高鐵酸鉀的製備及應用於降解四環素(TC), 鄰苯二甲酸二甲酯(DMP), 和泰勒菌素(TYL)

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研究生：	楊世芬 Yang, Shih Fen
論文名稱：	高鐵酸鉀的製備及應用於降解四環素(TC), 鄰苯二甲酸二甲酯(DMP), 和泰勒菌素(TYL) Preparation of Potassium Ferrate(VI) for degradation of Tetracycline (TC), Dimethyl Phthalate ester (DMP), and Tylosin (TYL)
指導教授：	董瑞安 Doong, Ruey An
口試委員:	孫毓璋 Sun, Yuh Chang 張淑閔 Chang, Sue Min
學位類別：	碩士 Master
系所名稱：	原子科學院 - 生醫工程與環境科學系 Department of Biomedical Engineering and Environmental Sciences
論文出版年：	2015
畢業學年度：	103
語文別：	中文
論文頁數：	93
中文關鍵詞：	高鐵(VI)酸鉀、二氧化鈦(TiO2) 、UV照射、四環素(TC) 、鄰苯二甲酸二甲酯 (DMP) 、泰樂菌素(TYL) 、電子順磁共振譜(EPR)
外文關鍵詞：	Ferrate(VI), TiO2, UV irradiation, Tetracycline (TC), Dimethyl phthalate ester (DMP), Tylosin (TYL), EPR spectrum
相關次數：	點閱：2 下載：0
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高鐵(VI)酸鉀是一種具有高氧化電位的強氧化劑，且因其無毒性之產品——鐵(III)離子或鐵(III)氫氧化物——高鐵(VI)酸鉀也是綠色化學藥劑。在本研究中，使用高鐵(VI)酸鉀來降解新興污染物，包括四環素（TC）、鄰苯二甲酸二甲酯（DMP）和泰樂菌素（TYL），並在pH值7.0 -10.0 的範圍進行研究。經由液相色譜-質譜法（LC-MS），本研究中還確定了高鐵(VI)酸鉀降解新興污染物的副產品。高鐵(VI)酸鉀對水溶液中的TC，DMP和TYL的降解具有良好的氧化潛力。由電子順磁共振（EPR）和液相色譜-質譜法顯示，高鐵(VI)酸鉀可產生鐵-氧自由基（iron-oxo radicals），自由基與 DMP的芳香烴環反應，生成di-hydroyxl-DMP和tri-hydroyxl-DMP。研究結果顯示二氧化鈦（TiO2）/ UV輻射的添加可增強DMP的降解，因其可生成氫氧自由基（．OH）與DMP的烷基鏈反應，產生monomethyl phthalate和 mono-hygroxyl-phthalate。此外，研究中也探討了高鐵(VI)酸鉀結合二氧化鈦（TiO2）/ UV輻射對TYL的分解。高鐵(VI)酸鉀可迅速且有效的分解TYL，並在1分鐘內完全反應。由研究結果可清楚地顯示，對四環素、鄰苯二甲酸二甲酯、泰樂菌素的分解而言，高鐵(VI)酸鉀是一種有效的綠色化學藥劑，同時也可成為水和廢水處理中的新興污染物移除之創新進階技術。

Ferrate(VI) is a powerful oxidant with the high oxidation potential, and a green chemical with its non-toxic product, i.e. ferric ions or ferric hydroxides. In this syudy, the potential use of ferrate(VI) for the degradation of emerging pollutants including tetracycline (TC), dimethyl phthalates (DMP) and tylosin (TYL) at various pHs ranging from 7.0－10.0 was investigated. The degradation byproducts of emerging pollutants by ferrate(VI) were also identified by liquid chromatography-mass spectrometry. ferrate(VI) exhibits the good oxidation potential for the degradaation of TC, DMP and TYL in aqueous solutions. EPR and LC-MS spectra showed that ferrate(VI) can produce iron-oxo radicals to attack the aromatic ring of DMP to produce di-hydroyxl-DMP and tri-hydroyxl-DMP. Addition of TiO2 improved the DMP degradation by ferrate(VI) under UV light irradation and the produced ．OH radicals attacked the alkyl chains of DMP yo form monomethyl phthalate and mono-hygroxyl-phthalate. In addition, the decomposition of TYL by ferrate(VI) in the presence of TiO2/UV irradition was investigated. Ferrate(VI) is an effective chemical to rapidly decompose TYL and the reaction can be completed within 1 min. Results obtained in this study clearly indicate that ferrate(VI) is an effective green chemical for decomposition of tetracycline, dimethyl phthalate, and tylosin, which open an avenue to design the new advanced technology for removal of emerging pollutants in water and wastewater treatment.

謝誌        I
中文摘要        II
Abstrct        III
Content Index    IV
Figure Index    VI
Table Index    VIII
Chapter 1 Motivation and Objective    1
1    Motivation    2
2    Objective    3
Chapter 2 Background and theory    5
1    Potassium Ferrate（K2FeO4）    6
1.1 Properties and Advantages of Possium Ferrate    6
1.2 Preparation of Possium Ferrate    9
1.3 Degradation of Environmental Contaminents by Possium Ferrate    11
1.4 Mechanism of Fe(VI) as an oxidant    20
1.5 Quantitation of Fe(VI)    25
2    Titanium dioxide（TiO2）    27
3    Degradation of environmental contaminants by ferrate    30
3.1 Tetracyclin    30
3.2 Dimethyl Phthalates（DMP）    31
3.3 Tylosin (TYL)    33
Chapter 3 Materials and methods    37
1 Chemicals    38
2 Preparation of potassium ferrate    39
3 Stability of ferrate(VI)    40
4 Degradation of chemicals by Fe(VI)    40
4.1 Degradation of Tetracycline    40
4.2 Degradation of Dimethyl phthalate    40
4.3 Degradation of Tylosin    41
5 Analytical methods    41
5.1 GC and LCMS for dimethyl phthalate    41
5.2 EPR performance    42
5.3 HPLC for Tylosin    43
Chapter 4 Results and discussion    44
1 Preparation of Potassium Ferrate    45
2 Sensitivity of ABTS method    45
3 Degradation of tetracycline by Fe(VI)    47
3.1 Stoichiometry    47
3.2 Degradation of tetracycline    49
4 Degradation of DMP with Fe(VI)    53
4.1 Degradation of DMP by Ferrate(VI)    53
4.2 Effect of TiO2/UV on the DMP degradation by ferrate(VI)    56
4.3 Possible reaction mechanism    61
5 Degradation of tylosin by Fe(VI)    67
Chapter 5 Conclusions    69
References        71
Appedix        77

                                

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