation concepts using one-shell columns," Chemical Engineering and Processing, vol. 43, pp. 339-346, Mar 2004.
[86] J. Y. Lee, Y. H. Kim, and K. S. Hwang, "Application of a fully thermally coupled distillation column for fractionation process in naphtha reforming plant," Chemical Engineering and Processing, vol. 43, pp. 495-501, Apr 2004.
[87] N. Ramirez and A. Jimenez, "Two alternatives to thermally coupled distillation systems with side columns," AIChE Journal, vol. 50, pp. 2971-2975, Nov 2004.
[88] B. G. Rong, A. Kraslawski, and L. Nystrom, "Design and synthesis of multicomponent thermally coupled distillation flowsheets," Computers & Chemical Engineering, vol. 25, pp. 807-820, May 1 2001.
[89] B. G. Rong, A. Kraslawski, and I. Turunen, "Synthesis of heat-integrated thermally coupled distillation systems for multicomponent separations," Industrial & Engineering Chemistry Research, vol. 42, pp. 4329-4339, Sep 17 2003.
[90] B. G. Rong, A. Kraslawski, and I. Turunen, "Synthesis of functionally distinct thermally coupled configurations for quaternary distillations," Industrial & Engineering Chemistry Research, vol. 42, pp. 1204-1214, Mar 19 2003.
[91] I. M. Alatiqi and W. L. Luyben, "Control of a Complex Sidestream Column/Stripper Distillation Configuration," Industrial & Engineering Chemistry Process Design and Development, vol. 25, pp. 762-767, Jul 1986.
[92] J. G. Segovia-Hernandez, M. Ledezma-Martinez, M. Carrera-Rodriguez, and S. Hernandez, "Controllability analysis of thermally coupled distillation systems: Five-component mixtures," Industrial & Engineering Chemistry Research, vol. 46, pp. 211-219, Jan 3 2007.
[93] M. Serra, A. Espuna, and L. Puigjaner, "Controllability of different multicomponent distillation arrangements," Industrial & Engineering Chemistry Research, vol. 42, pp. 1773-1782, Apr 16 2003.
[94] M. I. A. Mutalib and R. Smith, "Operation and control of dividing wall distillation columns - Part 1: Degrees of freedom and dynamic simulation," Chemical Engineering Research & Design, vol. 76, pp. 308-318, Mar 1998.
[95] M. Serra, M. Perrier, A. Espuna, and L. Puigjaner, "Analysis of different control possibilities for the divided wall column: feedback diagonal and dynamic matrix control," Computers & Chemical Engineering, vol. 25, pp. 859-866, May 1 2001.
[96] T. Adrian, H. Schoenmakers, and M. Boll, "Model predictive control of integrated unit operations: Control of a divided wall column," Chemical Engineering and Processing, vol. 43, pp. 347-355, Mar 2003.
[97] S. J. Wang and D. S. H. Wong, "Controllability and energy efficiency of a high-purity divided wall column," Chemical Engineering Science, vol. 62, pp. 1010-1025, Feb 2007.
[98] T. Herbert, "Practical distillation control," in Practical Experiences with Predictive Control (Ref. No. 2000/023), IEE Seminar on, 2000, pp. 2/1-2/2.
[99] S. J. Wang, C. J. Lee, S.-S. Jang, and S. S. Shieh, "Plant-wide design and control of acetic acid dehydration system via heterogeneous azeotropic distillation and divided wall distillation," Journal of Process Control, vol. 18, pp. 45-60, 2008.
[100] H. Ishii, M. Goyal, M. Ueda, K. Takeuchi, and M. Asai, "Oxidative carbonylation of phenol to diphenyl carbonate catalyzed by Pd complex with 2,2 '-bipyridyl ligands," Applied Catalysis a-General, vol. 201, pp. 101-105, Jun 26 2000.
[101] I. Hatanaka, N. Mitsuyasu, G. Yin, Y. Fujiwara, T. Kitamura, K. Kusakabe, and T. Yamaji, "The mechanic study of the Pd-catalyzed synthesis of diphenylcarbonate with heteropolyacid as a cocatalyst," Journal of Organometallic Chemistry, vol. 674, pp. 96-100, May 14 2003.
[102] W. Xue, J. C. Zhang, Y. J. Wang, Q. Zhao, and X. Q. Zhao, "Effect of promoter copper on the oxidative carbonylation of phenol over the ultrafine embedded catalyst Pd-Cu-O/SiO2," Journal of Molecular Catalysis a-Chemical, vol. 232, pp. 77-81, May 3 2005.
[103] H. Yasuda, K. Watarai, J. C. Choi, and T. Sakakura, "Effects of bulky ligands and water in Pd-catalyzed oxidative carbonylation of phenol," Journal of Molecular Catalysis a-Chemical, vol. 236, pp. 149-155, Jul 18 2005.
[104] L. Ronchin, A. Vavasori, E. Amadio, G. Cavinato, and L. Toniolo, "Oxidative carbonylation of phenols catalyzed by homogeneous and heterogeneous Pd precursors," Journal of Molecular Catalysis a-Chemical, vol. 298, pp. 23-30, Feb 2 2009.
[105] H. X. Guo, H. P. Chen, Y. H. Liang, Y. L. Rui, J. D. Lu, and Z. D. Fu, "Direct synthesis of diphenyl carbonate with heterogeneous catalyst and optimal synthesis conditions of the support prepared by sol-gel method," Chinese Journal of Chemical Engineering, vol. 16, pp. 223-227, Apr 2008.
[106] F. M. Mei, G. X. Li, J. Nie, and H. B. Xu, "A novel catalyst for transesterification of dimethyl carbonate with phenol to diphenyl carbonate: samarium trifluoromethanesulfonate," Journal of Molecular Catalysis a-Chemical, vol. 184, pp. 465-468, Jun 17 2002.
[107] W. Q. Zhou, X. Q. Zhao, Y. J. Wang, and J. Y. Zhang, "Synthesis of diphenyl carbonate by transesterification over lead and zinc double oxide catalyst," Applied Catalysis a-General, vol. 260, pp. 19-24, Mar 25 2004.
[108] H. Y. Niu, J. Yao, Y. Wang, and G. Y. Wang, "Cp2TiCl2 used as a catalyst for the transesterification between dimethyl carbonate and phenol to diphenyl carbonate," Journal of Molecular Catalysis a-Chemical, vol. 235, pp. 240-243, Jul 1 2005.
[109] A. V. Biradar, S. B. Umbarkar, and M. K. Dongare, "Transesterification of diethyl oxalate with phenol using MoO3/SiO2 catalyst," Applied Catalysis a-General, vol. 285, pp. 190-195, May 10 2005.
[110] D. S. Tong, J. Yao, Y. Wang, H. Y. Niu, and G. Y. Wang, "Transesterification of dimethyl carbonate with phenol to diphenyl carbonate over V2O5 catalyst," Journal of Molecular Catalysis a-Chemical, vol. 268, pp. 120-126, May 1 2007.
[111] Z. Du, Y. Xiao, T. Chen, and G. Wang, "Catalytic study on the transesterification of dimethyl carbonate and phenol to diphenyl carbonate," Catalysis Communications, vol. 9, pp. 239-243, Feb 2008.
[112] S. J. Wang, C. C. Yu, and H.-P. Huang, "Plant-wide design and control of DMC synthesis process via reactive distillation and thermally coupled extractive distillation," Computers & Chemical Engineering, vol. 34, pp. 361-373, 2010.
[113] 沈榮春, 方云進, 肖文德, and 朱開宏, "碳酸二甲酯与醋酸苯酯合成碳酸二苯酯的研究," 石油化工, vol. 31, 2002.
[114] 楊麟均, "碳酸二苯酯反應蒸餾程序之設計與控制", 國立台灣科技大學化學工程所碩士論文,2011.