研究生: |
魏士淵 Wei, Shih-Yuan |
---|---|
論文名稱: |
以共濺鍍方式製備氧化鋅鎂薄膜做為銅銦鎵硒無鎘緩衝層之研究 Study of Co-Sputtered Zn1-XMgXO as Cd-Free Buffer Layer on Cu(In,Ga) Se2 Solar Cell |
指導教授: |
林樹均
Lin, Su-Jien 賴志煌 Lai, Chih-Huang |
口試委員: |
林樹均
賴志煌 闕郁倫 施文傑 羅文勳 |
學位類別: |
碩士 Master |
系所名稱: |
工學院 - 材料科學工程學系 Materials Science and Engineering |
論文出版年: | 2011 |
畢業學年度: | 99 |
語文別: | 中文 |
論文頁數: | 64 |
中文關鍵詞: | 銅銦鎵硒 、緩衝層 、氧化鎂鋅 |
外文關鍵詞: | CIGS, buffer layer, ZMO, ZnMgO, Zn1-xMgxO |
相關次數: | 點閱:2 下載:0 |
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Cu(In,Ga)Se2 (CIGS)薄膜型太陽能電池以高效率聞名,並且在近幾年內已被廣泛的討論,其最高效率則是以硫化鎘(CdS)作為緩衝層。基於鎘對於環境以及人體都有不好的影響,無鎘緩衝層的研究也隨之而生,例如氧化鎂鋅 (Zn1-XMgXO)、硫化鋅 (ZnS)以及硫化銦 (InS)。本研究將採取共濺鍍的方式,並且著重於不同鎂摻雜來源(Mg, MgO)所鍍製出的氧化鎂鋅薄膜,對其薄膜性質以及應用在CIGS太陽能電池無鎘緩衝層的效率表現影響。
本研究將採用紫外-可見光譜、 X光繞射、X光光電子能譜儀、歐傑電子能譜儀、掃描式電子顯微鏡以及霍爾量測來分析其薄膜性質,並且使用光電流-電壓、暗電流電-電壓、電容-電壓以及外部量子效應來量測太陽能電池光電轉換效率表現。利用Mg靶材共鍍的薄膜其電阻率明顯較低,並且在太陽能電池表現上也較好。
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