以鎳金屬錯合物NiCl2(PPh3)2為催化劑可以成功的將1,2-雙烯(1a-e)、芳香基或烯基碘化合物(2a-h)及有機烯基鋯金屬試劑(3a-d)在一鍋反應之下，進行三分子偶合反應(three-components coupling reaction)，成功的得到1,4-雙烯衍生物(4a-q)。此加成反應都是發生在1,2-雙烯末端未取代的雙鍵上，具有極佳的位向選擇性。產物大多為E form，所以反應也具有不錯的立體選擇性。
另外，利用此鎳金屬錯合物NiCl2(PPh3)2也可以成功的催化7-氧庚二烯及其衍生物(5a-e)與有機烯基鋯金屬試劑(3a-h)進行開環加成反應，得到cis-2-alkenyl-dihydronaphthalene的衍生物 (6a-l, 7a-c)，反應只得到單一產物且為順式(cis form)產物，因此此反應具有極佳的位向(regio-)及立體選擇性(stereoselective)。而且此反應之反應機構也相當地有趣。
但是只有在不同配位基的鎳金屬錯合物NiBr2(dppe)催化下，才能將有機烷基鋯金屬試劑(alkylzirconium reagent)(15a-j)與7-氧庚二烯及其衍生物(5a-c)進行加成開環反應(ring-opening reaction)，得到cis-2-alkyl-dihydronaphthalene的衍生物 (16a-m)，且此催化系統可以擴大至丙烯基鋯金屬試劑(allylzirconium reagents)中間體(18a-c)上進行反應，這個反應所得到的產物也一樣具有很好的位向及立體選擇性。
我們也成功的利用鈷金屬錯合物CoI2(PPh3)2催化1,6-庚二炔化合物(1,6-heptadiynes)(24a-g)與丙二烯衍生物(25a-e) 進行[2+2+2]環化加成反應，得到多取代基苯環衍生物(27a-m, 28a-d)，若反應使用非對稱性的1,6-雙炔化合物，則產物幾乎全部為間位(meta)的化合物28，幾乎沒有鄰位(ortho)的產物產生，可見這個反應具有非常高的位向(regio)及化學選擇性(chemoselective)。
此CoI2(PPh3)2/Zn催化系統也可以成功的將雙炔(31a-g)化合物與剛性結構之 norbornene衍生物(32a,b)上的碳-碳雙鍵進行三分子環化加成反應(cyclotrimerization) ，成功地得到具多重環(multiple rings)之環己二烯架構之衍生物(33a-k)上，此反應比以前所報導過的利用釕(Ru) 金屬錯合物催化下所能使用的反應物還要廣。

1,2-Dienes (1a-e) and alkenylzirconium reagents (3a-d) underwent three-component assembly with a variety of aromatic iodides or vinyl iodide (2a-h) in the presence of NiCl2(PPh3)2, and Zn powder in dry THF at 50 □C for 24 h to furnish the corresponding 1,4-diene derivatives (4a-q) in moderate to good yields with very high regio- and stereoselectivity. In all of these three-component assembly reactions, the E isomers were formed predominantly with E/Z ratios between 94/6 to 99/1.
Treatment of 7-oxa- and 7-azabenzonorbornadienes (5a-e) with various alkenylzirconium reagents (3a-h) in the presence of NiCl2(PPh3)2, and Zn powder in dry THF at 50 □C for 12 h (or a combination of ZnCl2 and NEt3) afforded the corresponding cis-2-alkenyl-1,2-dihydro naphthalene derivatives (6a-l, 7a-c) in moderate to excellent yields with high regio- and stereoselectivity.
Treatment of 7-oxabenzonorbornadienes (5a-c) with various alkylzirconium reagents (15a-j) in the presence of NiBr2(dppe), and Zn powder in dry THF at 50 □C for 12 h afforded the corresponding cis-2-alkyl-1,2-dihydronaphthalene derivatives (16a-m) in good yields with high regio- and stereoselectivity.
The CoI2(PPh3)2/Zn system effectively catalyzed the [2+2+2] ene-diyne cycloaddition of 1,6-heptadiynes (24a-g) with allenes (25a-e) in a highly regio- and chemoselective fashion to yield substituted benzene derivatives (27a-m, 28a-d) in good to excellent yields.
Treatment of diynes (31a-g) with norbornenes (32a,b) in the presence of CoI2(PPh3)2 and Zn powder in 1,2-dichloroethane at 80 □C for 12 h afforded [2+2+2] cocyclotrimerization adduct (33a-k) exclusively in good yields. These cobalt-catalyzed results are in contrast to the ruthenium-catalyzed reaction of diyne with norbornene reported previously.

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