固態染料敏化太陽能電池（ssDSSC）在串聯太陽能電池配置中相較於液體電解質電池具有顯著優勢。主要好處在於其增強的穩定性和耐用性，因為ssDSSC消除了液體電解質常見的漏液、蒸發和腐蝕問題。這種穩定性確保了更長的操作壽命和更一致的性能，這對於設計用於高效率和可靠性的串聯太陽能電池至關重要。此外，ssDSSC可以更容易地與其他光伏技術（如鈣鈦礦或矽太陽能電池）集成，以創造高效的串聯結構。固態的形式也使其能夠更好地堆疊和分層，而不會有電解質相關劣化的風險，使其成為先進串聯太陽能電池架構的理想選擇。
本研究的第一部分涉及製造和表徵結合ssDSSC與鈣鈦礦太陽能電池（PSC）的4T串聯太陽能電池架構。選擇甲基銨鉛溴氯鈣鈦礦，因其高透明度和適度的近紫外光吸收能力。對各種染料化合物在ssDSSC上進行測試，以尋找高效的光伏設備。先進的製造技術確保了最佳的層沉積和界面工程，以實現結構中有效的電荷轉移。
本研究的第二部分深入探討了結合半透明寬帶隙太陽能電池FAMACsPbIBr與矽太陽能電池的串聯結構的製造，並在不同強度的低光和T5螢光燈下檢查其性能。這將提供對在各種光照條件下運行的兩種串聯系統之間差異的更深入理解，突顯鈣鈦礦在串聯太陽能電池中的潛力，因為其可以製成半透明並且具可調帶隙特性。

The primary benefit of solid-state dye-sensitized solar cells (ssDSSC) lies in their enhanced stability and durability, as ssDSSCs eliminate issues related to leakage, evaporation, and corrosion that are common with liquid electrolytes. This stability ensures longer operational lifespans and more consistent performance, which is crucial for tandem solar cells designed for high efficiency and reliability. Moreover, without using a sandwich design to seal the cell, ssDSSCs can further decrease the production cost and also minimize the optical loss for the whole system. Additionally, ssDSSCs can be more easily integrated with other photovoltaic technologies, such as perovskite or silicon solar cells, to create efficient tandem structures. Solid form also allows them to better stacking and layering without the risk of electrolyte-related degradation, making them an ideal choice for advanced tandem solar cell architectures.
The first part of this research involves fabricating and characterizing 4T tandem solar cell architectures combining ssDSSCs with perovskite solar cells (PSCs). Methylammonium (MA) lead bromide chloride perovskite is chosen for its high transparency and adequate near-UV absorbance. Various dye compounds are tested on ssDSSCs to find an efficient photovoltaic device. Advanced fabrication techniques ensure optimal layer deposition and interface engineering for efficient charge transfer across the structure.
The second part of this research delves into the fabrication of a tandem structure combining semi-transparent wide band gap solar cell FAMACsPbIBr and silicon solar cell, and examines their performance under low light and T5 fluorescent light at different intensities. This would provide a deeper understanding of the differences between the two tandem systems operating under various light conditions, highlighting the potential of perovskite in tandem solar cells due to its ability to be made semi-transparent and its tunable band gap characteristics.

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