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研究生: 張繼升
Jason Chang
論文名稱: 可撓式正溫度係數高分子電阻薄膜之研究
The Study of Flexible Positive Temperature Coefficient Resistor Film
指導教授: 金惟國
Wei-Kuo Chin
口試委員:
學位類別: 博士
Doctor
系所名稱: 工學院 - 化學工程學系
Department of Chemical Engineering
論文出版年: 2006
畢業學年度: 94
語文別: 中文
論文頁數: 200
中文關鍵詞: 正溫度係數可撓式
外文關鍵詞: PTC, Flexible, PCC
相關次數: 點閱:2下載:0
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  • 本研究係針對高分子導電複合材料(Polymer Conductive Composite, PCC)的正溫度係數(Positive Temperature Coefficient, PTC)行為,進行一系列的實驗與探討。研究的主題包括:導電粒子的製備,聚醯亞胺(Polyimide)基材,聚苯乙烯-丙烯酸正丁酯(Polystyrene-co-butylacrylate)基材,複合電阻膜的熱-電性質(Thermal-electrical property),尤其側重於上述這些組合對於正溫度係數行為所造成的影響。期望透過本研究的發現,能對於這類型導電複合材料在電子封裝、民生用途這兩大領域,開創新局。特別是可撓式的應用(Flexible application),更是我們寄希望之所在。


    This study is mainly to discuss the positive temperature coefficient (PTC) effect of Polymer Conductive Composite (PCC), which includes the preparation for Ni composite particle, polyimide and polystyrene-co- butylacrylate matrix, particularly the temperature-resistance behavior of composite films. What would be the impact to PTC feature for composite film, by changing the combination of above factors, as well as the process, is our major interest in overall study.
    The study consists of 3 main topics:
    Part I. Micro Ni-plated SiO2 particle/polyimide matrix system
    Part II. Core-shell type P(S-DVB) Ni-plated particle/P(S-co-nBA) matrix system
    Part III. The thickness-direction PTC feature of micro Ni powder/ polyimide matrix system

    第一章 緒論 第二章 理論與文獻回顧 2.1 高分子導電複合材料 2.2 導電填充物 2.3 高分子基材 2.4 導電機制 2.5 溫度係數電阻效應 2.6 近5年(2001~2005)相關領域的研究 2.7 無電電鍍鎳(Electroless Ni Plating) 2.8 聚醯亞胺(Polyimide) 2.9 複合型導電粒子(Composite Conductive Filler) 第三章 實驗方法與步驟 第四章 結果與討論 4-1 表面鍍鎳二氧化矽球形粒子/聚醯亞胺高分子複合膜系統 4-2 表面鍍鎳之殼核型苯乙烯-二乙烯苯共聚合的 球形粒子/苯乙烯-丙烯酸正丁酯高分子複合膜系統 4-3 微米鎳粉粒子/聚醯亞胺複合薄膜系統 第五章 總結

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