研究生: |
洪瑞廷 |
---|---|
論文名稱: |
鈣硼矽玻璃粉末在水溶液中之溶解及分散行為 |
指導教授: | 簡朝和 |
口試委員: | |
學位類別: |
碩士 Master |
系所名稱: |
工學院 - 材料科學工程學系 Materials Science and Engineering |
論文出版年: | 2004 |
畢業學年度: | 92 |
語文別: | 中文 |
論文頁數: | 57 |
中文關鍵詞: | 鈣硼矽玻璃 、分散 、流變行為 、旋轉半徑 、聚乙烯胺 |
相關次數: | 點閱:2 下載:0 |
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本論文乃探討如何將鈣硼矽玻璃粉末在水溶液中有效的分散。首先針對實驗中所使用的鈣硼矽玻璃粉末之基本性質作深入地了解。發現此玻璃粉體在水溶液中之表面電位大致上為負值,因此我們在選用分散劑時,則以帶有正電的聚乙烯胺(PEI)作為使用之首選。
進一步我們利用本質黏度及小角度x光散射法測量PEI在不同pHeq值之水溶液中的旋轉半徑,發現其大小會隨溶液pHeq值的減小而增大。然而量測PEI在粉體表面之吸附量後由公式推得之PEI旋轉半徑,則與前述結果有所出入。經分析後發現,由於在酸性溶液中,粉體會有大量的Ca2+、B3+離子溶出,造成PEI有團聚結構,而使此時PEI的吸附量異常變大。
而就CBSG漿料流變行為,則由粉體溶解及PEI的帶電情形作匹配,可在漿料之pHeq= 7.8 - 10.6的區間中,得到使漿料穩定所需之PEI添加量的穩定分佈圖。然改變漿料固含量亦會影響穩定分佈圖之分佈。由結果發現,PEI與CBSG漿料系統之最大穩定固含量約為45vol%。
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