本論文研究的第一部分，通過不同的有機轉化反應，探索了四種將烷基鏈接枝到金屬有機骨架(MOF)上的後修飾(PSM)反應。已獲得疏水性MOF，並進一步應用到製備MOF-高分子複合材，減少MOF-高分子複合材料之間的介面縫隙。在這部分，後修飾的疏水MOF因為消除了MOF-聚苯胺(PANI)複合材料中的介面縫隙，所以提升了對鐵片的防腐性能。結果顯示，PAZr-C18-5%複合材料表現出顯著的防腐性能，腐蝕電流密度從71.61降至0.18 μA/cm2。此外，將疏水性MOFs摻雜到PANI中也可以增加複合材料的表面疏水性並提高其阻氣性能。
在本論文研究中，也進行了MOF-三聚氰胺海綿，ZrTz-68-C18@海綿的複合材料的製備以及應用。在此部分中，三聚氰胺海綿首先通過烯烴官能基化改變，與合成的 ZrTz-68 MOF反應，來製備出ZrTz-68@海綿複合材，然後進一步與 1-十八烯進行點擊反應，得到了ZrTz-68-C18@海綿的疏水複合材，並針對油水分離應用，以及有機溶劑矽油和氯仿的吸附進行研究測試，ZrTz-68-C18@海綿的疏水複合材吸附矽油和氯仿能力分別達到很高的77和125 g/g。

For the first part of this study, four post-synthetic modification (PSM) reactions to incorporate alkyl chains onto metal-organic frameworks (MOFs) were explored by using various organic transformation reactions. The modified hydrophobic MOFs can reduce the interface voids within the MOF-polymer composites. It was demonstrated that the decorated hydrophobic MOFs eliminated the interfacial voids in the MOF-polyaniline (PANI) composites and increased the anticorrosion performance. In particular, PAZr-C18-5% composite exhibited significant anticorrosive properties as the corrosion current density was reduced from 71.61 to 0.18 μA/cm2. For the further, the doping of hydrophobic MOFs into PANI can also increases the surface hydrophobicity and improve gas barrier performance.
The further study also highlighted the facile preparation of ZrTz-68-C18@melamine sponge. Herein, the melamine sponge was first modified by alkene functionalization by reacted with as synthesized ZrTz-68. The ZrTz-68@sponge was further modifed by click-reaction with 1-octadecene. The hydrophobic ZrTz-68-C18@sponge demonstrates high sorption capacity for silicon oil and chloroform up to 77 and 125 g/g, respectively.

1. Hailian Li, M. Eddaoudi, M. O’Keeffe, Omar. M. Yaghi, Design and Synthesis of an Exceptionally Stable and Highly Porous Metal-Organic Framework. Nature, 1999, 402, 276-279.
2. Stephen S.-Y. Chui, Samuel M.-F. Lo, Jonathan P. H. Charmant, A. Guy Orpen, Ian D. Williams, A Chemically Functionalizable Nanoporous Material [Cu3(TMA)2(H2O)3]n. Science, 1999, 283, 1148-1150.
3. Peyman Z. Moghadam, Aurelia Li, Seth B. Wiggin, Andi Tao, Andrew G. P. Maloney, Peter A. Wood, Suzanna C. Ward, David Fairen-Jimenez, Development of a Cambridge Structural Database Subset: A Collection of Metal-Organic Frameworks for Past, Present, and Future. Chemistry of Materials, 2017, 29, 2618-2625.
4. Zhijie Chen, Megan C. Wasson, Riki J. Drout, Lee Robison, Karam B. Idrees, Julia G. Knapp, Florencia A. Son, Xuan Zhang, Wolfgang Hierse,3 Clemens Kühn, Stefan Marx, Benjamin Hernandez, Omar K. Farha, The state of the field: from inception to commercialization of metal-organic frameworks. Faraday Discuss., 2021, 225, 9-69.
5. Sung Hwa Jhung, Jin-Ho Lee, Jong-San Jong, Microwave synthesis of a nanoporous hybrid material, chromium trimesate. Bull. Korean Chem. Soc., 2005, 26, 880-881.
6. Sung Hwa Jhung, Jin-Ho Lee, Ji Woong Yoon, Christian Serre, Gerard Ferey, Jong-San Jong, Microwave synthesis of chromium terephthalate MIL-101 and its benzene sorption ability. Adv. Mater. 2007, 19, 121-124.
7. Jin Ho Bang, Kenneth S. Suslick, Applications of Ultrasound to the Synthesis of Nanostructured Materials. Adv. Mater. 2010, 22, 1039-1059.
8. T. Chalati, P. Horcajada, R. Gref, P. Couvreura, C. Serre, Optimisation of the synthesis of MOF nanoparticles made of flexible porous iron fumarate MIL-88A. J. Mater. Chem. 2011, 21, 2220-2227.
9. Ling-Guang Qiu, Zong-Qun Li, Yun Wu, Wei Wang, Tao Xu, Xia Jiang, Facile synthesis of nanocrystals of a microporous metal-organic framework by an ultrasonic method and selective sensing of organoamines. Chem. Commun. 2008, 31, 3642-3644.
10. Ulrich Muller, Hermann Putter, Michael Hesse, Helge Wessel, Markus Schubert, Jurgen Huff, Marcus Guzmann, Method for electrochemical production of a crystalline porous metal organic skeleton material. US7968739B2.
11. Anne Pichon, Ana Lazuen-Garay, Stuart L. James, Solvent-free synthesis of a microporous metal-organic framework. CrystEngComm, 2006, 8, 211-214.
12. Norbert Stock, Shyam Biswas, Synthesis of Metal-Organic Frameworks ( MOFs ) : Routes to Various MOF Topologies, Morphologies, and Composites. Chem. Rev. 2012, 112, 933-969.
13. Daqiang Yuan, Dan Zhao, Daofeng Sun, Hong-Cai Zhou, An Isoreticular Series of Metal-Organic Frameworks with Dendritic Hexacarboxylate Ligands and Exceptionally High Gas-Uptake Capacity. Angew. Chem. Int. Ed., 2010, 49, 5357-5361.
14. Omar K. Farha, A. Ozqur Yzazydin, Ibrahim Eryazici, Christos D. Malliakas, Brad G. Hauser, Mercouri G. Kanatzidis, SonBinh T. Nquyen, Randall Q. Snurr, Joseph T. Hupp, De novo synthesis of a metal-organic framework material featuring ultrahigh surface area and gas storage capacities. Nat. Chem., 2010, 2, 944-948.
15. Yong Yan, Xiang Lin, Sihai Yang, Alexander J. Blake, Anne Dailly, Neil R. Champness, Peter Hubberstey, Martin Schroder, Exceptionally high H2storage by a metal-organic polyhedral framework. Chem. Commun., 2009, 9, 1025-1027.
16. Dalal Alezi, Youssef Belmabkhout, Mikhail Suyetin, Prashant M. Bhatt, Łukasz J. Weseliński, Vera Solovyeva, Karim Adil, Ioannis Spanopoulos, Pantelis N. Trikalitis, Abdul-Hamid Emwas, Mohamed Eddaoudi, MOF crystal chemistry paving the way to gas storage needs: aluminum-based soc-MOF for CH4, O2, and CO2 storage. J. Am. Chem. Soc., 2015, 137, 13308-13318.
17. Hui-Min Wen, Bin Li, Libo Li, Rui-Biao Lin, Wei Zhou, Guodong Qian, Banglin Chen, A Metal-Organic Framework with Optimized Porosity and Functional Sites for High Gravimetric and Volumetric Methane Storage Working Capacities. Adv. Mater., 2018, 30, 1704792.
18. Xili Cui, Kaijie Chen, Huabin Xing, Qiwei Yang, Rajamani Krishna, Zongbi Bao, Hui Wu, Wei Zhou, Xinglong Dong, Yu Han, Bin Li, Qilong Ren, Michael J. Zaworotko, Banglin Chen, Pore chemistry and size control in hybrid porous materials for acetylene capture from ethylene. Science, 2016, 353, 141-144.
19. Bin Li, Xili Cui, Daniel O'Nolan, Hui-Min Wen, Mengdie Jiang, Rajamani Krishna, Hui Wu, Rui-Biao Lin, Yu-Sheng Chen, Daqiang Yuan, Huabin Xing, Wei Zhou, Qilong Ren, Guodong Qian, Michael J. Zaworotko, Banglin Chen, An Ideal Molecular Sieve for Acetylene Removal from Ethylene with Record Selectivity and Productivity. Adv. Mater., 2017, 29, 1704210.
20. Libo Li, Hui-Min Wen, Chaohui He, Rui-Biao Lin, Rajamani Krishna, Hui Wu, Wei Zhou, Jinping Li, Bin Li, Banglin Chen, A Metal-Organic Framework with Suitable Pore Size and Specific Functional Sites for the Removal of Trace Propyne from Propylene. Angew. Chem. Int. Ed., 2018, 57, 15183-15188.
21. Hai-Yang Li, Shu-Na Zhao, Shuang-Quan Zang, Jing Li, Functional metal-organic frameworks as effective sensors of gases and volatile compounds. Chem. Soc. Rev., 2020, 49, 6364-6401.
22. Weiwei Cheng, Xiaozhi Tang, Yan Zhang, Di Wu, Wenjian Yang, Applications of metal-organic framework (MOF)-based sensors for food safety: Enhancing mechanisms and recent advances. Trends in Food Science & Technology, 2021, 112, 268-282.
23. Xian Fang, Boyang Zong, Shun Mao, Metal-Organic Framework-Based Sensors for Environmental Contaminant Sensing. Nano-Micro Lett., 2018, 10, 64.
24. Liping Du, Wei Chen, Ping Zhu, Yulan Tian, Yating Chen, Chunsheng Wu, Applications of Functional Metal-Organic Frameworks in Biosensors. Biotechnol. J., 2021, 16, 1900424.
25. Vlad Pascanu, Greco González Miera, A. Ken Inge, Belén Martín-Matute, Metal-Organic Frameworks as Catalysts for Organic Synthesis: A Critical Perspective. J. Am. Chem. Soc., 2019, 141, 7223-7234.
26. Yong-Sheng Wei, Mei Zhang, Ruqiang Zou, Qiang Xu, Metal-Organic Framework-Based Catalysts with Single Metal Sites. Chemical Reviews, 2020, 120, 12089-12174.
27. Timothy A. Goetjen, Jian Liu, Yufang Wu, Jingyi Sui, Xuan Zhang, Joseph T. Hupp, Omar K. Farha, Metal-organic framework (MOF) materials as polymerization catalysts: a review and recent advances. Chem. Commun., 2020, 56, 10409-10418.
28. Ming-Xue Wu, Ying-Wei Yang, Metal-Organic Framework (MOF)-Based Drug/Cargo Delivery and Cancer Therapy. Adv. Mater., 2017, 29, 1606134.
29. Shadpour Mallakpour, Elham Nikkhoo, Chaudhery Mustansar Hussain, Application of MOF materials as drug delivery systems for cancer therapy and dermal treatment. Coordination Chemistry Reviews, 2022, 451, 214262.
30. Pamela Berilyn So, Hsin-Tsung Chen, Chia-Her Lin, De novo synthesis and particle size control of iron metal organic framework for diclofenac drug delivery. Microporous and Mesoporous Materials., 2020, 309, 110495.
31. Somboon Chaemchuen, Nawsad Alam Kabir, Kui Zhouab, Francis Verpoort, Metal-organic frameworks for upgrading biogas via CO2 adsorption to biogas green energy. Chem. Soc. Rev., 2013, 42, 9304-9332.
32. Jasmina Hafizovic Cavka, Søren Jakobsen, Unni Olsbye, Nathalie Guillou, Carlo Lamberti, Silvia Bordiga, Karl Petter Lillerud, A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability. J. Am. Chem. Soc., 2008, 130, 13850-13851.
33. Sheng-Han Lo, Ching-Hsuan Chien, Yu-Lun Lai, Chun-Chuen Yang, Jey Jau Lee, Duraisamy Senthil Rajaa, Chia-Her Lin, A mesoporous aluminium metal-organic framework with 3 nm open pores. J. Mater. Chem. A, 2013, 1, 324-329.
34. Kyo Sung Park, Zheng Ni, Adrien P. Côté, Jae Yong Choi, Rudan Huang, Fernando J. Uribe-Romo, Hee K. Chae, Michael O’Keeffe, Omar M. Yaghi, Exceptional chemical and thermal stability of zeolitic imidazolate frameworks. PANS, 2006, 103, 10186-10191.
35. Hexiang Deng, Christian J. Doonan, Hiroyasu Furukawa, Ricardo B. Ferreira, John Towne, Carolyn B. Knobler, Bo Wang, Omar M. Yaghi, Multiple Functional Groups of Varying Ratios in Metal-Organic Frameworks. Science, 2010, 327, 846-850.
36. Kristine K. Tanabe, Zhenqiang Wang, Seth M. Cohen, Systematic Functionalization of a Metal-Organic Framework via a Postsynthetic Modification Approach. J. Am. Chem. Soc., 2008, 130, 8508-8517.
37. Andrew P. Nelson, Omar K. Farha, Karen L. Mulfort, Joseph T. Hupp, Supercritical Processing as a Route to High Internal Surface Areas and Permanent Microporosity in Metal-Organic Framework Materials. J. Am. Chem. Soc., 2009, 131, 458-460.
38. Jihyun An, Chad M. Shade, Demetra A. Chengelis-Czegan, Stéphane Petoud, Nathaniel L. Rosi, Zinc-Adeninate Metal-Organic Framework for Aqueous Encapsulation and Sensitization of Near-infrared and Visible Emitting Lanthanide Cations. J. Am. Chem. Soc., 2011, 133, 1220-1223.
39. Jihyun An, Nathaniel L. Rosi, Tuning MOF CO2 Adsorption Properties via Cation Exchange. J. Am. Chem. Soc., 2010, 132, 5578-5579.
40. G. Calleja, J.A. Botas, M. Sánchez-Sánchez, M.G. Orcajo, Hydrogen adsorption over Zeolite-like MOF materials modified by ion exchange. International Journal of Hydrogen Energy, 2010, 35, 9916-9923.
41. Zhonghua Xiang, Zan Hu, Dapeng Cao, Wantai Yang, Jianmin Lu, Bingyong Han, Wenchuan Wang, Metal-Organic Frameworks with Incorporated Carbon Nanotubes: Improving Carbon Dioxide and Methane Storage Capacities by Lithium Doping. Angew. Chem. Int. Ed., 2010, 50, 491-494.
42. Danil Dybtsev, Christian Serre, Barbara Schmitz, Barbara Panella, Michanel Hirscher, Michel Latroche, Philip L. Llewellyn, Stephane Cordier, Yann Molard, Mohamed Haouas, Francis Taulelle, Gerard Ferey, Influence of [Mo6Br8F6]2- Cluster Unit Inclusion within the Mesoporous Solid MIL-101 on Hydrogen Storage Performance. Langmuir, 2010, 26, 11283-11290.
43. Kristine K. Tanabe, Seth M. Cohen, Postsynthetic modification of metal-organic frameworks-a progress report. Chem. Soc. Rev., 2011, 40, 498-519.
44. Seth M. Cohen, Postsynthetic Methods for the Functionalization of Metal-Organic Frameworks. Chem. Rev., 2012, 112, 970-1000.
45. Marianne Lalonde, Wojciech Bury, Olga Karagiaridi, Zachary Brown, Joseph T. Hupp, Omar K. Farha, Transmetalation: routes to metal exchange within metal-organic frameworks. J. Mater. Chem. A, 2013, 1, 5453-5468.
46. Carl K. Brozek, Mirea Dincă, Cation exchange at the secondary building units of metal-organic frameworks. Chem. Soc. Rev., 2014, 43, 5456-5467.
47. Pravas Deria, Joseph E. Mondloch, Olga Karagiaridi, Wojciech Bury, Joseph T. Hupp, Omar K. Farha, Beyond post-synthesis modification: evolution of metal-organic frameworks via building block replacement. Chem. Soc. Rev., 2014, 43, 5896-5912.
48. Olga Karagiaridi, Wojciech Bury, Joseph E. Mondloch, Joseph T. Hupp, Omar K. Farha, Solvent-assisted linker exchange: An alternative to the de novo synthesis of unattainable metal-organic frameworks. Angew. Chem., 2014, 53, 4530-4540.
49. Seth M. Cohen, The Postsynthetic Renaissance in Porous Solids. J. Am. Chem. Soc., 2017, 139, 2855-2863.
50. Juncong Jiang, Yingbo Zhao, Omar M. Yaghi, Covalent Chemistry beyond Molecules. J. Am. Chem. Soc., 2016, 138, 3255-3265.
51. Andrew D. Burrows, Christopher G. Frost, Mary F. Mahon, Christopher Richardson, Sulfur-tagged metal-organic frameworks and their post-synthetic oxidation. Chem. Commun., 2009, 28, 4218-4220.
52. Marie Savonnet, Delphine Bazer-Bachi, Nicolas Bats, Javier Perez-Pellitero, Erwann Jeanneau, Vincent Lecocq, Catherine Pinel, David Farrusseng, Generic Postfunctionalization Route from Amino-Derived Metal-Organic Frameworks. J. Am. Chem. Soc., 2010, 132, 4518-4519.
53. Sergio J. Garibay, Zhenqiang Wang, Kristine K. Tanabe, Seth M. Cohen, Postsynthetic Modification: A Versatile Approach Toward Multifunctional Metal-Organic Frameworks. Inorg. Chem., 2009, 48, 7341-7349.
54. Omar K. Farha, Karen L. Mulfort, Joseph T. Hupp, An Example of Node-Based Postassembly Elaboration of a Hydrogen-Sorbing, Metal-Organic Framework Material. Inorg. Chem., 2008, 47, 10223-10225.
55. Young Kyu Hwang, Do-Young Hong, Jong-San Chang, Sung Hwa Jhung, You-Kyong Seo, Jinheung Kim, Alexandre Vimont, Marco Daturi, Christian Serre, Gérard Férey, Amine Grafting on Coordinatively Unsaturated Metal Centers of MOFs: Consequences for Catalysis and Metal Encapsulation. Angew. Chem., 2008, 120, 4212-4216.
56. Teppei Yamada, Hiroshi Kitagawa, Protection and Deprotection Approach for the Introduction of Functional Groups into Metal-Organic Frameworks. J. Am. Chem. Soc., 2009, 131, 6312-6313.
57. Rajesh K. Deshpande, Jozeph L. Minnaar, Shane G. Telfer, Thermolabile Groups in Metal-Organic Frameworks: Suppression of Network Interpenetration, Post-Synthetic Cavity Expansion, and Protection of Reactive Functional Groups. Angew. Chem., 2010, 122, 4702-4706.
58. Nicholas C. Burtch, Himanshu Jasuja, Krista S. Walton, Water Stability and Adsorption in Metal-Organic Frameworks. Chem. Rev., 2014, 114, 10575-10612.
59. Syamantak Roy, Venkata M. Suresha, Tapas Kumar Maji, Self-cleaning MOF: realization of extreme water repellence in coordination driven self-assembled nanostructures. Chem. Sci., 2016, 7, 2251-2256.
60. Koya Prabhakara Rao, Masakazu Higuchi, Kenji Sumida, Shuhei Furukawa, Jingui Duan, Susumu Kitagawa, Design of Superhydrophobic Porous Coordination Polymers through the Introduction of External Surface Corrugation by the Use of an Aromatic Hydrocarbon Building Unit. Angew. Chem. Int. Ed., 2014, 53, 8225-8230.
61. Teng-Hao Chen, Ilya Popov, Oussama Zenasni, Olafs Daugulis, Ognjen Š. Miljanić, Superhydrophobic perfluorinated metal-organic frameworks. Chem. Commun., 2013, 49, 6846-6848.
62. Minghui Zhang, Xuelian Xin, Zhenyu Xiao, Rongming Wang, Liangliang Zhang, Daofeng Sun, A multi-aromatic hydrocarbon unit induced hydrophobic metal-organic framework for efficient C2/C1 hydrocarbon and oil/water separation. J. Mater. Chem. A, 2017, 5, 1168-1175.
63. Joseph G. Nguyen, Seth M. Cohen, Moisture-Resistant and Superhydrophobic Metal-Organic Frameworks Obtained via Postsynthetic Modification. J. Am. Chem. Soc., 2010, 132, 4560-4561.
64. Chuanyao Liu, Qian Liu, Aisheng Huang, A superhydrophobic zeolitic imidazolate framework (ZIF-90) with high steam stability for efficient recovery of bioalcohols. Chem. Commun., 2016, 52, 3400-3402.
65. Hai-Feng Zhang, Mian Li, Xue-Zhi Wang, Dong Luo, Yi-Fang Zhao, Xiao-Ping Zhou, Dan Li, Fine-tuning metal-organic framework performances by spatially-differentiated postsynthetic modification. J. Mater. Chem. A, 2018, 6, 4260-4265.
66. Qi Sun, Hongming He, Wen-Yang Gao, Briana Aguila, Lukasz Wojtas, Zhifeng Dai, Jixue Li, Yu-Sheng Chen, Feng-Shou Xiao, Shengqian Ma, Imparting amphiphobicity on single-crystalline porous materials. Nat Commun, 2016, 7, 13300.
67. Jerome Canivet, Sonia Aguado, Cecile Daniel, David Farrusseng, Engineering the Environment of a Catalytic Metal-Organic Framework by Postsynthetic Hydrophobization. ChemCatChem, 2011, 3, 675-678.
68. Wang Zhang, Yingli Hu, Jin Ge, Hai-Long Jiang, and Shu-Hong Yu, A Facile and General Coating Approach to Moisture/Water-Resistant Metal-Organic Frameworks with Intact Porosity. J. Am. Chem. Soc., 2014, 136, 16978-16981.
69. Wen Meng, Zhijuan Feng, Feng Li, Taohai Li, Wei Cao, Porous coordination polymer coatings fabricated from Cu3(BTC)2·3H2O with excellent superhydrophobic and superoleophilic properties. New J. Chem., 2016, 40, 10554-10559.
70. Kolleboyina Jayaramulu, Kasibhatta Kumara Ramanatha Datta, Christoph Rösler, Martin Petr, Michal Otyepka, Radek Zboril, Roland A. Fischer, Biomimetic Superhydrophobic/Superoleophilic Highly Fluorinated Graphene Oxide and ZIF-8 Composites for Oil-Water Separation. Angew. Chem. Int. Ed., 2016, 55, 1178.
71. Zixi Kang, Sasa Wang, Lili Fan, Zhenyu Xiao, Rongming Wang, Daofeng Sun, Surface wettability switching of metal-organic framework mesh for oil-water separation. Materials Letters, 2017, 189 , 82-85.
72. Xukun Qian, Fuxing Sun, Jing Sun, Hongyu Wu, Fei Xiao, Xinxin Wua, Guangshan Zhu, Imparting surface hydrophobicity to metal-organic frameworks using a facile solution-immersion process to enhance water stability for CO2 capture. Nanoscale, 2017, 9, 2003-2008.
73. Gang Wen, ZhiGuang Guo, Facile modification of NH2-MIL-125(Ti) to enhance water stability for efficient adsorptive removal of crystal violet from aqueous solution. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2018, 541, 58-67.
74. Shushan Yuan, Junyong Zhu, Yi Li, Yan Zhao, Jian Li,a Peter Van Puyvelde, Bart Van der Bruggen, Structure architecture of micro/nanoscale ZIF-L on a 3D printed membrane for a superhydrophobic and underwater superoleophobic surface. J. Mater. Chem. A, 2019, 7, 2723-2729.
75. Jingcheng Du, Changyuan Zhang, Hong Pu, Yufeng Li, Saimeng Jin, Luxi Tan, Cailong Zhou, Lichun Dong, HKUST-1 MOFs decorated 3D copper foam with superhydrophobicity/superoleophilicity for durable oil/water separation. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2019, 573, 222-229.
76. Chao Chen, Corinne A. Allen, Seth M. Cohen, Tandem Postsynthetic Modification of Metal-Organic Frameworks Using an Inverse-Electron-Demand Diels-Alder Reaction. Inorg. Chem., 2011, 50, 10534-10536.
77. Liang Feng, Sheng-Han Lo, Kui Tan, Bing-Han Li, Shuai Yuan, Yi-Feng Lin, Chia-Her Lin, Sue-Lein Wang, Kuang-Lieh Lu, Hong-Cai Zhou, An Encapsulation-Rearrangement Strategy to Integrate Superhydrophobicity into Mesoporous Metal-Organic Frameworks. Matter, 2020, 2, 988-999.
78. Pravas Deria, Yongchul G. Chung, Randall Q. Snurr, Joseph T. Hupp, Omar K. Farha, Water stabilization of Zr6-based metal-organic frameworks via solvent-assisted ligand incorporation. Chem. Sci., 2015, 6, 5172-5176.
79. Shuliang Yang, Vikram V. Karve, Anita Justin, Ilia Kochetygov, Jordi Espín, Mehrdad Asgari, Olga Trukhina, Daniel T. Sun, Li Peng, Wendy L. Queen, Enhancing MOF performance through the introduction of polymer guests. Coordination Chemistry Reviews, 2021, 427, 213525.
80. Takashi Uemura, Kana Kitagawa, Satoshi Horike, Takashi Kawamura, Susumu Kitagawa, Motohiro Mizuno, Kazunaka Endo, Radical polymerisation of styrene in porous coordination polymers. Chem. Commun., 2005, 48, 5968-5970.
81. Benjamin Le Ouay, Mickael Boudot, Takashi Kitao, Takeshi Yanagida, Susumu Kitagawa, Takashi Uemura, Nanostructuration of PEDOT in Porous Coordination Polymers for Tunable Porosity and Conductivity. J. Am. Chem. Soc., 2016, 138, 10088-10091.
82. Nan Ding, Haiwei Li, Xiao Feng, Qianyou Wang, Shan Wang, Li Ma, Junwen Zhou, and Bo Wang, Partitioning MOF-5 into Confined and Hydrophobic Compartments for Carbon Capture under Humid Conditions. J. Am. Chem. Soc., 2016, 138, 10100-10103.
83. Zhenjie Zhang, Ha Thi Hoang Nguyen, Stephen A. Miller, Seth M. Cohen, polyMOFs: A Class of Interconvertible Polymer-Metal-Organic-Framework Hybrid Materials. Angew. Chem. Int. Ed., 2015, 54, 6152-6157.
84. Yuanyuan Zhang, Xiao Feng, Haiwei Li, Yifa Chen, Jingshu Zhao, Shan Wang, Lu Wang, Bo Wang, Photoinduced Postsynthetic Polymerization of a Metal-Organic Framework toward a Flexible Stand-Alone Membrane. Angew. Chem. Int. Ed., 2015, 54, 4259-4263.
85. Bing-Jian Yao, Luo-Gang Ding, Fei Li, Jiang-Tao Li, Qi-Juan Fu, Yujie Ban, Ang Guo, Yu-Bin Dong, Chemically Cross-Linked MOF Membrane Generated from Imidazolium-Based Ionic Liquid-Decorated UiO-66 Type NMOF and Its Application toward CO2 Separation and Conversion. ACS Applied Materials & Interfaces, 2017, 9, 38919-38930.
86. Shunjiro Nagata, Kenta Kokado, Kazuki Sada, Metal-organic framework tethering PNIPAM for ON-OFF controlled release in solution. Chem. Commun., 2015, 51, 8614-8617.
87. Vincent J. Pastore, Timothy R. Cook, Javid Rzayev, Polymer-MOF Hybrid Composites with High Porosity and Stability through Surface-Selective Ligand Exchange. Chemistry of Materials, 2018, 30, 8639-8649.
88. Daewon Kim, Hwon Im, Moo Jin Kwak, Eunkyoung Byun, Sung Gap Im, Yang-Kyu Choi, A Superamphiphobic Sponge with Mechanical Durability and a Self-Cleaning Effect. Sci Rep, 2016, 6, 29993.
89. Jiahui Gu, Hongwei Fan, Chunxi Li, Jürgen Caro, Hong Meng, Robust Superhydrophobic/Superoleophilic Wrinkled Microspherical MOF@rGO Composites for Efficient Oil-Water Separation. Angew. Chem. Int. Ed., 2019, 58, 5297-5301.
90. Mingbo Shi, Renliang Huang, Wei Qi, Rongxin Su, Zhimin He, Synthesis of superhydrophobic and high stable Zr-MOFs for oil-water separation. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2020, 602, 125102.
91. Kun-Yi Andrew Lin, Hsuan-Ang Changa, Bo-Jau Chen, Multi-functional MOF-derived magnetic carbon sponge. Journal of Materials Chemistry A, 2016, 4, 13611-13625.
92. Liang Feng, Kun-Yu Wang, Gregory S. Day, Matthew R. Ryder, Hong-Cai Zhou, Destruction of Metal-Organic Frameworks: Positive and Negative Aspects of Stability and Lability. Chemical Reviews, 2020, 120, 13087-13133.
93. Mark Kalaj, Kyle C. Bentz, Sergio Ayala, Joseph M. Palomba, Kyle S. Barcus, Yuji Katayama, Seth M. Cohen, MOF-Polymer Hybrid Materials: From Simple Composites to Tailored Architectures. Chemical Reviews, 2020, 120, 8267-8302.
94. Hongliang Wang, Sanfeng He, Xuedi Qin, Conger Li, Tao Li, Interfacial Engineering in Metal-Organic Framework-Based Mixed Matrix Membranes Using Covalently Grafted Polyimide Brushes. J. Am. Chem. Soc., 2018, 140, 17203-17210.
95. Simon M. Ivesona, James D. Litster, Karen Hapgood, Bryan J. Ennis, Nucleation, growth and breakage phenomena in agitated wet granulation processes: a review. Powder Technology, 2001, 117, 3-39.
96. Bardiya Valizadeh, Tu N. Nguyen, Kyriakos C. Stylianou, Shape engineering of metal-organic frameworks. Polyhedron, 2018, 145, 1-15.
97. Anil H. Valekar, Kyung-Ho Cho, U-Hwang Lee, Ji Sun Lee, Ji Woong Yoon, Young Kyu Hwang, Seung Gwan Lee, Sung June Cho, Jong-San Chang, Shaping of porous metal-organic framework granules using mesoporous ρ-alumina as a binder. RSC Adv., 2017, 7, 55767-55777.
98. Yifa Chen, Xianqiang Huang, Shenghan Zhang, Siqing Li, Sijia Cao, Xiaokun Pei, Junwen Zhou, Xiao Feng, Bo Wang, Shaping of Metal-Organic Frameworks: From Fluid to Shaped Bodies and Robust Foams. J. Am. Chem. Soc., 2016, 138, 34, 10810-10813.
99. Yuge Zhang, Yufei Zhang, Xianfeng Wang, Jianyong Yu, Bin Ding, Ultrahigh Metal-Organic Framework Loading and Flexible Nanofibrous Membranes for Efficient CO2 Capture with Long-Term, Ultrastable Recyclability. ACS Appl. Mater. Interfaces, 2018, 10, 34802-34810.
100. Chi-Hao Chang, Tsao-Cheng Huang, Chih-Wei Peng, Tzu-Chun Yeh, Hsin-I Lu, Wei-I Hung, Chang-Jian Weng, Ta-I Yang, Jui-Ming Yeh, Novel anticorrosion coatings prepared from polyaniline/graphene composites. Carbon, 2012, 50, 5044-5051.
101. Wei Li, Electrodeposition of PANI/MWCNT Coatings on Stainless Steel and Their Corrosion Protection Performances. Int. J. Electrochem. Sci., 2018, 13, 1367-1375.
102. M.I. Khan1, A. Amari, A. Mustafa, H. Shoukry, Ismat H. Ali, Saviour A. Umoren, A. Madhan Kumar, Synthesis, Characterization and Application of Ferrochrome slag/polyaniline Nanocomposite as Corrosion Protection Coatings for Carbon Steel. Int. J. Electrochem. Sci., 2018, 13, 7385-7396.
103. Abdalrhman G. Al-Gamal, Ahmed A. Farag, Elsayed M. Elnaggar, Khalid I. Kabel, Comparative impact of doping nano-conducting polymer with carbon and carbon oxide composites in alkyd binder as anti-corrosive coatings. Composite Interfaces, 2018, 25, 959-980.
104. Jeenat Aslam, Irfan Hussain Lone, Nagi Radwan, Mohammad Mobin, Saman Zehra, Ruby Aslam, Development of Poly(aniline-co-o-toluidine)/TiO2 nanocomposite coatings for low carbon steel corrosion in 3.5% NaCl solution. Journal of Adhesion Science and Technology, 2018, 32, 2552-2568.
105. Gen Hayase, Kazuyoshi Kanamori, Masashi Fukuchi, Hironori Kaji, Kazuki Nakanishi, Facile Synthesis of Marshmallow-like Macroporous Gels Usable under Harsh Conditions for the Separation of Oil and Water. Angew. Chem. Int. Ed., 2013, 52, 1986-1989.
106. Hengchang Bi, Zongyou Yin, Xiehong Cao, Xiao Xie, Chaoliang Tan, Xiao Huang, Bo Chen, Fangtao Chen, Qingling Yang, Xinyang Bu, Xuehong Lu, Litao Sun, Hua Zhang, Carbon Fiber Aerogel Made from Raw Cotton: A Novel, Efficient and Recyclable Sorbent for Oils and Organic Solvents. Adv. Mater., 2013, 25, 5916-5921.
107. Xuchun Gui, Jinquan Wei, Kunlin Wang, Anyuan Cao, Hongwei Zhu, Yi Jia, Qinke Shu, Dehai Wu, Carbon Nanotube Sponges. Adv. Mater., 2010, 22, 617-621.
108. Yang Zhao, Chuangang Hu, Yue Hu, Huhu Cheng, Prof. Gaoquan Shi, Liangti Qu, A Versatile, Ultralight, Nitrogen-Doped Graphene Framework. Angew. Chem. Int. Ed., 2012, 51, 11371-11375.
109. Haiyan Sun, Zhen Xu, Chao Gao, Multifunctional, Ultra-Flyweight, Synergistically Assembled Carbon Aerogels. Adv. Mater., 2013, 25, 2554-2560.
110. Duc Dung Nguyen, Nyan-Hwa Tai, San-Boh Lee, Wen-Shyong Kuo, Superhydrophobic and superoleophilic properties of graphene-based sponges fabricated using a facile dip coating method. Energy Environ. Sci., 2012, 5, 7908-7912.
111. Yue Liu, Junkui Ma, Tao Wu, Xingrui Wang, Guanbo Huang, Yu Liu, Haixia Qiu, Yi Li, Wei Wang, Jianping Gao, Cost-Effective Reduced Graphene Oxide-Coated Polyurethane Sponge As a Highly Efficient and Reusable Oil-Absorbent. ACS Applied Materials & Interfaces, 2013, 5, 10018-10026.
112. Changping Ruan, Kelong Ai, Xingbo Li, Lehui Lu, A Superhydrophobic Sponge with Excellent Absorbency and Flame Retardancy. Angew. Chem. Int. Ed., 2014, 53, 5556-5560.
113. Viet Hung Pham, James H. Dickerson, Superhydrophobic Silanized Melamine Sponges as High Efficiency Oil Absorbent Materials. ACS Applied Materials & Interfaces, 2014, 6, 14181-14188.
114. Bing-Han Li, Sue-Lein Wang, Souvik Pal, Pamela Berilyn So, Guan-Ying Chen, Wei-Jie Huang, Yu-Ling Hsu, Szu-Yu Kuo, Jui-Ming Yeh, Chia-Her Lin, Versatile reactions on hydrophobic functionalization of metal-organic frameworks and anticorrosion application. Microporous and Mesoporous Materials, 2021, 325, 111319.
115. DS BIOVIA. Dassault Systèmes BIOVIA. Retrieved 24 January 2017.
116. Allen C. Larson, Robert B. Von Dreele. Generalized Structure Analysis System, Los Alamos National Laboratory, Los Alamos NM (1986).