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研究生: 謝東穎
Hsieh, Tung-Ying
論文名稱: PAA-NH4被覆高分子抑制劑之鈦酸鋇粉體正方性及介電分析
Tetragonality and Dielectric Analysis of Barium Titanate Powder Coated with Polymer Inhibitors
指導教授: 簡朝和
口試委員: 向性一
王錫福
簡朝和
學位類別: 碩士
Master
系所名稱: 工學院 - 材料科學工程學系
Materials Science and Engineering
論文出版年: 2011
畢業學年度: 99
語文別: 中文
論文頁數: [51]
中文關鍵詞: 介電常數居禮溫度正方性濕式球磨法鈦酸鋇阻抗頻譜分析
外文關鍵詞: Dielectric constant, Curie point, Tetragonality, Wet ball-milling, Barium Titanium, Impedance analysis
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  • 本研究在鈦酸鋇粉體表面被覆高分子作為粉體成長的抑制劑,使粉體在高溫過程中凝團成長受到抑制,並透過空氣及氮氣的切換控制抑制劑的殘存量,達到粒徑大小的控制。研究結果顯示,在高溫熱處理下,鈦酸鋇粉體粒徑會隨著高分子被覆量的增加而變小;同時,透過X光繞射圖譜及拉曼光譜的分析結果顯示,粉體的正方性會隨著粒徑的變小而下降。並利用阻抗頻譜模擬分析與熱差分析儀證實粉體的介電常數及居禮溫度也會隨著粒徑的變小而下降。最後將1000oC下被覆2.5wt% PAA-NH4之鈦酸鋇粉體進行濕式球磨法,在不改變其正方性的狀態下使粉體粒徑下降。


    The barium titanate powder, coated with various amounts of PAA-NH4 polymer inhibitor, was heat treated in different atmosphere to control the particle size. The results show that particle size will decrease as increasing amounts of PAA-NH4 polymer inhibitor. As the particle size decreasing, the tetragonality, dielectric constant and Curie point of the powder will become smaller.

    1.前言…………………………………………………………………1 2.實驗方法……………………………………………………………3 2.1原料………………………………………………………….3 2.2 樣品的製備…………………………………………………3 2.2.1 被覆(Coating)流程…………………………………..3 2.2.2 煆燒(Calcination)流程………………………………4 2.3 實驗基本量測方法…………………………………………4 2.3.1 熱重損失量量測…………………………………….4 2.3.2 列塔電位量測……………………………………….4 2.3.3 表面官能機的量測………………………………….4 2.3.4 粒徑大小量測……………………………………….5 2.3.5 正方性(Tetragonality)量測………………………….5 2.3.6 粉體介電常數量測………………………………….6 2.3.7 拉曼光譜的量測…………………………………….6 2.3.8 居禮溫度的量測…………………………………….7 3. 結果與討論…………………………………………………………8 3.1高分子材料的熱穩定性分析……………………………….8 3.2 PAA-NH4在鈦酸鋇表面上的吸附行為…………………….8 3.2.1 鈦酸鋇粉末的表面電位……………………………8 3.2.2 PAA-NH4在鈦酸鋇表面的吸附行為與機制探討… 9 3.3 PAA-NH4的吸附對粉末粒徑的影響…………………………9 3.4 粒徑效應(Size effect)對相組成的影響………………………10 3.5 相組成(Phase composition)變化對鈦酸鋇粉體之物理性質的 影響…………………………………………………………12 3.6 濕式球磨法對粉體粒徑及其正方性的影響………………..14 4. 結論…………………………………………………………………16 5. 參考文獻……………………………………………………………17

    5. 參考文獻
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