有鑑於大多數的文獻對於塊狀非晶合金的研究，通常對於力學性質方面的探討相較於物理性質方面來得多，所以本論文主要著重在研究鋯基塊狀非晶合金物理性質探討。藉由傳統銅模鑄造法，我們得到了三個以鋯為主要元素的合金，分別是Zr50Cu40Al10、Zr50Cu30Ni10Al10和Zr41.5Ti13.8Cu12.5Ni10Be22.5。將上列三種非晶相合金研磨成薄片之後，拿去經X-RAY diffraction確定其結構為「非晶相」，再利用傳統四點量測方法去測量其超導溫度、4.2-300K電阻率的變化、加9 Tesla磁場下4.2-300K電阻率的變化及不同定溫下的磁阻變化，以瞭解其性質，並試著找出解釋方法。後來結果發現對於電阻率在溫度4.2-300K的變化，無法完全的以已提出的理論模型來解釋，可能需要考慮其它修正或建立更完整的理論模型才行；此外，三個合金都有超導溫度，分別是0.61K、0.61K、0.73K；經由加入9 Tesla磁場，含10%鎳的Zr50Cu30Ni10Al10和Zr41.5Ti13.8Cu12.5Ni10Be22.5的電阻率並沒有明顯的變化，表示鎳在高磁場下對於電阻率幾乎沒有貢獻；最後這個三個合金只有在低溫（5K）的時候呈現正磁阻，而在其他溫度（100K、200K、300K）時磁阻並沒有太明顯的變化，除了Zr50Cu40Al10在高溫300K時有些許逆磁阻的趨勢。

We have measured the superconductivity transition temperature and transport properties of the three Zr-based bulk metallic glasses(BMGs), Zr_{50}Cu_{40}Al_{10}, Zr_{50}Cu_{30}Ni_{10}Al_{10}, and Zr_{41.2}Ti_{13.8}Cu_{12.5}Ni_{10}Be_{22.5} which were fabricated by using the ladle-hearth type arc-melt tilt-casting machine. At first,We determine the amorphous state of these alloys by X-ray diffraction pattern. The resistivities of them at room
temperature are 350, 236, 196 micro-omega cm, respectively. And the temperature coefficients of the resistivities (TCR) are all negative. We also fit the temperature dependence to
rho=a[1+be^{-2W(T)}] from 4.2K to 300K. By using this formula, we can calculate the Debye temperatures of the three Zr-based BMGs. At much lower temperature, the superconducting transition temperature of the BMGs is separately determined by using a 3He low temperature measurement system and their Tc are 0.61K, 0.61K, 0.73K, respectively. The magnetoresistance of theses three
BMGs show that when the temperature is 5K, all of them exhibit positive magnetoresistance due to the superconducting fluctuation, but at other fixed temperature such as 100K, 200K, 300K, there are no apparent field dependence of the resistance, except for the Zr_{50}Cu_{40}Al_{10} that exhibits small variation negative magnetoresistance at 300K.

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