本論文分為三個部份。在第一個部份，我們利用添加
ZrOCl2、改變矽源、
改變水量、改變pH值、改變Zr4+濃度以及改變攪拌時間等方法調控中孔洞二氧
化矽SBA-15的形貌，得到面積大而且厚度薄的片狀SBA-15。在此合成系統中由
於二氧化矽表面含有高含量的Zr4+，其酸性可以催化糠醇的聚合，因此我們在
第二部份中，以片狀二氧化矽作為模板，合成出類似CMK-5的片狀中孔洞碳
材。在第三部份中，
我們以片狀中孔洞碳為載體，將高分子單體以自由基聚合
的方式使高分子交織於中孔洞碳材的孔洞中，形成高分子/中孔洞碳複合材料，
並應用於氣體感測器作氣體的偵測。

The
thesis
is
divided
into
three
parts.
In
the
first
part,
we
modulated
the
morphology
of
mesoporous
silica
SBA-15
in
the
presence
of
ZrOCl2
by
controlling
several
synthesis
parameters,
such
as
silica
source,
the
concentration
of
surfactant
and
silica
source,
the
concentration
of
ZrOCl2,
the
value
of
pH,
or
by
changing
the
time
for
stirring
after
the
addition
of
silica
source.
The
synthesis
parameters
were
controlled
in
order
to
obtain
platelet
SBA-15
with
large
area
and
thin
thickness.
The
high
content
of
Zr4+
on
the
SBA-15
surface
could
catalyze
the
polymerization
of
furfuryl
alcohol,
thus
in
the
second
part,
we
synthesized
CMK-5-like
platelet
mesoporous
carbon
by
nanocasting
and
the
platelet
SBA-15
was
used
as
hard
template.
In
the
third
part,
monomers
of
various
polymers
were
polymerized
inside
platelet
mesoporous
carbon
by
free-radical
polymerization.
We
used
these
polymer/mesoporous
carbon
nanocomposite
as
sensing
materials
and
applied
on
gas
sensor
for
gas
detection.

[1]
Ying, J. Y.;Mehnert, C. P.;Wong, M. S., Angew. Chem. Int. Ed. 1999, 38,
56.
[2]
Beck, J. S.;Vartuli, J. C.;Roth, W. J.;Leonowicz, M. E.;Kresge, C.
T.;Schmitt, K. D.;Chu, C. T. W.;Olson, D. H.;Sheppard, E.
W.;McCullen, S. B.;Higgins, J. B.;Schlenker, J. L., J. Am. Chem. Soc.
1992, 114, 10834.
[3]
Kresge, C. T.;Leonowicz, M. E.;Roth, W. J.;Vartuli, J. C.;Beck, J. S.,
Nature 1992, 359, 710.
[4]
Huo, Q. S.;Margolese, D. I.;Ciesla, U.;Feng, P. Y.;Gier, T. E.;Sieger,
P.;Leon, R.;Petroff, P. M.;Schuth, F.;Stucky, G. D., Nature 1994, 368,
317.
[5]
Stucky, G. D.;Petroff, P. M.;Leon, R.;Huo, Q., Science 1995, 268, 1324.
[6]
Stucky, G. D.;Zhao, D.;Chmelka, B. F.;Fredrickson, G. H.;Melosh,
N.;Huo, Q.;Feng, J., Science 1998, 279, 548.
[7]
Sakamoto, Y.;Kaneda, M.;Terasaki, O.;Zhao, D. Y.;Kim, J. M.;Stucky,
G.;Shim, H. J.;Ryoo, R., Nature 2000, 408, 449.
[8]
Shen, S. D.;Li, Y. Q.;Zhang, Z. D.;Fan, J.;Tu, B.;Zhou, W. Z.;Zhao, D.
Y., Chem. Commun. 2002, 2212.
[9]
El Haskouri, J.;Cabrera, S.;Caldes, M.;Guillem, C.;Latorre, J.;Beltran,
A.;Beltran, D.;Marcos, M. D.;Amoros, P., Chem. Mater. 2002, 14, 2637.
[10]
Fan, J.;Yu, C. Z.;Gao, T.;Lei, J.;Tian, B. Z.;Wang, L. M.;Luo, Q.;Tu,
B.;Zhou, W. Z.;Zhao, D. Y., Angew. Chem. Int. Ed. 2003, 42, 3146.
[11]
Garcia-Bennett, A. E.;Miyasaka, K.;Terasaki, O.;Che, S. N., Chem.
Mater. 2004, 16, 3597.
[12]
El-Safty, S. A.;Mizukami, F.;Hanaoka, T., J. Mater. Chem. 2005, 15,
2590.
[13]
Garcia-Bennett, A. E.;Kupferschmidt, N.;Sakamoto, Y.;Che, S.;Terasaki,
O., Angew. Chem. Int. Ed. 2005, 44, 5317.
[14]
Shen, S. D.;Garcia-Bennett, A. E.;Liu, Z.;Lu, Q. Y.;Shi, Y. F.;Yan, Y.;Yu,
C. Z.;Liu, W. C.;Cai, Y.;Terasaki, O.;Zhao, D. Y., J. Am. Chem. Soc.
2005, 127, 6780.
[15]
Gao, C. B.;Sakamoto, Y.;Sakamoto, K.;Terasaki, O.;Che, S. N., Angew.
Chem. Int. Ed. 2006, 45, 4295.
[16]
El-Safty, S. A.;Kiyozumi, Y.;Hanaoka, T.;Mizukami, F., Mater. Lett.
2008, 62, 2950.
[17]
Neumann, R.;Khenkin, A. M., Chem. Commun. 1996, 2643.
[18]
Hoffmann, F.;Cornelius, M.;Morell, J.;Froba, M., Angew. Chem. Int. Ed.
2006, 45, 3216.
[19]
Tiemann, M., Chem. Mater. 2008, 20, 961.
[20]
Stockholm, L., Surfactants and Polymers in Aqueous Solution, John
Wiley, New York, 1997.
[21]
Lindman, B. W., Amohiphile Aggregation in Aqueous Solution,
Springer-Verlag, Heidelberg, 1976.
[22]
Israelachvili, J. N.;Mitchell, D. J.;Ninham, B. W., J. Chem. Soc. Farad.
T. 2 1976, 72.
[23]
Soler-illia, G. J. D.;Sanchez, C.;Lebeau, B.;Patarin, J., Chem. Rev. 2002,
102, 4093.
[24]
Forster, S.;Antonietti, M., Adv. Mater. 1998, 10, 195.
[25]
Chu, B., Langmuir 1995, 11, 414.
[26]
Alexandridis, P.;Hatton, T. A.;Athanassiou, V., Langmuir 1995, 11,
2442.
[27]
Lopes, J. R.;Loh, W., Langmuir 1998, 14, 750.
[28]
Alexandridis, P.;Holzwarth, J. F.;Hatton, T. A., Macromolecules 1994,
27, 2414.
[29]
張有義;郭蘭生,
膠體界面化學入門,
高立, 1998.
[30]
Evans, D. F., The Colloidal Domain, VCH: Wiley, New York, 1999.
[31]
Wanka, G.;Hoffmann, H.;Ulbricht, W., Macromolecules 1994, 27, 4145.
[32]
Zhao, D. Y.;Huo, Q. S.;Feng, J. L.;Chmelka, B. F.;Stucky, G. D., J. Am.
Chem. Soc. 1998, 120, 6024.
[33]
Blinker, C. J.;Scherer, G. W., Sol-Gel Science, 1990.
[34]
Iler, R. K., The Chemistry of Silica, John Wiley, New York, 1979.
[35]
Wan, Y.;Zhao, D. Y., Chem. Rev. 2007, 107, 2821.
[36]
Brinker, C. J.;Lu, Y. F.;Sellinger, A.;Fan, H. Y., Adv. Mater. 1999, 11,
579.
[37]
Huo, Q. S.;Margolese, D. I.;Ciesla, U.;Demuth, D. G.;Feng, P. Y.;Gier,
T. E.;Sieger, P.;Firouzi, A.;Chmelka, B. F.;Schuth, F.;Stucky, G. D.,
Chem. Mater. 1994, 6, 1176.
[38]
Stucky, G. D.;Firouzi, A.;Atef, F.;Oertli, A. G.;Chmelka, B. F., J. Am.
Chem. Soc. 1997, 119, 3596.
[39]
Chen, C.-Y.;Burkett, S. L.;Li, H.-X.;Davis, M. E., Microporous Mater.
1993, 2, 27.
[40]
Monnier, A.;Schuth, F.;Huo, Q.;Kumar, D.;Margolese, D.;Maxwell, R.
S.;Stucky, G. D.;Krishnamurty, M.;Petroff, P.;Firouzi, A.;Janicke,
M.;Chmelka, B. F., Science 1993, 261, 1299.
[41]
Inagaki, S.;Fukushima, Y.;Kuroda, K., J. Chem. Soc. Chem. Comm.
1993, 680.
[42]
Terasaki, O.;Sakamoto, Y.;Inagaki, S.;Ohsuna, T.;Ohnishi,
N.;Fukushima, Y.;Nozue, Y., Micropor. Mesopor. Mater. 1998, 21, 589.
[43]
Wang, X. G.;Chen, C. C.;Chen, S. Y.;Mou, Y.;Cheng, S. F., Appl. Catal.
A-Gen. 2005, 281, 47.
[44]
Feng, X.;Fryxell, G. E.;Wang, L. Q.;Kim, A. Y.;Liu, J.;Kemner, K. M.,
Science 1997, 276, 923.
[45]
Sun, J. M.;Zhang, H.;Tian, R. J.;Ma, D.;Bao, X. H.;Su, D. S.;Zou, H. F.,
Chem. Commun. 2006, 1322.
[46]
Yang, H. F.;Zhao, D. Y., J. Mater. Chem. 2005, 15, 1217.
[47]
Wang, Y. Q.;Yang, C. M.;Schmidt, W.;Spliethoff, B.;Bill, E.;Schuth, F.,
Adv. Mater. 2005, 17, 53.
[48]
Baskaran, S.;Liu, J.;Domansky, K.;Kohler, N.;Li, X. H.;Coyle,
C.;Fryxell, G. E.;Thevuthasan, S.;Williford, R. E., Adv. Mater. 2000, 12,
291.
[49]
Yang, C. M.;Cho, A. T.;Pan, F. M.;Tsai, T. G.;Chao, K. J., Adv. Mater.
2001, 13, 1099.
[50]
Bartl, M. H.;Puls, S. P.;Tang, J.;Lichtenegger, H. C.;Stucky, G. D.,
Angew. Chem. Int. Ed. 2004, 43, 3037.
[51]
Soler-Illia, G.;Crepaldi, E. L.;Grosso, D.;Sanchez, C., Curr. Opin.
Colloid. In. 2003, 8, 109.
[52]
Yu, C. Z.;Fan, J.;Tian, B. Z.;Zhao, D. Y., Chem. Mater. 2004, 16, 889.
[53]
Sundblom, A.;Oliveira, C. L. P.;Pedersen, J. S.;Palmqvist, A. E. C., J.
Phys. Chem. C 2010, 114, 3483.
[54]
Sundblom, A.;Palmqvist, A. E. C.;Holmberg, K., Langmuir 2010, 26,
1983.
[55]
Shan, W.;Wang, B.;Zhang, Y. H.;Tang, Y., Chem. Commun. 2005, 1877.
[56]
Fan, J.;Lei, J.;Wang, L. M.;Yu, C. Z.;Tu, B.;Zhao, D. Y., Chem.
Commun. 2003, 2140.
[57]
Yu, C. Z.;Fan, J.;Tian, B. Z.;Zhao, D. Y.;Stucky, G. D., Adv. Mater.
2002, 14, 1742.
[58]
Sayari, A.;Han, B. H.;Yang, Y., J. Am. Chem. Soc. 2004, 126, 14348.
[59]
Ji, X. L.;Lee, K. T.;Monjauze, M.;Nazar, L. F., Chem. Commun. 2008,
4288.
[60]
Sujandi;Park, S. E.;Han, D. S.;Han, S. C.;Jin, M. J.;Ohsuna, T., Chem.
Commun. 2006, 4131.
[61]
Cheng, S. F.;Chen, S. Y.;Jang, L. Y., Chem. Mater. 2004, 16, 4174.
[62]
Cheng, S.;Liu, Y.-C.;Lin, C.-Y.;Chan, J. C. C.;Tsai, Y.-L.;Lee, J.-
J.;Chuang, W.-T.;Tang, C.-Y.;Chen, S.-Y., Chem. Mater. 2008, 20, 3906.
[63]
Li, F.;Wang, J. G.;Liu, Y. P.;Zhou, H. J.;Chen, T. H., J. Mater. Sci. 2009,
44, 6505.
[64]
Celik, O.;Dag, O., Angew. Chem. Int. Ed. 2001, 40, 3800.
[65]
He, Q. J.;Shi, J. L.;Zhao, J. J.;Chen, Y.;Chen, F., J. Mater. Chem. 2009,
19, 6498.
[66]
vanderSchoot, P., Langmuir 1997, 13, 4926.
[67]
Knox, J. H.;Kaur, B.;Millward, G. R., J. Chromatogr. 1986, 352, 3.
[68]
Lee, J.;Kim, J.;Hyeon, T., Adv. Mater. 2006, 18, 2073.
[69]
Ryoo, R.;Joo, S. H.;Jun, S., J. Phys. Chem. B 1999, 103, 7743.
[70]
Jun, S.;Joo, S. H.;Ryoo, R.;Kruk, M.;Jaroniec, M.;Liu, Z.;Ohsuna,
T.;Terasaki, O., J. Am. Chem. Soc. 2000, 122, 10712.
[71]
Joo, S. H.;Choi, S. J.;Oh, I.;Kwak, J.;Liu, Z.;Terasaki, O.;Ryoo, R.,
Nature 2001, 412, 169.
[72]
Ryoo, R.;Choi, M., Nat. Mater. 2003, 2, 473.
[73]
Kohl, D., J. Phys. D Appl. Phys. 2001, 34, R125.
[74]
Tschulena, G.;Lahrmann, A., Sensors in Household Applications in
Sensors Application, Vol. 5, Wiley-VCH, Weinheim, 2003.
[75]
Yamazoe, N., Sensor. Actuat. B-Chem. 2005, 108, 2.
[76]
Öberg, P. A.;Togawa, T.;Spelman, F. A., Sensors in Medicine and Health
Care in Sensors Application, Vol. 3, Wiley-VCH, Weinheim, 2004.
[77]
Yamazoe, N.;Sakai, G.;Shimanoe, K., Catal. Surv. Asia. 2003, 7, 63.
[78]
GardnerJW;BartlettPN, Electronicnoses:principles and applications,
Oxford University Press, Oxford, 1999.
[79]
Gardner, J. W.;Pearce, T. C.;Schiffman, S. S.;Nagle, H. T., Handbook of
machine olfaction, Wiley-VCH, Weinheim, 2003.
[80]
Schaller, E.;Bosset, J. O.;Escher, F., Food Sci. Technol-Leb 1998, 31,
305.
[81]
Ampuero, S.;Bosset, J. O., Sensor. Actuat. B-Chem. 2003, 94, 1.
[82]
Mielle, P., Trends Food Sci. Technol. 1996, 7, 432.
[83]
Thaler, E. R.;Kennedy, D. W.;Hanson, C. W., Am. J. Rhinol. 2001, 15,
291.
[84]
Albert, K. J.;Lewis, N. S.;Schauer, C. L.;Sotzing, G. A.;Stitzel, S.
E.;Vaid, T. P.;Walt, D. R., Chem. Rev. 2000, 100, 2595.
[85]
Janata, J.;Josowicz, M.;Vanysek, P.;DeVaney, D. M., Anal. Chem. 1998,
70, 179R.
[86]
Janata, J.;Josowicz, M.;Devaney, D. M., Anal. Chem. 1994, 66, R207.
[87]
Falcitelli, M.;Benassi, A.;Di Francesco, F.;Domenici, C.;Marano,
L.;Pioggia, G., Sensor. Actuat. B-Chem. 2002, 85, 166.
[88]
Scott, S. M.;James, D.;Ali, Z.;O'Hare, W. T., J. Therm. Anal. Calorim.
2004, 76, 693.
[89]
James, D.;Scott, S. M.;Ali, Z.;O'Hare, W. T., Microchimica Acta 2005,
149, 1.
[90]
Hsu, Y. C.;Hsu, Y. T.;Hsu, H. Y.;Yang, C. M., Chem. Mater. 2007, 19,
1120.
[91]
Stober, W.;Fink, A.;Bohn, E., J. Colloid. Interf. Sci. 1968, 26, 62.
[92]
Bertarione, S.;Bonino, F.;Cesano, F.;Damin, A.;Scarano, D.;Zecchina,
A., J. Phys. Chem. B 2008, 112, 2580.
[93]
Lund, K.;Muroyama, N.;Terasaki, O., Micropor. Mesopor. Mater. 2010,
128, 71.