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研究生: 陳建男
Chen, Jian Nan
論文名稱: 微型化可攜式氨氣感測系統
The miniaturized portable ammonia sensing system
指導教授: 洪勝富
Horng, Sheng Fu
口試委員: 冉曉雯
Zan, Hsiao Wen
呂家榮
Lu, Chia Jung
孟心飛
Meng, Hsin Fei
學位類別: 碩士
Master
系所名稱: 電機資訊學院 - 電子工程研究所
Institute of Electronics Engineering
論文出版年: 2015
畢業學年度: 103
語文別: 中文
論文頁數: 74
中文關鍵詞: 氨氣感測呼氣氨即時性感測非侵入式
相關次數: 點閱:3下載:0
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  • 本篇論文利用Poly(3-octylthiophene-2,5-diyl)並搭配刮刀塗佈聚苯乙烯奈米球(Nano-sized polystyrene sphere)技術製作高孔洞密度垂直式二極體元件,藉由偵測通過氨氣氣體造成的電流變化得知氨氣的濃度,並且擁有製程成本低廉、即時偵測、高靈敏度、非侵入式等優勢。並且著手將整體感測系統微小化,通過各種實驗測試排除人體呼氣水氣,找出合適的氣體採集方式提供呼氣感測另外該方法必須能穩定度的量測,並且系統能夠偵測到100 ppb氨氣濃度,而在本篇論文中也提到利用許多不同量測方法來簡化量測系統減少系統成本,另外可搭配微處理器模組來運算感測元件電壓降變化,取代量測機組使感測系統成為可攜式即時量測設備。


    We use Poly (3-octylthiophene-2,5-diyl) to serve as sensing material and producing a high porous density vertical diode by blade coating process to detect ammonia. The ammonia gas sensor in air background sensing system can detect the ammonia concentration from 100 part per billion (ppb) to 1 part per million (ppm) with good resolution. Besides, we try many ways to enhance the sensing system’s reliability. For example, utilizing the gastight syringe to avoid the electric signal noise during gas injection. And we also investigate how to collect human breath properly, thus sensing system can detect breath-ammonia without disturbing by the high humidity in breath or the variation of background flow. In addition, high-end measurement instrument is replaced by a microprocessor, which computes ammonia sensor’s voltage signal to identify the ammonia concentration to miniaturize sensing system. The miniaturized portable ammonia sensing system has many advantages such as non-invasive sensing, real-time sensing, low-cost and room temperature operation.

    摘要 2 Abstract 3 致謝 4 目錄 6 圖目錄 8 表目錄 10 第一章 緒論 11 1-1研究動機 11 1-2 先期成果 12 1-2-1先期空氣背景系統 14 1-2-3呼氣感測系統文獻 15 第二章 氣體感測有機二極體 19 2-1 有機材料的特性與簡介 19 2-2 有機二極體操作原理 21 2-3 金屬與半導體接面原理 23 2-4 載子傳輸理論及空間電荷限制理論 25 2-4-1 塊材限制及空間電荷限制 25 2-4-2 接面限制之熱離子發射理論與穿隧效應 26 2-3 元件製程 28 2-3-1 元件基板之圖樣化定義製程 28 3-2-2 利用有機材料製作垂直式孔洞結構二極體 29 第三章 實驗結果與討論 35 3-1 系統架設介紹 35 3-2 氮氣背景系統及氨氣感測實驗 36 3-2-1氮氣背景系統 36 3-2-2氮氣背景系統感測實驗 38 3-3 空氣背景系統及氨氣感測實驗 41 3-3-1空氣背景系統 41 3-3-2低濕度模組Dryer 43 3-3-3空氣背景系統感測實驗 47 3-3-4人體呼氣採氣感測 48 3-3-5空氣背景系統移除抽氣幫浦實驗 54 3-4環境背景擴散實驗 59 3-5 空氣量測系統體積微型化 61 3-5-1 系統體積微縮 61 3-5-2 量測機組微小化 64 3-6 製程元件差異性 68 3-6-1 不同批次差異性 68 3-6-2 增加感測層厚度減少元件製程差異性 70 第四章 研究總結與未來展望 72 第五章 參考文獻 74

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