研究先進連接板材應用於固態氧化物燃料電池

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研究生：	蘇科銓 Su, Ko Chuan
論文名稱：	研究先進連接板材應用於固態氧化物燃料電池 Development of advanced interconnect alloys for SOFC interconnect application
指導教授：	葉安洲 Yeh, An Chou 張士欽 Chang, Shih Chin
口試委員:	黃金川蔡哲瑋
學位類別：	碩士 Master
系所名稱：	工學院 - 材料科學工程學系 Materials Science and Engineering
論文出版年：	2016
畢業學年度：	104
語文別：	英文
論文頁數：	87
中文關鍵詞：	固態氧化物燃料電池、金屬連接板、成形性、釔、晶界工程
外文關鍵詞：	SOFC, Metallic interconnect, Formability, Yttrium, Grain boundary engineering
相關次數：	點閱：1 下載：0
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本研究使用Gleeble-3500熱機模擬器搭配CALPHAD-base Jmatpro及Deform-3D模擬軟體對鎳基CMH1、鎳鐵基CMH2與鐵基CMH3進行成形性實驗，並評斷其成形能力。探討添加100 ppm釔對鎳基SCY1、鎳鐵基SCY2及鐵基SCY3連接版應用特性的影響，除此之外，也探討晶界工程對CMH3連接版應用特性的影響。此研究中的連接版應用特性包括於800°C下：抗氧化能力試驗、面積比電阻值（ASR）、熱膨脹係數量測（CTE）以及鉻揮發趨勢。
使用電子天秤量測氧化增重的變化，四點探針量測高溫的材料電阻，熱機分析(TMA)熱膨脹的變化，化學反應附著粉末分析以檢測鉻揮發的多寡，實驗儀器囊括Gleeble熱機模擬器之壓縮模式、拋光研磨機、光學顯微鏡、電子顯微鏡、高溫爐、電弧熔煉爐、放電線切割機、二次離子質譜儀。研究結果顯示，鎳基CMH1之成形性差；鎳鐵基CMH2和鐵基CMH3之成形性良好。添加100 ppm釔能提升SCY1、SCY2及SCY3之抗氧化能力與高溫電性。於鉻揮發的表現，添加釔對SCY1和SCY3能降低鉻揮發，但對SCY2而言，添加釔之後，其鉻揮發變嚴重。另一方面，晶界工程處理的試片（RX2與STA1）與CMH3相比具較好的抗氧化能力與高溫電性。和CMH3比較，RX2試片有較低的鉻揮發，但STA1卻有較高的鉻揮發。除此之外，氧化增重結果也需要考慮材料的鉻揮發的影響。添加釔與晶界工程處理的試片，其熱膨脹係數沒有明顯得變化。

In present study, the formability of Ni-based CMH1, Ni-Fe-based CMH2, and Fe-based CMH3 has been evaluated by the Gleeble-3500 thermo-mechanical simulator with the assistance of CALPHAD-base Jmatpro and Deform-3D simulation software. The effect of 100 ppm yttrium addition on the properties of interconnect application in SOFCs has been assessed for SCY1, SCY2, and SCY3. In addition, grain boundary engineering (GBE) has been applied to CMH3 to enhance the high temperature properties. Meanwhile, the effect of GBE on the properties of interconnect application in SOFCs has been analyzed. The properties of interconnect application in SOFCs in this study include the oxidation resistance, area specific resistance (ASR), coefficient of thermal expansion (CTE), and Cr evaporation test at 800°C.
Research results indicate that the formability of CMH2 and CMH3 is good while the formability of CMH1 is bad. The addition of 100 ppm yttrium can enhance the oxidation resistance and electrical resistance for SCY1, SCY2, and SCY3. With the addition of yttrium, the Cr evaporation rate has been reduced for SCY1 and SCY3 while the Cr has evaporated more severely in SCY2. There is no difference in the coefficient of thermal expansion with the addition of yttrium. On the other hand, GBE-processed specimens (RX2 and STA1) have shown better oxidation resistance and lower ASR values in comparison to CMH3. The Cr evaporation rate for RX2 is lower while for STA1 is higher compared to CMH3. The oxidation weight change should be evaluated in company with the degree of Cr evaporation. Similarly, the thermal expansion behavior for CMH3, RX2, and STA1 has shown no difference.

Abstract    I
摘要    II
誌謝    III
Table of Contents    IV
   Introduction    1
   Literature Review    3
1.    Fuel cell    3
2.    Solid oxide fuel cells (SOFCs)    5
2.1    Properties of SOFCs:    7
2.2    Anode    8
2.3    Cathode    9
2.4    Electrolyte    10
2.5    Interconnect    11
3    Area specific resistance (ASR)    12
4    Coefficient of thermal expansion (CTE)    13
5    Cr evaporation    14
6    Metallic interconnect material    16
6.1    Metallic interconnect material    16
6.2    Reactive element effect (REE)    17
7.    Grain boundary engineering    18
7.1    Special boundary    18
7.2    Grain boundary engineering    19
7.3    Special boundary interaction    20
   Material Selection and Experimental Methods    22
1    Material selection    22
2    Experimental procedure    26
3    Sample preparation and heat treatment    28
4    Formability test    29
5    Grain boundary engineering    32
6    EBSD analysis    33
7    Oxidation test    34
8    ASR measurement    35
9    CTE measurement    35
10    Cr evaporation test    36
11    SIMS analysis    37
   Results and Discussion    38
1    Formability    38
1.1    Formability of CMH1    38
1.2    Formability of CMH2    41
1.3    Formability of CMH3    43
2    Effect of Y addition    45
2.1    Oxidation test    45
2.2    Area specific resistance (ASR)    52
2.3    Coefficient of thermal expansion (CTE)    58
2.4    Cr evaporation behavior    59
3    Grain boundary engineering (GBE) effect    65
3.1    Grain boundary character distribution (GBCD)    65
3.2    Oxidation test    73
3.3    Area specific resistance (ASR)    75
3.4    Coefficient of thermal expansion (CTE)    77
3.5    Cr evaporation behavior    78
   Conclusions    81
   Reference    83

                                

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