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研究生: 林有為
You-Wei Lin
論文名稱: 以BULGE TEST量測鎳矽化物機械性質
Mechanical Properties of Nickel Silicide Measured by Bulge Test
指導教授: 蔡哲正
Cho-Jen Tsai
口試委員:
學位類別: 碩士
Master
系所名稱: 工學院 - 材料科學工程學系
Materials Science and Engineering
論文出版年: 2006
畢業學年度: 94
語文別: 中文
論文頁數: 54
中文關鍵詞: Bulge test鎳矽化物機械性質楊氏係數
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  • 薄膜廣泛的應用在日常生活中。為了確保元件內的材料在長時間使用下的可靠度,薄膜機械性質的的得知便是十分的重要。然而當薄膜尺寸縮小時,其機械性質的量測是較為困難的。
    鎳矽化物廣泛使用在積體電路來作為連接使用,降低元件中的接觸電阻與片電阻,以改善電路的效能。本實驗將利用鼓膜測試對鎳矽化物的機械性質做一系列的探討。鼓膜測試為一種量測薄膜機械性質的方法,量測方式為對一懸浮薄膜吹氣,記錄其壓力與鼓起高度的關係,藉由資料處理及曲線凝合,與Vlassak等人所推導公式對照之後,可求得薄膜的殘留應力、楊氏係數、浦松比。
    實驗量測出Ni2Si、NiSi、NiSi2的楊氏係數分別為180±30、136±16、265±42 GPa。其中NiSi2的量測值與文獻上160GPa相差甚遠,仍須做進一步驗證。TEM與AES的分析結果均指出Ni2Si的試片製備有問題,其量測結果需在檢驗與探討。
    鼓膜測試的準確性受到膜厚量測的準確性影響極大,本實驗薄膜厚度大約為20nm左右,受到粗糙度的影響,使得厚度的量測準確性受到影響,因此楊氏係數的誤差可大到10%以上。本實驗的量測方法在奈米尺度的薄膜仍有改善的空間。


    總目錄 總目錄 I 致謝 III 摘要 VI 圖目錄 VII 表目錄 IX 第一章 前言 1 1.1 薄膜 1 1.2 量測薄膜機械性質的技術 2 曲率量測(Wafer curvature) 2 微拉伸測試(Micro-tensile test) 3 X-ray繞射儀(X-ray diffraction) 3 應變導致彈性彎曲係數不穩定之力學量測 (Strain-induced elastic buckling instability for mechanical measurements, SIEBIMM) 4 懸臂樑(Cantilever beam test) 5 壓痕量測(Depth-sensing indentation) 6 鼓膜測試(Bulge test) 7 1.3 實驗動機 8 第二章 鼓膜測試----一種量測薄膜機械性質的方法 10 2.1鼓膜測試的目的 10 2.2圓形薄膜的鼓膜模型 11 2.3 圓形薄膜鼓膜模型的能量最低解 13 2.4其它幾何形狀的薄膜(Noncircular geometries) 14 長方形薄膜(Infinitely long rectangular membranes) 14 正方形薄膜(Suare membrane) 15 鼓膜測試的通解(Generalized bulge equation) 16 2.5 複合薄膜的分析 17 第三章 鼓膜測試系統 18 3.1 鼓膜測試系統 18 外腔體(The external chamber) 18 內腔體(The inner chamber) 18 3.2 干涉儀 21 影像分析流程 24 3.3 試片準備 24 氮化矽薄膜的沉積 26 微影 26 反應性離子蝕刻(Reactive ion etching) 27 非等向性濕式蝕刻(Anisotropic wet etching) 27 試片的黏著(Sample mounting) 29 第四章 結果與討論 30 4.1實驗與分析 30 試片製備過程 30 鼓膜測試 30 浦松比的量測 31 薄膜厚度的量測 33 粗糙度 34 相鑑定 35 鼓膜測試結果 37 4.2結果比較與誤差討論 37 結果比較 37 誤差討論 38 4.3結論 39 參考文獻 41 附錄 47 鼓膜測試結果 47 粗糙度量測結果 53

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