研究生: |
謝東穎 Hsieh, Tung-Ying |
---|---|
論文名稱: |
PAA-NH4被覆高分子抑制劑之鈦酸鋇粉體正方性及介電分析 Tetragonality and Dielectric Analysis of Barium Titanate Powder Coated with Polymer Inhibitors |
指導教授: | 簡朝和 |
口試委員: |
向性一
王錫福 簡朝和 |
學位類別: |
碩士 Master |
系所名稱: |
工學院 - 材料科學工程學系 Materials Science and Engineering |
論文出版年: | 2011 |
畢業學年度: | 99 |
語文別: | 中文 |
論文頁數: | [51] |
中文關鍵詞: | 介電常數 、居禮溫度 、正方性 、濕式球磨法 、鈦酸鋇 、阻抗頻譜分析 |
外文關鍵詞: | Dielectric constant, Curie point, Tetragonality, Wet ball-milling, Barium Titanium, Impedance analysis |
相關次數: | 點閱:2 下載:0 |
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本研究在鈦酸鋇粉體表面被覆高分子作為粉體成長的抑制劑,使粉體在高溫過程中凝團成長受到抑制,並透過空氣及氮氣的切換控制抑制劑的殘存量,達到粒徑大小的控制。研究結果顯示,在高溫熱處理下,鈦酸鋇粉體粒徑會隨著高分子被覆量的增加而變小;同時,透過X光繞射圖譜及拉曼光譜的分析結果顯示,粉體的正方性會隨著粒徑的變小而下降。並利用阻抗頻譜模擬分析與熱差分析儀證實粉體的介電常數及居禮溫度也會隨著粒徑的變小而下降。最後將1000oC下被覆2.5wt% PAA-NH4之鈦酸鋇粉體進行濕式球磨法,在不改變其正方性的狀態下使粉體粒徑下降。
The barium titanate powder, coated with various amounts of PAA-NH4 polymer inhibitor, was heat treated in different atmosphere to control the particle size. The results show that particle size will decrease as increasing amounts of PAA-NH4 polymer inhibitor. As the particle size decreasing, the tetragonality, dielectric constant and Curie point of the powder will become smaller.
5. 參考文獻
1 S.W. Kwon, D.H. Yoon, “Tetragonality of Nano-Sized Barium Titanate Powder Prepared with Growth Inhibitors upon Heat Treatment” Journal of the European Ceramic Society, 27 247–252 (2007).
2 Vivekanandan, R. and Kutty, T. R. N., “Characterization of Barium Titanate Fine Powders Formed from Hydrothermal Crystallization.” Powder Tech., 57 181–192 (1989).
3 Hennings, D. F. K., Metzmacher, C. and Schreinemacher, B. S., “Defect Chemistry and Microstructure of Hydrothermal Barium Titanate. ” J. Am.Ceram. Soc., 84(1) 179–182( 2001).
4 Noma, Tatsuo; Wada, Satoshi; Yano, Mamoru; Suzuki, Takeyuk.
“Analysis of Lattice Vibration in Fine Particles of Barium Titanate Single
Crystal Including the Lattice Hydroxyl Group”, Journal of Applied Physics , 80 (9) 5223 – 5233 (1996).
5 D. J. Shaw, “Introduction to Colloid and Surface Chemistry”, Butterworth Heimann, 182 ( 1992).
6 Uchino, K., Sadanaga, E. and Hirose, T., “ Dependence of the Crystal Structure on Particle Size in Barium Titanate. ” J. Am. Ceram. Soc.,72(8) 1555–1558 (1989).
7 Arlt, G., Hennings, D. and With, G. D., “ Dielectric Properties of Finegrained Barium Titanate Ceramics. ” J. Appl. Phys., 58(4) 1619–1625 (1985).
8 Begg, B. D., Vance, E. R. and Nowotny, J., “Effect of Particle Size on the Room-Temperature Crystal Structure of Barium Titanate. ”J. Am. Ceram. Soc.,77(12) 3186–3192 (1994).
9 D. J. Bergman, “The Dielectric Constant of Composite Material—A Problem of Classical Physics ” Phys. Rep., 43 377–407 (1978).
10 K. Wakino, K. Yukawa, and S. Imagawa, “Method of Measuring Dielectric Constant of Powder” US Patent #5451882 (1995).
11 S. Wada, H. Yasuno, T. Hoshina, S-M Nam, H. Kakemoto, and T. Tsurumi, “Preparation of nm-Sized Barium Titanate Fine Particles and their Powder DielectricProperties, ” Jpn. J. Appl. Phys, 42[9B] 6188–6195 (2003).
12 T. Tsurumi, T. Sekine, H. Kakemoto, T. Hoshina, S-M. Nam, H. Yasuno, and S. Wada, “Evaluation of Dielectric Permittivity of Barium Titanate Fine Powders”; Materials Research Society Symposium Proceedings, 7 243 (2005).
13 A. Manohar and F. Dogan, “Dielectric Properties of Suspensions Containing BaTiO3 Particles”; pp. in Ceramic Transactions, Advances in Electronic and Electrochemical Ceramics,179, 93–102 (2005) .
14Arlt, G.; Hennings, D.; de With, G. “Dielectric Properties of Fine-Grained Barium Titanate Ceramics” ,Journal of Applied Physics, 58 1619-1625 (1985) .
15 M. Kuwabara* and H. Matsuda “Shift of the Curie Point of Barium Titanate Ceramics with Sintering Temperature”, J. Am. Ceram. Soc., 80 [10] 2590–96 (1997).