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研究生: 游雅涵
Yu, Ya-Han
論文名稱: DNA-金屬奈米粒子複合物製備與太陽能電池應用
Preparation and characterization of DNA-metal nanoparticle composite and its application in solar cells
指導教授: 洪毓玨
Hung, Yu-Chueh
口試委員: 金雅琴
黃淑娟
學位類別: 碩士
Master
系所名稱: 電機資訊學院 - 光電工程研究所
Institute of Photonics Technologies
論文出版年: 2012
畢業學年度: 100
語文別: 中文
論文頁數: 133
中文關鍵詞: 脫氧核醣核酸光化學法太陽能電池奈米粒子
外文關鍵詞: DNA, photochemical method, solar cell, nanoparticle
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  • 新穎的生物材料脫氧核醣核酸 (deoxyribonucleic acid,DNA)由於其特殊的結構和性質使它在奈米科技的應用上日趨廣泛,近年來,以DNA結構做為模板成長金屬奈米粒子的應用在電子元件領域更是越來越多。
    不同於以往複雜的化學製備方法,本論文以DNA生物材料為模板利用光化學法(photochemical method)製備銀奈米粒子,使奈米粒子成長於其中並藉由不同波段可見光源改變其形態,藉此製造出不同形狀的奈米粒子,我們使用三種波段的可見光:紫光LED、藍光LED和紅光LED,成功地於DNA模板中製造三種不同形狀的奈米粒子並將其應用於太陽能電池,研究發現利用金屬奈米粒子的散射效應,不同形狀的奈米粒子會在元件上對應不同波段的外部量子效率提升,而光電流最多能提升6%。
    以DNA模板合成金屬奈米粒子的製程方法簡單,且在元件製作上大幅減少了製成時間及成本,再配合不同波段的光源照射來控制其表面電漿共振的波段,這些特性將能在有機發光二極體、表面增強拉曼散射和生物感測等領域有更廣泛及多功能性的應用。


    第一章 緒論………………………………………………………………1 1.1 前言…………………………………………………………1 1.2 研究動機……………………………………………………2 1.3 論文架構……………………………………………………3 第二章 基本理論與文獻回顧……………………………………………4 2.1 金屬奈米粒子的介紹………………………………………4 2.1.1 效應…………………………………………………4 2.1.2 金屬奈米粒子的表面電漿共振……………………6 2.1.3 金屬奈米粒子的表面電漿模態……………………8 2.2 金屬奈米粒子的製備方法………………………………12 2.2.1 一般形態奈米粒子的製備………………………12 2.2.2 多型態奈米粒子的製備…………………………14 2.3 DNA奈米技術的研究及應用………………………………27 2.3.1 DNA簡介……………………………………………27 2.3.2 DNA模板用於奈米粒子的組裝……………………29 2.3.3 DNA模板金屬化的機制……………………………30 2.4 金屬奈米粒子的應用……………………………………36 2.4.1 太陽能電池基本參數介紹………………………36 2.4.2 金屬奈米粒子應用於太陽能電池………………39 第三章 實驗方法………………………………………………………44 3.1 藥品…………………………………………………………………44 3.2 DNA材料的製備……………………………………………46 3.2.1 DNA的製備…………………………………………46 3.2.2 合成銀奈米粒子的製備…………………………50 3.2.3 合成銀奈米粒子於DNA的製備……………………50 3.3 光源的介紹………………………………………………52 3.4 太陽能電池元件實驗流程………………………………56 3.5 元件結構與製程…………………………………………57 3.6 量測儀器介紹……………………………………………61 3.6.1 UV-Visible光譜儀………………………………61 3.6.2 穿透式電子顯微鏡………………………………61 3.6.3 I-V量測系統……………………………………62 3.6.4 量子效率量測系統………………………………62 第四章 結果與討論……………………………………………………65 4.1 DNA的電泳結果……………………………………………………65 4.2 材料的製備結果…………………………………………67 4.2.1 合成銀奈米粒子的製備結果……………………67 4.2.2 合成銀奈米粒子於DNA的製備結果………………77 4.2.3 材料的製備結果與討論…………………………94 4.3 太陽能電池元件結果……………………………………110 4.3.1 SEM結果…………………………………………110 4.3.2 I-V曲線比較……………………………………112 4.3.3 EQE曲線比較……………………………………117 4.3.4 元件的製備結果與討論………………………121 第五章 結論與未來展望………………………………………………124 參考文獻………………………………………………………………126

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