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研究生： 馬少陽
Ma, Shao-Yang
論文名稱： 聚丙烯腈/氧化石墨烯改良基材膜於正滲透複合膜之應用
Polyacrylonitrile/Graphene Oxide Modified Film for the Application in Forward Osmosis Membrane
指導教授： 戴念華
Tai, Nyan-Hwa
口試委員: 洪仁陽
Hung, Ren-Yang
林冠佑
Lin, Guan-You
李紫原
Lee, Chi-Young
學位類別： 碩士
Master
系所名稱： 工學院 - 材料科學工程學系
Materials Science and Engineering
論文出版年： 2020
畢業學年度： 108
語文別： 中文
論文頁數： 93
中文關鍵詞： 正滲透複合薄膜 、正滲透 、分子級逐層堆疊法 、氧化石墨烯 、氧化石墨烯改良基材膜
外文關鍵詞： Thin-film composite membrane, Forward osmosis, Molecular layer-by-layer method, Graphene oxide, GO-modified substrate
相關次數： 點閱：2  下載：0 
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    • 本研究旨在製備具有高通量與高阻鹽之複合膜，並將其應用於正滲透(Forward osmosis, FO)分離程序，以期改善全球水資源短缺之問題。實驗首先製備聚丙烯腈(Polyacrylonitrile, PAN)高分子鑄模液，並使其經過倒相聚合法形成基材膜，接著將聚電解質沉積於PAN底表面上，隨後以分子級逐層堆疊法(Molecular layer-by-layer, mLBL)成長聚醯胺(Polyamide, PA)阻鹽層於經聚電解質沉積後之基材膜上。再者，本研究亦配製聚丙烯腈/氧化石墨烯(Polyacrylonitrile/ Graphene oxide, PAN/GO)之高分子鑄模液，進行基材膜之改良，製成複合膜後，比較不同重量氧化石墨烯混摻之聚丙烯腈性能差異。研究內容包含測試高分子漿料之帶電性，基材膜表面之親疏水性和表面、截面形貌，以及正滲透複合膜之表面與正滲透分析。研究結果顯示，經過氧化石墨烯的改良，複合膜擁有更好的正滲透效能。其中混摻0.2 wt% GO之複合膜擁有最佳之正滲透效能，在提取液為1 M氯化鈉，進流液為去離子水的情況下，其水通量可達18.15 LMH，逆溶質擴散維持在6.51 gMH，說明本實驗提出之製備複合膜方式未來可做為FO系統隔離膜之參考。本實驗也嘗試將氧化石墨烯混摻於阻鹽層中，研究結果顯示，分散不好的氧化石墨烯會破壞聚醯胺阻鹽層而使效能下降，若能提升氧化石墨烯於阻鹽層之分散性，將有機會能夠提升碳複合膜之正滲透效能表現。

    Water scarcity is one of the most critical problems in the world. To solve this problem, we design a high performance thin film composite (TFC) membrane for the forward osmosis (FO) application. First, we fabricate a polyacrylonitrile (PAN) substrate and deposite polyelectrolyte on it, followed by using the molecular layer-by-layer (mLBL) method to fabricate the polyamide (PA) active layer. Additionally, we modify the substrate by adding graphene oxide (GO) into the PAN cast solution while remaining the other processes unchanged.
    Results show that after GO modification of the PAN substrate, the substrate hydrophilicity and pore connectivity increase, and the FO performance is significantly improved. The best FO performance with water flux of 18.15 LMH and reverse salt flux of 6.51 gMH is achieved by the PAN/GO(0.2)250-PEIPAA-mLBL3 membrane, indicating that this novel method may have great potential used in future FO technologies.
    Furthermore, this work also tries to modify the PA layer by adding GO into it, and the results show that GO might damage the PA layer and get a higher Js value if the dispersity of GO is poor. Thus, how to increase the GO dispersity in PA layer may be a key factor to produce a high performance membrane.

    摘要 I Abstract II 致謝 III 目次 IV 表目次 VIII 圖目次 X 第一章 緒論 1 1.1 前言 1 1.2 研究動機 2 第二章 文獻回顧 3 2.1 薄膜技術簡介 3 2.1.1 薄膜定義 3 2.1.2 薄膜分離程序 4 2.1.3 薄膜型態 6 2.2 複合薄膜簡介與製備 8 2.2.1 多孔支撐層之製備 9 2.2.2 緻密選擇層之製備 10 2.3 正向滲透技術簡介 13 2.3.1 正向滲透技術之歷史與發展 14 2.3.2 正向滲透技術之原理與應用 14 2.3.3 正向滲透技術之瓶頸 15 2.4 石墨烯之簡介 20 2.4.1 石墨烯之製備方式 20 2.4.2 石墨烯於正滲透薄膜之應用 22 2.5 本實驗室過去在水資源的探討回顧 23 第三章 實驗方法與分析 36 3.1 實驗用化學藥品、實驗設備與材料分析儀器 37 3.1.1 電磁加熱攪拌器 37 3.1.2 高速離心機 38 3.1.3 超音波震盪機 38 3.1.4 介達電位分析儀 38 3.1.5 X射線繞射分析儀 39 3.1.6 場發射掃描式電子顯微鏡 39 3.1.7 原子力顯微鏡 40 3.1.8 水接觸角量測儀 40 3.1.9 正滲透效能測試系統 41 3.2 實驗方法及步驟 45 3.2.1 氧化石墨烯之製備 45 3.2.2 基材膜製備 46 3.2.3 聚醯胺阻鹽層之製備 48 第四章 結果與討論 57 4.1 聚丙烯腈混摻氧化石墨烯之漿料及基材膜分析 58 4.1.1 高分子漿料之介達電位分析 58 4.1.2 X射線繞射分析 59 4.1.3 水接觸角分析 59 4.1.4 場發式掃描電子顯微鏡之形貌分析 60 4.2 聚丙烯腈混摻氧化石墨烯之正滲透複合薄膜分析 62 4.2.1 場發式掃描電子顯微鏡之形貌分析 62 4.2.2 原子力顯微鏡之形貌觀察 63 4.2.3 正滲透效能之分析 64 4.2.4 不同提取液濃度對正滲透效能之影響 65 4.2.5 不同提取液濃度對壓力延遲滲透效能之影響 66 4.2.6 正滲透和壓力延遲滲透模式之比較 66 4.2.7 本研究製備之正滲透複合薄膜與商用膜及其他研究之複合膜效能比較 67 4.3 聚丙烯腈與聚醯胺阻鹽層混摻氧化石墨烯之正滲透複合薄膜分析 68 4.3.1 場發式掃描電子顯微鏡之形貌分析 68 4.3.2 正滲透效能之分析 69 第五章 結論 87 參考文獻 89

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