水相中銅與胺基酸錯合物之光分解含氮產物研究

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研究生：	王博彥
論文名稱：	水相中銅與胺基酸錯合物之光分解含氮產物研究 Determination of Ammonium Ion and Amines in the Photolysis of Cu(II)-Amino Acid Complexes in Aqueous Solution
指導教授：	吳劍侯羅俊光
口試委員:
學位類別：	碩士 Master
系所名稱：	原子科學院 - 生醫工程與環境科學系 Department of Biomedical Engineering and Environmental Sciences
論文出版年：	2004
畢業學年度：	92
語文別：	英文
論文頁數：	134
中文關鍵詞：	銨離子、胺類、銅錯合物、胺基酸、量子產率
外文關鍵詞：	Ammonium ion, amines, copper complexes, amino acids, quantum yields
相關次數：	點閱：1 下載：0
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本論文主要是使用高效能液相層析（High Performance Liquid Chromatography, HPLC）搭配鄰苯二甲醛（o-phthaldialdehyde, OPA）螢光衍生法以及離子層析法（Ion Chromatography, IC）來探討銅胺基酸錯合物在經由波長313 nm的光照射之後，可能產生的含氮產物（銨離子(NH4+）與胺類(amines））及其量子產率。光照下，銅胺基酸錯合物經由配位基（胺基酸）上的電子轉移到金屬（銅）（ligand to metal charge transfer, LMCT），使二價銅還原成一價銅，胺基酸則被氧化，並進行一系列分解。實驗結果顯示，銅錯合物系統下，除了配位基為β-丙胺酸(β-alanine)時，可以量測到乙胺(ethylamine)外，在本實驗中所使用的α-胺基酸（α-alanine, leucine, isoleucine, phenylalanine, valine, methionine and arginine ）都只能量測到銨離子。同時，在不同的條件（pH、銅與配位基濃度）下，一價銅與銨離子的量子產率比(ΦCu(I) /ΦNH3)皆約維持在2。根據實驗結果，提出一個可能的光分解反應路徑。

Two analytical methods, High Performance Liquid Chromatography (HPLC) o-phthaldialdehyde (OPA) derivatization / Fluorometry and Ion Chromatography (IC) / Conductimetry, have been established for qualitative and quantitative analysis of the possible nitrogen-containing photoproduct compounds (amines and ammonium ions) from photolysis of copper(II) – amino acids complexes in aqueous soultion without oxygen under monochromatic radiation at 313 nm. Due to the ligand to metal charge transfer (LMCT) during the irradiation, copper(II) was reduced to copper(I) and the ligand was oxidized and decomposed to final products. While testing different ligands including α-alanine, leucine, isoleucine, phenylalanine, valine, methionine, proline and arginine with copper(II), photoproduction of ethylamine instead of NH4+ is only observed in Cu(II)-β-alanine complex system. The quantum yields of ammonium ion (ΦNH3) as a major nitrogen-containing photoproduct is just the half of the quantum yields of copper(I) (ΦCu(I)) in the copper(II)-α-amino acid complex system. The experimental results show that the value ΦCu(I) /ΦNH3 ratio still remains the same while alternating the pH, concentration of metal, and ligand in Cu(II)-α-alanine complexes. According to the results from the study, a possible pathway for the decomposition of the amino acids in the copper(II)-α-amino acid complex system is proposed.

Chinese Abstract
English Abstract
Acknowledgements
Table of Contents
List of Figures
List of Tables
Preface
Part 1    1
Chapter 1 Introduction    2
1-1 The Properties of NH4+    2
1-2 The Properties of Amines    3
1-3 Motivation    4
1-4 Objectives    4
Chapter 2 Literature Review    6
2-1 Methods for Determination of Amines    6
2-1-1 Gas Chromatography (GC)    6
2-1-2 High Performance Liquid Chromatography (HPLC)    7
2-2 Methods for Determination of NH4+ in Aqueous Phase    13
2-2-1 Electroanalytical Methods    13
2-2-2 Spectrophotometry    13
2-2-3 Fluorometry    14
2-2-4 Gas Chromatography    15
2-2-5 Determination of Ammonium Ion by Ion Chromatography    18
2-3 Conclusion    23
2-4 Introduction of Fluorometry    23
2-5 Introduction of Ion Chromatography    24
2-5-1 The Principle of Ion Chromatography    24
2-5-2 The Principle of Conductmetric Detection    29
Chapter 3 Experimental Section    33
3-1 Equipment    33
3-2 Reagents    36
3-3 Cleaning Condition and Instrument Maintenance    38
3-4 Experimental Procedures    38
3-4-1 Stock Solution Preparation    38
3-4-2 Procedures for Analysis of Ethylamine    40
3-4-3 Procedures for Analysis of NH4+    43
Chapter 4 Results and Discussion    45
4-1 Determination of Ethylamine    45
4-1-1 Determination of Excitation and Emission Wavelength of OPA-ethylamine Derivative    45
4-1-2 Effect of OPA Reagent pH    46
4-1-3 Effect of 2-mercaptoethanol Concentration    47
4-1-4 Effect of OPA Concentration    48
4-1-5 Effect of Na2B4O7 Buffer Concentration    49
4-1-6 Effect of Reaction Time    50
4-1-7 Effect of Sample Matrix Interference    51
4-1-8 Calibration Curve, Precision and Method Detection Limit    52
4-2 Determination of NH4+    54
4-2-1 Effect of Temperature on Ion Chormatography    55
4-2-2 Effect of Concentration of Methanesulfonic Acid (MSA)    57
4-2-3 Effect of Disproportional Concentration Ratio of Na+ and NH4+ Ions on Their Separation    60
4-2-4 Standard Addition Method    62
4-2-5 Calibration Curve, Precision and Method Detection Limit    63
Chapter 5 Conclusion    66
Reference    68
Part 2    76
Chapter 1 Introduction    77
1-1 Properties of Copper    77
1-2 Copper in the Environment    77
1-3 Research Objectives    79
Chapter 2 Literature Review    81
2-1 Photochemical Behavior of Copper Complexes    81
2-2 Model Assumption    85
Chapter 3 Experimental Section    90
3-1 Equipments    90
3-2 Reagents    92
3-3 Experimental Procedures    92
3-3-1 Preparation of Working Solution    92
3-3-2 Procedures for Determination of Cu+, Amines and NH4+    93
3-3-3 Procedures for Determination of Light Intensity    95
3-4 Experimental Scheme    96
Chapter4 Results and Discussion    98
4-1 Determination of Possible N-containing Photolysis Products    98
4-2 Cu+/NH4+ Ratio    102
4-2-1 Effect of pH Value    103
4-2-2 Effect of Concentration of Ligand    108
4-2-3 Effect of Concentration of Cu(II)    112
4-3 Purge Effect    120
4-4 Effect of Different Ligands    123
4-4-1 Non-polar Amino Acids    123
4-4-2 Basic Amino Acids    125
4-5 Glycine and Serine    129
Chapter 5 Conclusion    130
Chapter 6 Future Works    131
References    132

                                

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