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研究生: 張智豪
Chang, Chi-Hao
論文名稱: 多鐵性材料Ba2Mg2Fe12O22的磁性相變
Magnetic Transitions of Multiferroic Hexaferrite Ba2Mg2Fe12O22
指導教授: 黃迪靖
Huang, D. J.
口試委員:
學位類別: 碩士
Master
系所名稱: 理學院 - 物理學系
Department of Physics
論文出版年: 2009
畢業學年度: 97
語文別: 英文
論文頁數: 67
中文關鍵詞: 磁性相變多鐵性軟X光共振散射
外文關鍵詞: Ba2Mg2Fe12O22, magnetic transition, multiferroics, soft x-ray resonant scattering
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  • 多鐵性是指一個材料在同一個狀態下有兩個或兩個以上的鐵性質,其中有一個特別的多鐵性是磁電效應目前受到很多注目,所謂的磁電效應是用外加電場來控制材料內部的磁極,或者是利用外加磁場來控制材料的電極,六方晶系的Ba2Mg2Fe12O22就是磁電效應材料,它是利用微弱的外加磁場(0.03 T)就可以控制材料的電極,然而這個現象尚未完全釐清。我們利用超導量子干涉儀(SQUID)、軟X光吸收光譜包括磁旋光二元性(MCD)以及共振軟X光磁性散射來研究Ba2Mg2Fe12O222磁性以及其相變,實驗數據顯示出Ba2Mg2Fe12O22有各向異性的自旋有序性,並且有一個commersurate-incommeersurate的磁性相變,二維的共振X光散射數據展現出Ba2Mg2Fe12O22在c軸方向的自旋與自旋之間的耦合微弱,因為如此可能會有微弱的外加磁場可以控制Ba2Mg2Fe12O22電極化的情況。


    Multiferroics are materials that exhibit more than one primary ferroic order parameter
    in single phase. A special kind of multiferroics with a gigantic magnetoelectric coupling has attracted much attention. Haxeferrite Ba2Mg2Fe12O22 is a particularly interesting magnetoelectric material because its electric polarization can be controlled by a low magnetic field. However, such a multiferroic feature is far from being understood. We here investigated magnetic properties and transitions of Ba2Mg2Fe12O22 by using a superconducting quantum interference device (SQUID), soft x-ray absorption including magnetic circular dichroism, and resonant soft x-ray magnetic scattering. The results indicate that Ba2Mg2Fe12O22 exhibits an anisotropic spin ordering and a commensurate-to-incommensurate magnetic transition. Two-dimension distributions of magnetic scattering reveal a weak spin-spin correlation along the c axis, leading to a possible scenario for the low-field control of electric polarization discovered in haxeferrite Ba2Mg2Fe12O22.

    1 Introduction of Magnetoelectricity 1.1 Multiferroics 1.1.1 Magnetoelectric materials 1.2 Theory of ME effect 1.2.1 Landau theory 1.3 Spin current model 1.4 Exchange Interaction 1.4.1 Superexchange 2 Experimental Techniques and Setup 21 2.1 Diffractometer 2.2 Soft X-ray Absorption Spectroscopy 2.2.1 Absorption spectrum 2.2.2 The interaction between the electrons and photon 2.2.3 Electron and fluorescence yields 2.2.4 Magnetic-Circular-Dichroism 2.2.5 Sum rules 2.3 Soft x-ray scattering 2.3.1 Resonant scattering 2.3.2 Resonant scattering in quantum mechanics 2.3.3 Resonant X-ray magnetic scattering 2.4 Soft x-ray detector 3 Magnetic Transitions of Multiferroic Hexaferrite Ba2Mg2Fe12O22 3.1 Introduction 3.1.1 Haxaferrite 3.2 Experiment 3.2.1 Soft x-ray absorption 3.2.2 SQUID results 3.2.3 MCD results 3.3 Resonant soft x-ray magnetic scattering 3.3.1 Neutron diffraction 4 Conclusion

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