本論文是以固相微萃取(SPME)配合GC-ECD分析水中多氯聯苯(PCBs)為研究主題，分析之毒性物質為六種多氯聯苯化合物：2,4,4'-trichlorobiphenyl(PCB28)、2,2',5,5'-tetrachlorobiphenyl(PCB52)、2,2',4,5,5'-pentachlorobiphenyl(PCB101)、2,2',3,4,4',5'-pentachlorobiph- enyl(PCB138)、2,2',4,4',5,5'-hexachlorobiphenyl(PCB153)、2,2',3,4,4', 5,5'-heptachlorobiphenyl(PCB180)。
固相微萃取具有快速、省時、不需使用任何有機溶劑及符合經濟效率的優點，本實驗之研究重心在探索各種實驗變因對萃取效率所造成的影響，探討的主題包括：吸附和時間的關係、吸附和溫度的關係、脫附和時間的關係、脫附和溫度的關係、鹽類對吸附的影響、酸鹼值對吸附的影響、有機溶劑對吸附的影響、偵測極限、及湖水的測定。

實驗結果發現使用65μm PDMS/DVB纖維時，其偵測極限介於0.03ppb到0.1ppb之間，而使用100μm PDMS纖維時，其偵測極限介於0.02ppb到0.1ppb之間，且各分析物的檢量線也均有很好的線性。

Solid-phase microextraction (SPME) coupled with gas chromatography (GC) for the analysis of Polychlorinationated biphenyls(PCBs) is described. In this study 65-mm polydimethylsiloxane/divinylbenzene(PDMS/DVB) and 100-mm polydimethyl siloxane(PDMS) fibers were used. Several parameters of the extraction and desorption procedure were studied and optimized, such as extraction time, extraction temperature, desorption time, desorption temperature, ionic strength, organic solvent and pH. Using a 30-min SPME extraction, 65-mm PDMS/DVB fiber analysis with GC-ECD. The limits of detection was from 0.03 ng/mL to 0.10 ng/mL. And 100-mm PDMS fiber was from 0.02 ng/mL to 0.10 ng/mL. The linear correlation coefficient (>0.9977) of this method are all very well.

[1]黃賢達，化學, 54 (1996) 119
[2]黃寶慧、李茂榮，科儀新知，十八卷二期(1996)
[3]黃敬德、謝有容，科儀新知，十八卷四期(1997)
[4]黃敬德、謝有容，化學,56 (1998) 311
[5]Z. Zhang, M. J. Yang, J. Pawliszyn, Anal. Chem., 66 (1994) 884A
[6]SPME applications guide from SUPELCO, 1999
[7]O. Hutzinger, S Safe, V. Zikto, "The Chemistry of PCBs" CRC press, Cleveland
[8]"台灣電力公司含多氯聯苯廢電容器及變壓器處理可行性研究
工作報告書",財團法人台灣研究試驗中心, (1990) p.3-2
[9]S. Jensen, New Sci., 32 (1966) 612
[10]H. Tsukamato, S. Makisumi and H. Yoshimura, Fuk Oka Acta Med., 60 (1969) 496
[11]M. Kuratsune, Environ. Health Prospec., 1 (1969) 496
[12]陳國誠, 饒運財, 台灣植物保護中心毒理綜合論, 第12號(1980)
[13]P.H. Cheng, K.T. Chang, Y.D. Lu, Ball Environ. Contam. Toxicol., 26 (1981) 489
[14]W.J. Rogan, B.C. Galden, S.L. Koong and L.Y. Shih, Science, 241 (1980) 334
[15]K. Ballschmiter, M. Zell, Fresenius' Z. Anal. Chem., 302 (1980) 20
[16]P.D. Voogt, D.E. Wells, L. Retergardh, U.A. Brinkman, J. Environ. Anal Chem., 40 (1990) 1
[17]Code of Federal Regulations, 44 CFR 3833, US GPO, Washington, DC (1979)
[18]凌永健，環保科技通訊，第六卷第二期，民國八十二年九月，pp.7-17
[19]環署檢字第12636號公告NIEA R102.00C民國八十五年四月
[20]環署檢字第26444號公告NIEA R103.00C民國八十五年五月
[21]環署檢字第59200號公告NIEA R110.00C民國八十五年十月
[22]環署檢字第31085號公告NIEA R108.00C民國八十五年六月
[23]環署檢字第31083號公告NIEA R104.00C 民國八十五年六月
[24]H. Kessels, W. Hoogerwerf, J. Lips, J. Chromatogr. Sci., 30 (1992) 207
[25]C.L. Arthur, J. Pawliszyn, J. Water Pollut. Res. J. Can, 62 (1990) 2145-2148
[26]C.L. Arthur, L.M. Killam, K.D. Buchholz, J. Pawliszyn, J.R. Berg, Anal. Chem., 64 (1992) 1960-1966
[27]D. Louch, S. Motlagh, J. Pawliszyn, Anal. Chem., 64 (1992) 1187-1199
[28]M. Chai, C.L. Arthur, J. Pawliszyn, R.P. Belardi, K.F. Pratt, J. Analyst, 118 (1993) 1501-1505
[29]Z. Zhang, J. Pawliszyn, Anal. Chem., 65 (1993) 1843-1852
[30]K.D. Buchholz, J. Pawliszyn, J. Environ. Sci. Technol., 27 (1993) 2844-2848
[31]K.D. Buchholz, J. Pawliszyn, Anal. Chem., 66 (1994) 160-167
[32]Y. Yang, D. Miller, S. Hawthorne, J. Chromatogr., A 800 (1998) 257-266
[33]Y. Yang, S. Hawthorne, D. Miller, Anal. Chem., 70 (1998) 1866-1869
[34]T. Gorecki, R. Mindrup, J. Pawliszyn, Analyst, 121 (1996) 1381-1386
[35]C. Miege, J. Dugay, Aanalusis, 26 (1998) M137-M143
[36]C. Aguilar, S.Penalver, E. Pocurull, F. Borrull, R. Marce, J. Chromatogr., A 795 (1998) 105-115
[37]J. Lipinski, Fressen J. Anal. Chem., 367 (2000) 445-449
[38]W.R. Barrionuevo, F.M. Lancas, Hrc-j. High Res. Chrom., 23 (2000) 485-488
[39]L. Pan, M. Chong, J. Pawliszyn, J. Chromatogr., A 773 (1997) 249-260
[40]D. Gorlo, L. Wolska, B. Zygmunt, J. Namiesnik, Talanta, 44 (1997) 1543-1550
[41]R. Bartelt, B. Zilkowski, Anal. Chem., 71 (1999) 92-101
[42]H. Daimon, J. Pawiliszyn, Anal. Commun., 33 (1996) 421-424
[43]J. Langenfeld, S. Hawthorne, D. Miller, J. Chromatogr. A 740 (1996) 139-145
[44]Y.P. Liu, W.H. Ho, J. Chin. Chem. Soc-taip. 47 (2000) 415-420
[45]A. Zgang, G. Kopinke, J. Pawliszyn, Anal. Chem., 69 (1997) 597-600
[46]P. Bartak, L. Cap J. Chromatogr., A 767 (1997) 171-175
[47]I. Valor, C. Cortafa, J. Molto, J. High Res. Chromatogr., 19 (1996) 472-474
[48]S. Thomas, S. Ranjan, G. Webster, L. Sarna, Environ. Sci. Technol., 30 (1996) 1521
[49]S. Huang, C. Cheng, Y. Sung, Anal. Chim. Acta., 343 (1997) 101-108
[50]B. Dittmann, B. Zimmermann, C. Engelen, J. Agr. Food Chem., 48 (2000) 2887-2892
[51]J.C. Paniandy, J. Chane-Ming, J.C. Pieribattesti, J. Essent Oil Res., 12 (2000) 153-158
[52]T. Kumazawa, X. Lee, K. Sato, H. Seno, A. Lshii, O. Suzuki, Jpn. J. Forensic Toxicol., 13 (1995)182-188
[53]T. Kumazawa, K. Sato, H. Seno, A. Lshii, O. Suzuki, Chromatographia, 43 (1996) 59
[54]M. Chiarotti, R. Marsili, J Microcolumn Sep., 6 (1994) 577-581
[55]D. Figeys, Y. Ahang, R. Aebersold, Electrophoresis, 19 (1998) 2338-2347
[56]Y. Yang, D.J. Miller, S.B. Hawthorne, J Chromatogr., A 800 (1998) 1866
[57]S.B. Hawthorne, C.B. Grabanski, K.I. Hageman, D.J. Miller, J Chromatogr., A 814 (1998) 151-160
[58] B. Erik, S. Pat, D. Frank, J. Hans-Gerd, C. Carel, Anal. Chem., 71 (1999) 5213-5216
[59] L. Maria, L. Ken, F. Merv, Anal. Chem., 70 (1998) 2510-2515
[60]A.N. Clarke and D.J. Wilson, Sep. Purif. Methods, 7 (1987) 55
[61]E.L. Thackston, D.J. Wilson, J.S. Hanson, D.L. Miller, J. Water Pollut control Fed., 52 (1980) 317
[62]J.Gorechi, J. Pawliszyn, Anal. Chem., 67 (1995) 3265
[63]C.L. Arthur, L.M. Killam, K.D. Buchholz, J. Pawliszyn, J.R. Berg, Anal. Chem., 64 (1992) 1960-1966
[64]B.E. Richer, J.L. Ezzell, K.A. Roberts, D.W. Later, Anal. Chem., 67 (1995) 24
[65]Y. Yang, S.B. Hawhorne, D. J. Miller, Environ. Sci. Technol., 31 (1997) 430
[66]J.Y. Horng, S.D. Huang, J. Chromatogr., A 678 (1994) 133
[67]Z. Zhang, J. Pawliszyn, Anal. Chem., 67 (1995) 34
[68]J.A. Glaser, D.L. Foerst, G.D. McKee, S.A. Quave, W.L. Budde, Environ. Sci. Technol., 15 (1981) 1427
[69]G.H. Morrison, Anal. Chem., 52 (1980) 2241