中文摘要
本次論文主要透過開發兼具環境友善與優異性能的材料來推動鋰電池技術的進步。此次介紹了新型的水基果膠-PEG 結合劑，用於鋰鐵磷酸鹽（LiFePO₄, LFP）正極；利用自由結構的果膠天然柔韌性與聚乙二醇（PEG-200）配合，與傳統的 PVDF 結合劑相比，該果膠-PEG 結合劑展現出優良自我修復特性，更提升了優異的黏著性與穩定的性能平衡。使用此結合劑在 1C 倍率 500 多次循環後仍能保持約 150 mAh g⁻¹ 的容量，且容量維持率約 99%；在 3C 下，放電容量約 141 mAh g⁻¹，保持率達到 97% 以上。在使用循環保護方法後，展現出高倍率充放電性能。
循環伏安法顯示該果膠-PEG 正極材料具備優異的離子擴散特性，而伽凡諾間歇滴定法則揭示 LFP-PP250 電極在工作電壓內表現出較高的鋰離子擴散係數 (DLi⁺)，本次開發了該果膠-PEG 的高性能應用。並引入不同鋰鹽（LiTFSI、LiNO₃ 和 Li₂SO₄）的模擬聚合物電解質 (GPE)，提升電解質的機械強度、離子導電性及界面穩定性。
其中，LiNO₃-GPE 表現出非常優異的性能優勢，在 1C 充電、3C 放電條件下經過 270 次以上的循環仍保有約 79% 的容量，且在 10C 倍率下保持容量衰減相當緩慢的優秀表現。該設計具備良好的水溶性，促進了材料的可回收性，為未來能源技術奠定演算法；使用該 GPE 的 18650 電池可實現 146 Wh kg⁻¹ 的能量密度及 4.1 kW kg⁻¹ 的功率密度，優於商業化的 18650 電池。這些成果為鋰電池的後續回收鏈提供了重要的實力與啟發。

關鍵詞：水基黏結劑、果膠、聚乙二醇、磷酸鐵鋰、環境友善

ABSTRACT
This study focuses on advancing lithium-ion battery technology by developing environmentally friendly materials that enhance both performance and sustainability. A new water-based binder for LiFePO₄ (LFP) cathodes was introduced, combining the natural flexibility of pectin with the mechanical and electrochemical benefits of polyethylene glycol (PEG) through radical copolymerization. The pectin-PEG binder exhibited enhanced self-repair capabilities, superior cycling durability, and significantly improved ionic transport efficiency when compared to traditional PVDF binders. With this binder, the electrodes showed remarkable performance, keeping 150 mAh g⁻¹ with 99% capacity retention after 500 cycles at 1C and 97% capacity retention, or 141 mAh g⁻¹, at 3C. Through cyclic voltammetry, high sweep rates validated its effective ionic transport properties, and galvanostatic intermittent titration showed that the LFP-PP250 electrodes had a higher diffusion coefficient of lithium ions (DLi⁺).
Further advancements in mechanical strength, ionic conductivity, and interfacial stability were also shown by the creation of quasi-solid lithium-ion batteries using pectin-PEG-based gel polymer electrolytes (GPEs) formulated with different lithium salts, such as LiTFSI, LiNO₃, and Li₂SO₄. Among these, the LiNO₃-based GPE exhibited the best performance, retaining 79% capacity after 270 cycles at 1C/3C rates, with excellent C-rate performance up to 10C. Additionally, this electrolyte design promotes recyclability due to its water solubility and delivers energy densities of 146 Wh kg⁻¹ and 4.1 kW kg⁻¹ in 18650 cells. These findings provide valuable insights for developing eco-friendly lithium-ion batteries with elevated energy densities and lay a strong foundation for further advancement of GPE technology in energy storage systems.
Keywords: Water-based-Binder, Pectin, PEG, LiFePO4, Eco-friendly

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