本論文以”非水解溶凝膠法”製備摻雜與非摻雜Co、Ni原子之ZrO2與HfO2奈米粒子，欲研究可能出現於材料中的物理現象。於”非水解溶凝膠法”製備出的奈米粒子，在室溫下以X光繞射分析出具有一定程度的晶性，其大小以謝樂方程與穿透式電子顯微鏡觀測估計平均粒子直徑約為5nm以下，但此些粒子形狀多為不規則狀。各樣品間能隙上的變化也反應其組成物與結構上的不同。於磁性方面，未摻雜其他元素的ZrO2與HfO2粒子表現微弱的反磁性，而一旦摻雜入過度金屬Ni、Co，順磁性便超越原本的反磁性質，並於溫度40K下經摻雜後的奈米粒子皆無發現鐵磁性存在。

“Nonhydrolytic Sol-Gel Synthesis Method” is adopted to prepare not only ZrO2 and HfO2 but also Co-doped and Ni-doped ZrO2、HfO2 nanoparticles in this paper﹒It can be found that Zr compounds are well-crystallized and average particle size is estimated below 5 nm﹒Hf compounds are bad-crystallized and appearance of particles reveals nonhomogeneity﹒It may be attribute to the factor in experimental conditions like temperature or pressure﹒Otherwise，ZrO2 and HfO2 particles reveal diamagnetism，but Co-doped and Ni-doped ZrO2、HfO2 particles are paramagnetic﹒Ferromagnetism is not detected in all kind of particles at 40K﹒

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