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研究生: 牛培倫
Niu, Pei-Lun
論文名稱: 滾筒式壓印殘餘層控制與移除研究
A study on the thickness control and removal of residual layer of roller-type nanoimprint
指導教授: 宋震國
Sung, Cheng-Kuo
口試委員: 傅建中
冉曉雯
孟心飛
學位類別: 碩士
Master
系所名稱: 工學院 - 動力機械工程學系
Department of Power Mechanical Engineering
論文出版年: 2011
畢業學年度: 99
語文別: 中文
論文頁數: 98
中文關鍵詞: 奈米壓印殘餘層電漿蝕刻舉離製程
外文關鍵詞: Nanoimprint, Residual layer, O2 plasma, Lift-off
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  • 本論文之研究重點為奈米壓印製程之殘餘層移除,探討壓印參數對壓印後殘餘層厚度之影響性,以及移除殘餘層之方法,利用實驗和量測,了解參數間的關係,增加奈米結構完整性,以提升後續lift-off製程之穩定性。
    實驗從平面壓印出發,再將平面壓印研究中得到的結果與趨勢運用到滾筒壓印上。本文採用紫外光奈米壓印,薄膜材料選擇低黏度UV光阻,以達到較佳的模具填充能力並有效減低殘餘層厚度;基板則是選擇具有透光性及可撓性的聚對苯二甲酸乙二酯(Polyethylene terephthalate, PET)材料。在壓印的過程中,對殘餘層厚度具影響性之參數有壓印力、壓印時間,以及光阻塗布厚度;另一方面,殘餘層移除的方法是採用電漿蝕刻,蝕刻過程之兩大重要因子為蝕刻率以及對結構的側向蝕刻率影響,而影響的參數包含Ar流速、O2流速以及電漿功率。由於本文所採用之基板為高分子材料,實驗量測將透過穿遂電子顯微鏡(SEM)搭配聚焦離子束切割儀( FIB)進行。
    本文研究結果發現,在壓印的製程中光阻的塗佈厚度以及均勻性扮演著相當重要的角色,隨著光阻初始厚度越薄,最後所得到的殘餘層厚度也會跟著減少;在後續電漿蝕刻移除殘餘層製程中,利用較高的氬氣流量以及電漿功率,搭配較短的製程時間,能在維持奈米結構完整性的情況下成功的移除殘餘層;本文已能在軟性基板上得到無殘餘層的奈米結構。


    中文摘要 I 英文摘要 III 致謝 V 目錄 VI 圖目錄 IX 表目錄 XV 第一章 緒論 1 1.1前言 1 1.2研究動機 2 1.3文獻回顧 3 1.3.1奈米壓印技術 3 1.3.2壓印參數對殘餘層影響 10 1.4本文內容 16 第二章 殘餘層理論與電漿原理 17 2.1平面壓印殘餘層理論推導 17 2.2滾筒式壓印殘餘層理論推導 22 2.2.1膠帶張力對殘餘層厚度之影響 22 2.2.2背向輪對殘餘層厚度之影響 25 2.2.3實際滾筒壓印下之情況 27 2.3電漿理論 30 2.3.1電漿生成 30 2.3.2電漿特性 35 2.3.3電漿蝕刻 37 第三章 實驗研究 40 3.1實驗設備 40 3.2 實驗準備 47 3.2.1模具製作 47 3.2.2 PET基板選用 49 3.2.3 UV光阻選用 50 3.3實驗設計規劃 52 3.3.1平面壓印殘餘層實驗 52 3.3.2滾壓實驗 54 3.3.3利用電漿蝕刻去除殘餘層實驗 56 3.3.4 Lift-off實驗與高分子雙層結構製作 57 3.4實驗流程 58 第四章 實驗結果與討論 60 4.1模具量測 60 4.2平面壓印殘餘層實驗 62 4.2.1定量吸管塗佈 63 4.2.2旋鍍法塗佈 64 4.2.3噴塗法塗佈 66 4.3滾壓實驗 70 4.4利用電漿蝕刻去除殘餘層實驗 76 4.5 Lift-off實驗以及高分子金屬雙層結構製作 83 第五章 結論與未來工作 92 5.1結論 92 5.2未來工作 94 參考資料 96

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